ChemicalBook > CAS DataBase List > 2-aminomethyloxetane

2-aminomethyloxetane

Product Name
2-aminomethyloxetane
CAS No.
882402-12-2
Chemical Name
2-aminomethyloxetane
Synonyms
2-Oxetanemethanamine;2-aminomethyloxetane;(Oxetan-2-yl)methylamine;C-Oxetan-2-yl-methylamine;2-Oxetanemethanamine - [X6187];2-aminomethyloxetane ISO 9001:2015 REACH
CBNumber
CB32520608
Molecular Formula
C4H9NO
Formula Weight
87.12
MOL File
882402-12-2.mol
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2-aminomethyloxetane Property

Boiling point:
130.9±13.0 °C(Predicted)
Density 
1.004±0.06 g/cm3(Predicted)
storage temp. 
2-8°C(protect from light)
pka
9.47±0.29(Predicted)
form 
liquid
color 
Colourless
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Safety

RIDADR 
UN2811
HS Code 
2932990090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

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N-Bromosuccinimide Price

TRC
Product number
E590030
Product name
oxetan-2-ylmethanamine
Packaging
50mg
Price
$155
Updated
2021/12/16
Matrix Scientific
Product number
070690
Product name
2-Oxetanemethanamine
Purity
95%
Packaging
500mg
Price
$260
Updated
2021/12/16
SynQuest Laboratories
Product number
4H56-1-6C
Product name
2-(Aminomethyl)oxetane
Packaging
250mg
Price
$275
Updated
2021/12/16
Matrix Scientific
Product number
070690
Product name
2-Oxetanemethanamine
Purity
95%
Packaging
1g
Price
$545
Updated
2021/12/16
AK Scientific
Product number
V8594
Product name
2-Oxetanemethanamine
Packaging
1g
Price
$613
Updated
2021/12/16
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2-aminomethyloxetane Chemical Properties,Usage,Production

Synthesis

882402-11-1

882402-12-2

Step 2: Preparation of 2-aminomethyl oxetane: 2-(phthaloylmethyl)oxetane (product of step 1, 19 g, 87.5 mmol) was dissolved in ethanol (250 ml) followed by addition of hydrazine hydrate (6.56 g, 131.2 mmol). The reaction mixture was heated to reflux and maintained for 30 min. After completion of the reaction, the precipitate was collected by filtration. A small amount of Raney Ni (catalyst type W-2) was added to the filtrate and the reaction was continued at reflux for 1.5 hours. At the end of the reaction, the filtrate was filtered to remove inorganic solid impurities. The filtrate was carefully concentrated under reduced pressure to give the crude product. The crude product was purified by vacuum distillation to collect a colorless liquid fraction (3.63 g, about 47% yield) with a boiling point of 55-60 °C/30 mbar. The product contained ethanol and DMF residues and could be used directly in subsequent reactions without further purification.

References

[1] Patent: US2008/275065, 2008, A1. Location in patent: Page/Page column 18

2-aminomethyloxetane Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 2-aminomethyloxetane manufacturers

Career Henan Chemical Co
Product
OXETAN-2-YLMETHANAMINE 882402-12-2
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2020-01-09