ChemicalBook > CAS DataBase List > 5-bromo-2-phenoxypyridine
5-bromo-2-phenoxypyridine
- Product Name
- 5-bromo-2-phenoxypyridine
- CAS No.
- 59717-96-3
- Chemical Name
- 5-bromo-2-phenoxypyridine
- Synonyms
- 5-bromo-2-phenoxypyridine;Pyridine,5-bromo-2-phenoxy-
- CBNumber
- CB32499704
- Molecular Formula
- C11H8BrNO
- Formula Weight
- 250.09
- MOL File
- 59717-96-3.mol
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5-bromo-2-phenoxypyridine Property
- Boiling point:
- 310.0±22.0 °C(Predicted)
- Density
- 1.476±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- pka
- 0.18±0.22(Predicted)
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Safety
- HS Code
- 2933399990
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
TRC
- Product number
- B687393
- Product name
- 5-Bromo-2-phenoxypyridine
- Packaging
- 250mg
- Price
- $55
- Updated
- 2021/12/16
Biosynth Carbosynth
- Product number
- FB140371
- Product name
- 5-Bromo-2-phenoxypyridine
- Packaging
- 1g
- Price
- $55
- Updated
- 2021/12/16
Biosynth Carbosynth
- Product number
- FB140371
- Product name
- 5-Bromo-2-phenoxypyridine
- Packaging
- 2g
- Price
- $95
- Updated
- 2021/12/16
Biosynth Carbosynth
- Product number
- FB140371
- Product name
- 5-Bromo-2-phenoxypyridine
- Packaging
- 5G
- Price
- $190
- Updated
- 2021/12/16
AK Scientific
- Product number
- Z0717
- Product name
- 5-Bromo-2-phenoxypyridine
- Packaging
- 10g
- Price
- $244
- Updated
- 2021/12/16
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5-bromo-2-phenoxypyridine Chemical Properties,Usage,Production
Synthesis
624-28-2
108-95-2
59717-96-3
2,5-dibromopyridine (237 mg, 1 mmol, 1.0 equiv) and phenol (140 mg, 1.5 mmol, 1.5 equiv) were added with copper powder (32.5 mg, 0.5 mmol, 0.5 equiv), cuprous iodide (95 mg, 0.5 mmol, 0.5 equiv) and cesium carbonate (978 mg. 3.0 mmol, 3.0 equiv) in N-methylpyrrolidone (NMP, 10 mL). The reaction mixture was heated to 135 °C under nitrogen protection and maintained at this temperature for 5 h of reaction. After completion of the reaction, the solid insoluble material was removed by filtration and the filtrate was concentrated. Purification by column chromatography (eluent: ethyl acetate/petroleum ether = 10/1, v/v) afforded 5-bromo-2-phenoxypyridine as a brown solid (200 mg, 84.4% yield).
References
[1] Tetrahedron, 2013, vol. 69, # 1, p. 327 - 333
[2] Patent: CN108069974, 2018, A. Location in patent: Paragraph 0162-0165
[3] Patent: WO2018/35061, 2018, A1. Location in patent: Paragraph 0358
[4] Journal of Organometallic Chemistry, 2003, vol. 677, # 1-2, p. 57 - 72
[5] Patent: CN106146518, 2016, A. Location in patent: Paragraph 0038; 0039; 0040; 0041; 0042; 0043
5-bromo-2-phenoxypyridine Preparation Products And Raw materials
Raw materials
Preparation Products
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