ChemicalBook > CAS DataBase List > 5-CHLORO-[1,2,4]TRIAZOLO[4,3-A]PYRIDINE

5-CHLORO-[1,2,4]TRIAZOLO[4,3-A]PYRIDINE

Product Name
5-CHLORO-[1,2,4]TRIAZOLO[4,3-A]PYRIDINE
CAS No.
27187-13-9
Chemical Name
5-CHLORO-[1,2,4]TRIAZOLO[4,3-A]PYRIDINE
Synonyms
Nsc289808;5-CHLORO-[1,2,4]TRIAZOLO[4,3-A]PYRIDINE;1,2,4-TRIAZOLO[4,3-A]PYRIDINE, 5-CHLORO-;5-Chloro-1,2,4-triazolo[4,3-a]pyridine,97%;5-Chloro-[1,2,4]triazolo[4,3-a]pyridine
CBNumber
CB32455946
Molecular Formula
C6H4ClN3
Formula Weight
153.57
MOL File
27187-13-9.mol
More
Less

5-CHLORO-[1,2,4]TRIAZOLO[4,3-A]PYRIDINE Property

Melting point:
87-89 °C
Density 
1.51±0.1 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
1.97±0.50(Predicted)
form 
Solid
Appearance
Brown to reddish brown Solid
More
Less

Safety

Hazard Codes 
Xn
Risk Statements 
22
WGK Germany 
3
HS Code 
2933998090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P330Rinse mouth.

P403Store in a well-ventilated place.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
SYX00172
Product name
5-Chloro-[1,2,4]triazolo[4,3-a]pyridine
Purity
Aldrich
Packaging
1g
Price
$475
Updated
2025/07/31
TRC
Product number
C384393
Product name
5-Chloro-[1,2,4]triazolo[4,3-A]pyridine
Packaging
100mg
Price
$90
Updated
2021/12/16
Apolloscientific
Product number
OR909064
Product name
5-chloro-[1,2,4]triazolo[4,3-a]pyridine
Purity
95%
Packaging
250mg
Price
$130
Updated
2021/12/16
SynQuest Laboratories
Product number
3H32-5-QE
Product name
5-Chloro-[1,2,4]triazolo[4,3-a]pyridine
Purity
95%
Packaging
1g
Price
$480
Updated
2021/12/16
Matrix Scientific
Product number
069856
Product name
5-Chloro-[1,2,4]triazolo[4,3-a]pyridine
Purity
98%
Packaging
1g
Price
$492
Updated
2021/12/16
More
Less

5-CHLORO-[1,2,4]TRIAZOLO[4,3-A]PYRIDINE Chemical Properties,Usage,Production

Synthesis

5193-03-3

122-51-0

27187-13-9

General procedure for the synthesis of 5-chloro-[1,2,4]triazolo[4,3-a]pyridine from 2-chloro-6-hydrazinylpyridine and triethyl orthoformate: 2-chloro-6-hydrazinylpyridine (3.0 g, 20.9 mmol) and triethyl orthoformate (20 mL, 120.2 mmol) were added to a 125 mL round bottom flask. The reaction mixture was heated to reflux for 4 hours, then cooled to room temperature and allowed to stand overnight. The mixture was concentrated to dryness under reduced pressure and trichlorophosphate (50 mL) was added. The mixture was refluxed overnight. Upon completion of the reaction, the reaction solution was quenched in an ice bath and washed with dichloromethane (CH2Cl2). The aqueous phase was adjusted to pH 6 with 1 N sodium hydroxide solution and subsequently extracted with dichloromethane. The organic phases were combined, concentrated under reduced pressure and purified by silica gel column chromatography, eluting sequentially with 100% ethyl acetate (500 mL) and 5% methanol/dichloromethane to afford 5-chloro-[1,2,4]triazolo[4,3-a]pyridine (1.73 g, 11.25 mmol, 53% yield) as a solid.

References

[1] Patent: WO2008/118718, 2008, A2. Location in patent: Page/Page column 119

5-CHLORO-[1,2,4]TRIAZOLO[4,3-A]PYRIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

5-CHLORO-[1,2,4]TRIAZOLO[4,3-A]PYRIDINE Suppliers

Alfa Aesar
Tel
--
Fax
--
Email
tech@alfa.com
Country
India
ProdList
6905
Advantage
58
A.J Chemicals
Tel
--
Fax
--
Email
sales@ajchem.in
Country
India
ProdList
6100
Advantage
58
More
Less

View Lastest Price from 5-CHLORO-[1,2,4]TRIAZOLO[4,3-A]PYRIDINE manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
1,2,4-Triazolo[4,3-a]pyridine,5-chloro- 27187-13-9
Price
US $1.10-9.90/KG
Min. Order
1KG
Purity
99% min
Supply Ability
100kg
Release date
2025-08-18

27187-13-9, 5-CHLORO-[1,2,4]TRIAZOLO[4,3-A]PYRIDINERelated Search:


  • 1,2,4-TRIAZOLO[4,3-A]PYRIDINE, 5-CHLORO-
  • 5-CHLORO-[1,2,4]TRIAZOLO[4,3-A]PYRIDINE
  • Nsc289808
  • 5-Chloro-1,2,4-triazolo[4,3-a]pyridine,97%
  • 5-Chloro-[1,2,4]triazolo[4,3-<i>a</i>]pyridine
  • 27187-13-9