4-Acryloylmorpholine

Product Name: 4-Acryloylmorpholine
CAS No.: 5117-12-4
Chemical Name: 4-Acryloylmorpholine
Synonyms: ACRYLOYL MORPHOLINE;1-Morpholinoprop-2-en-1-one;N-ACRYLOYLMORPHOLINE;N-Acrylylmorpholine;4-AcryL;Acrylmorpholide;Acryloylmorpholin;4-Acrylmorpholine;ACRYOYL MORPHOLINE;N-Acrolylmorpholine
CBNumber: CB3229639
Molecular Formula: C7H11NO2
Formula Weight: 141.17
MOL File: 5117-12-4.mol

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4-Acryloylmorpholine Property

Melting point:: −35 °C(lit.)
Boiling point:: 158°C 50mm
Density: 1.122 g/mL at 25 °C(lit.)
vapor pressure: 1.03-1.64Pa at 25-29.9℃
refractive index: n20/D 1.512(lit.)
Flash point:: >230 °F
storage temp.: 2-8°C
solubility: Soluble in water
pka: -1.08±0.20(Predicted)
form: Liquid
color: Colorless to yellow
Water Solubility: 1000g/L at 20℃
Sensitive: Light Sensitive
BRN: 119302
InChIKey: XLPJNCYCZORXHG-UHFFFAOYSA-N
LogP: -0.46 at 20.5-21℃
CAS DataBase Reference: 5117-12-4(CAS DataBase Reference)
NIST Chemistry Reference: N-acryloylmorpholine(5117-12-4)
EPA Substance Registry System: Morpholine, 4-(1-oxo-2-propenyl)- (5117-12-4)

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Safety

Hazard Codes: Xn
Risk Statements: 22-41-43-48/22
Safety Statements: 23-26-36/37/39
WGK Germany: 2
TSCA: Yes
HS Code: 29349990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H317May cause an allergic skin reaction

H318Causes serious eye damage

H373May cause damage to organs through prolonged or repeated exposure

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 448273
Product name: 4-Acryloylmorpholine
Purity: 97%, contains 1,000 ppm monomethyl ether hydroquinone as inhibitor
Packaging: 50ml
Price: $82.3
Updated: 2024/03/01

Sigma-Aldrich

Product number: 448273
Product name: 4-Acryloylmorpholine
Purity: 97%, contains 1,000 ppm monomethyl ether hydroquinone as inhibitor
Packaging: 250ml
Price: $288
Updated: 2024/03/01

TCI Chemical

Product number: A0841
Product name: 4-Acryloylmorpholine (stabilized with MEHQ)
Purity: >98.0%(GC)
Packaging: 25mL
Price: $28
Updated: 2024/03/01

TCI Chemical

Product number: A0841
Product name: 4-Acryloylmorpholine (stabilized with MEHQ)
Purity: >98.0%(GC)
Packaging: 100mL
Price: $77
Updated: 2024/03/01

Alfa Aesar

Product number: L12947
Product name: 4-Acryloylmorpholine, 98+%, stab. with 4-methoxyphenol
Packaging: 5g
Price: $36.65
Updated: 2024/03/01

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4-Acryloylmorpholine Chemical Properties,Usage,Production

Chemical Properties

4-Acryloylmorpholine has a melting point of ?35 °C and is clear liquid at room temperature. At 25 °C, it has a density of 1.122 g/mL. It needs to be stored at 2-8°C.

Uses

4-Acryloylmorpholine is used in adhesives, UV curable resins, industrial coatings, UV printing ink, oil recovery polymer, medicinal and commodity chemicals.

Flammability and Explosibility

Non flammable

Synthesis

A solution of 0.04 mol of the corresponding amine in 20 ml of anhydrous methylene chloride was slowly added at 0-5??C to 0.02 mol of acryloyl chloride in 20 ml of anhydrous methylene chloride. The mixture was stirred for 3 h at room temperature in an inert atmosphere, and the precipitate was filtered off and washed with methylene chloride (2 ?á 10 ml). The organic layer was washed in succession with 5 ml of water and 5 ml of a saturated solution of NaHCO3 and dried over Na2SO4, the solvent was removed under reduced pressure, and the residue was purified by column chromatography on silica gel using hexane-ethyl acetate (5 : 1 to 1 : 1) as eluent. 4-Acryloylmorpholine, Yield 1.78 g (63%). IR spectrum, |í, cm-1: 2857, 1647, 1612, 1439, 1263, 1238, 1115, 1038, 953. 1H NMR spectrum, |?, ppm: 3.51-3.73 m (8H, NCH2CH2O), 5.72 d.d (1H, 3-Hcis, 3J = 10.6, 2J = 1.9 Hz), 6.29 d.d (1H, 3-Htrans, 3J = 16.7, 2J = 1.9 Hz), 6.57 d.d (1H, 2-H, J = 16.7, 10.6 Hz). 13C NMR spectrum, |?C, ppm: 41.74 and 45.66 (CH2N), 66.22 (CH2O), 126.64 (C2), 127.69 (C3), 164.92 (C1). Mass spectrum, m/z (Irel, %): 141 (36) [M]+, 140 (12), 126 (58), 112 (22), 111 (15), 110 (15), 109 (12), 98 (10), 96 (26), 86 (72), 83 (13), 70 (14), 68 (14), 57 (17), 56 (86), 55 (100), 42 (23).Fig. The synthetic method 2 of 4-Acryloylmorpholine

4-Acryloylmorpholine Preparation Products And Raw materials

Raw materials

Morpholine

Preparation Products

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4-Acryloylmorpholine Suppliers

Americas 1 China 250 Europe 2 Germany 3 India 2 Japan 2 Switzerland 1 United Kingdom 4 United States 13 Global 278

Jinan Wanduoxin Chemical Co., Ltd.

Tel: 531-88770993 13905318421
Fax: 0531-88275220
Email: wonderfulchem@163.com
Country: China
ProdList: 169
Advantage: 58

Yancheng Green Chemicals Co.,Ltd.

Tel: 25-86736275 15896456536
Email: marketing@royal-chem.com
Country: China
ProdList: 73
Advantage: 58

Anhui Royal Chemical Co., Ltd.

Tel: 25-86655873 13962173137
Fax: +86-25-52279193
Email: marketing@royal-chem.com
Country: China
ProdList: 170
Advantage: 60

Qingdao RENAS Polymer Material Co.,Ltd.

Tel: 0532-0532-86867058 18562606086
Fax: 0532-86867058
Email: sales@qdrenas.com
Country: China
ProdList: 89
Advantage: 50

Jobachem Suzhou Co., Ltd

Tel: 0512-62927368; 18136961057
Email: min.li@jobachem.com
Country: China
ProdList: 47
Advantage: 58

Suzhou Senfeida Chemical Material Co., Ltd.

Tel: 512-83500002 13862111431
Fax: 0512-66387035
Email: sales2@senfeida.com
Country: China
ProdList: 152
Advantage: 58

Tianjin Zhongxin Chemtech Co., Ltd.

Tel: 022-66880623
Fax: 86(0)22-66880086
Email: sales@tjzxchem.com
Country: China
ProdList: 614
Advantage: 60

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006608290; 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40241
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30132
Advantage: 84

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View Lastest Price from 4-Acryloylmorpholine manufacturers

Qingdao RENAS Polymer Material Co., Ltd.

Product: 4-Acryloylmorpholine 5117-12-4
Price: US $0.00/kg
Min. Order: 20kg
Purity: 98.0%
Supply Ability: 10 tons
Release date: 2024-04-29

Shanghai Longyu Biotechnology Co., Ltd.

Product: 4-Acryloylmorpholine 5117-12-4
Price: US $1.00/g
Min. Order: 1g
Purity: 99
Supply Ability: 20tons
Release date: 2021-12-04

Ouhuang Engineering Materials (Hubei) Co., Ltd

Product: 4-Acryloylmorpholine 5117-12-4
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99.6%
Supply Ability: 100000
Release date: 2024-04-23

5117-12-4, 4-AcryloylmorpholineRelated Search:

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ACRYLOYL MORPHOLINE

4-ACRYLOYLMORPHOLINE

N-ACRYLOYLMORPHOLINE

4-(1-oxo-2-propenyl)-Morpholine

N-Acrolylmorpholine

N-Acrylylmorpholine

ACRYOYL MORPHOLINE

4-Acryloylmorpholine (stabilized with MEHQ)

Morpholine, 4-(1-oxo-2-propenyl)-

Acryloylmorpholin

4-ACRYLOYLMORPHOLINE, 98+%, STAB. WITH 4-METHOXYPHENOL

4-Acryloylmorpholine,98+%

4-Acryloylmorpholine(ACMO)

2-Propen-1-one,1-(4-morpholinyl)- /ACMO

2-Propen-1-one,1-(4-Morpholinyl)-

4-AcryloylMorpholine 97%, contains 1,000 ppM MonoMethyl ether hydroquinone as inhibitor

1-Morpholinoprop-2-en-1-one

1-Morpholino-2-propen-1-one

4-Acrylylmorpholine

4-Propenoylmorpholine

Acrylmorpholide

4-Acryloylmorpholine, Stab. With 4-Methoxyphenol

4-Acryloylmorpholine, stabilized with 4-methoxyphenol

4-Acryloylmorpholine (contains 1,000 ppm monomethyl ether hydroquinone as inhibitor)≥ 99% (Assay)

4-AcryL

4-Acryloylmorpholine(stabilizedwithMEHQ)&gt

AMCO、4-Acryloylmorpholine

Metformin Impurity 42

4-Acrylmorpholine Photoinitiator

4-Acrylmorpholine

Sinomer? ACMO Monomer / 4-acryloylmorpholine

5117-12-4

C7H11O2N

AMINE

Acrylate

Acrylic Monomers

Monomers