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METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZOATE

Product Name
METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZOATE
CAS No.
26107-80-2
Chemical Name
METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZOATE
Synonyms
BUTTPARK 89\07-68;RARECHEM AL BF 0207;Methyl 3,5-bis(trifluoromethyl);METHYL 3,5-DI(TRIFLUOROMETHYL)BENZOATE;METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZOATE;Methyl3,5-bis(trifluoromethyl)benzoate98%;Methyl 3,5-bis(trifluoromethyl)benzoate 98%;3,5-BIS(TRIFLUOROMETHYL)BENZOIC ACID METHYL ESTER;Benzoic acid, 3,5-bis(trifluoromethyl)-, methyl ester
CBNumber
CB3212910
Molecular Formula
C10H6F6O2
Formula Weight
272.14
MOL File
26107-80-2.mol
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METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZOATE Property

Boiling point:
85 °C
Density 
1.400±0.06 g/cm3 (20 ºC 760 Torr)
Flash point:
85-87°C/15mm
storage temp. 
Sealed in dry,Room Temperature
Appearance
Colorless to light yellow Liquid
CAS DataBase Reference
26107-80-2(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
Hazard Note 
Irritant
HS Code 
2916310090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC
Product number
M337685
Product name
Methyl3,5-bis(Trifluoromethyl)benzoate
Packaging
50mg
Price
$45
Updated
2021/12/16
AK Scientific
Product number
W4943
Product name
Methyl3,5-bis(trifluoromethyl)benzoate
Packaging
25g
Price
$58
Updated
2021/12/16
Matrix Scientific
Product number
002681
Product name
Methyl 3,5-bis(trifluoromethyl)benzoate
Purity
98%
Packaging
100g
Price
$71
Updated
2021/12/16
AK Scientific
Product number
J50373
Product name
Methyl3,5-bis(trifluoromethyl)benzoate
Packaging
100g
Price
$135
Updated
2021/12/16
Matrix Scientific
Product number
002681
Product name
Methyl 3,5-bis(trifluoromethyl)benzoate
Purity
98%
Packaging
5g
Price
$9
Updated
2021/12/16
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METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZOATE Chemical Properties,Usage,Production

Synthesis

67-56-1

401-96-7

26107-80-2

To the reaction system was added 25.9 g (0.8 mol) of methanol, and after chlorine-fluorine exchange using HF according to the method of Example 2, 13.8 g (0.053 mol) of 3,5-bis(trifluoromethyl)benzoyl fluoride fraction was obtained, which was added slowly and dropwise to the reaction system over 60 minutes. Subsequently, the reaction mixture was stirred at 40°C for 4 hours. The generation of 14.2 g (0.052 mol) of methyl 3,5-bis(trifluoromethyl)benzoate was confirmed by gas chromatographic analysis (yield: 98%, selectivity: 100%). By vacuum distillation, 13.9 g (0.05 mol) of methyl 3,5-bis(trifluoromethyl)benzoate was isolated (yield: 96%). Examples 17-31 Various (fluoroalkyl)benzene derivatives were prepared with reference to the methods of Examples 2-16. To improve the purity of the product, Example 17 was purified by crystallization twice, and the final distillation step was repeated in the remaining Examples. The purity, residual halogen content and residual metal content of all (fluoroalkyl)benzene derivatives are summarized in Table 2.

References

[1] Patent: EP1500641, 2005, A1. Location in patent: Page 10; 15

METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZOATE Suppliers

China 78 France 1 Germany 4 India 3 Italy 1 United Kingdom 9 United States 12 Global 108
Alfa Aesar, Thermo Fisher Scientific
Tel
--
Fax
--
Email
es@alfa.com
Country
Germany
ProdList
5123
Advantage
58
Service Chemical Inc.
Tel
--
Fax
--
Email
sales@chemos-group.com
Country
Germany
ProdList
6350
Advantage
71
ABCR GmbH & CO. KG
Tel
--
Fax
--
Email
info@abcr.de
Country
Germany
ProdList
6831
Advantage
75
Rare Chemicals GmbH
Tel
--
Fax
--
Email
sales@rarechem.de
Country
Germany
ProdList
6297
Advantage
38
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View Lastest Price from METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZOATE manufacturers

Career Henan Chemical Co
Product
METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZOATE 26107-80-2
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
Customized
Release date
2020-03-05

26107-80-2, METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZOATERelated Search:

3,5-Bis(trifluoromethyl)benzoic acid METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZOATE (1-METHYL-3-PHENYL-5-([3-(TRIFLUOROMETHYL)PHENYL]SULFONYL)-1H-PYRAZOL-4-YL)METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZENECARBOXYLATE RARECHEM AL FE 0083 ETHYL 3,5-BIS(TRIFLUOROMETHYL)BENZOATE (1-METHYL-3-PHENYL-5-[3-(TRIFLUOROMETHYL)PHENOXY]-1H-PYRAZOL-4-YL)METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZENECARBOXYLATE (5-[(2-CHLOROPHENYL)SULFANYL]-1-METHYL-3-PHENYL-1H-PYRAZOL-4-YL)METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZENECARBOXYLATE (1-METHYL-3-PHENYL-5-([3-(TRIFLUOROMETHYL)PHENYL]SULFANYL)-1H-PYRAZOL-4-YL)METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZENECARBOXYLATE (5-[(4-CHLOROPHENYL)SULFANYL]-1-METHYL-3-PHENYL-1H-PYRAZOL-4-YL)METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZENECARBOXYLATE (5-[(4-CHLOROPHENYL)SULFONYL]-1-METHYL-3-PHENYL-1H-PYRAZOL-4-YL)METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZENECARBOXYLATE

  • RARECHEM AL BF 0207
  • BUTTPARK 89\07-68
  • METHYL 3,5-DI(TRIFLUOROMETHYL)BENZOATE
  • METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZOATE
  • 3,5-BIS(TRIFLUOROMETHYL)BENZOIC ACID METHYL ESTER
  • Methyl 3,5-bis(trifluoromethyl)benzoate 98%
  • Methyl3,5-bis(trifluoromethyl)benzoate98%
  • Methyl 3,5-bis(trifluoromethyl)
  • Benzoic acid, 3,5-bis(trifluoromethyl)-, methyl ester
  • 26107-80-2
  • Benzoic acid