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Boron trifluoride methyl sulfide complex

Product Name
Boron trifluoride methyl sulfide complex
CAS No.
353-43-5
Chemical Name
Boron trifluoride methyl sulfide complex
Synonyms
C2H6BF3S;uoride-dimethyL;purified,packagedunderArgon;boron trifluoride-dimethyl s;TRIFLUOROBORANE-METHYL SULFIDE;DIMETHYL SULFIDE-TRIFLUOROBORANE;Boron trifluoride DMS complex-95%;Boron Trifluoride-Dimethyl Sulfide;BORON FLUORIDE-DIMETHYL SULFIDE COMPLEX;BORON TRIFLUORIDE-METHYL SULFIDE COMPLEX
CBNumber
CB3251258
Molecular Formula
C2H7BF3S
Formula Weight
130.94
MOL File
353-43-5.mol
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Boron trifluoride methyl sulfide complex Property

Density 
1.235 g/mL at 25 °C (lit.)
Flash point:
4 °F
solubility 
sol most organic solvents such as pentane
form 
Liquid
Sensitive 
Moisture Sensitive
InChI
InChI=1S/C2H7BF3S/c1-7(2)3(4,5)6/h7H,1-2H3
InChIKey
VPECYQXBNOAJIF-UHFFFAOYSA-N
SMILES
[B+3]([F-])([F-])([F-])S(C)C
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Safety

Hazard Codes 
F,C
Risk Statements 
11-34
Safety Statements 
16-26-27-36/37/39-45
RIDADR 
UN 2924 3/PG 2
WGK Germany 
3
HazardClass 
8
PackingGroup 
I
HS Code 
2930909899
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
261998
Product name
Boron trifluoride methyl sulfide complex
Purity
95%
Packaging
100ml
Price
$363
Updated
2025/07/31
SynQuest Laboratories
Product number
5166-3-02
Product name
Boron trifluoride methyl sulfide complex
Purity
95%
Packaging
500g
Price
$355
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB166777
Product name
Boron trifluoride methyl sulfide complex
Packaging
250g
Price
$600
Updated
2021/12/16
Apolloscientific
Product number
PC32794
Product name
Boron trifluoride methyl sulfide complex
Packaging
500g
Price
$617
Updated
2021/12/16
AK Scientific
Product number
7016DU
Product name
Boronfluoride-dimethylsulfidecomplex
Packaging
250g
Price
$860
Updated
2021/12/16
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Boron trifluoride methyl sulfide complex Chemical Properties,Usage,Production

Description

Boron trifluoride methyl sulfide complex is reagent for the cleavage of benzyl ethers and carbamates.

Uses

Boron trifluoride methyl sulfide complex is a common reagent used for dealkylation of ethers. It can also be used to synthesize boron trifluoride complex with phosphine ligands.

Preparation

Boron trifluoride methyl sulfide complex is made by the addition of equimolar amounts of the two components at -78 °C. Dissociation of the complex reported as 96.2% at 12 °C and 97.4% at 34 °C. Also formed when crystalline bromodimethylsulfonium tetrafluoroborate is aspirated at rt to give a colorless product without change in crystal form. The reagent system is normally assembled by adding a large excess of dimethyl sulfide to an excess of boron trifluoride etherate.

reaction suitability

core: boron
reagent type: Lewis acid
reagent type: catalyst

storage

moisture-sensitive; use with carefully dried apparatus. All work must be carried out in an efficient fume hood.

Boron trifluoride methyl sulfide complex Preparation Products And Raw materials

Raw materials

Preparation Products

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Boron trifluoride methyl sulfide complex Suppliers

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