ChemicalBook > CAS DataBase List > [(S,S)-Teth-TsDpen RuCl]
[(S,S)-Teth-TsDpen RuCl]
- Product Name
- [(S,S)-Teth-TsDpen RuCl]
- CAS No.
- 851051-43-9
- Chemical Name
- [(S,S)-Teth-TsDpen RuCl]
- Synonyms
- [(S,S)-Teth-TsDpen RuCl];[(S,S)-Teth-TsDpen RuCl];[(S,S)-Teth-TsDPEN-RuCl], Ru 16.3%;(S,S)-TETH-TSDPEN RUCL WILLS CATALYST;chloro-[[1,2-diphenyl-2-(3-phenylpropylamino)ethyl]-(p-tolylsulfonyl)amino]ruthenium;6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN')-ethyl-2-amino-;{N-[3-(·:6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN')-ethyl-2-amino-;N-[(1S,2S)-1,2-Diphenyl-2-[(3-phenylpropyl)amino]ethyl]-4-methylphenylsulfonamido]ruthenium(II) Chloride;Chloro[N-[(1S,2S)-1,2-diphenyl-2-[[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]ruthenium;{N-[3-(η6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN)-ethyl-2-amino-(kN)]}ruthenium(II)
- CBNumber
- CB32620041
- Molecular Formula
- C30H25ClN2O2RuS
- Formula Weight
- 614.12
- MOL File
- 851051-43-9.mol
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[(S,S)-Teth-TsDpen RuCl] Property
- Melting point:
- 260-268℃
- storage temp.
- 2-8°C
- form
- Powder
- color
- orange
- optical activity
- [α]22/D +339°, c = 0.5% in chloroform
- Sensitive
- Air & Moisture Sensitive
- InChIKey
- JEYDUUAESBTPET-UHFFFAOYSA-M
- SMILES
- [Cl-][Ru+2]1234567N(CCCC81=C2C3=C4C5=C68)C(C1C=CC=CC=1)C(C1C=CC=CC=1)[N-]7S(C1C=CC(C)=CC=1)(=O)=O
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Safety
- WGK Germany
- 3
- Storage Class
- 11 - Combustible Solids
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 752800
- Product name
- [(S,S)-Teth-TsDpen RuCl]
- Packaging
- 100mg
- Price
- $133
- Updated
- 2025/07/31
Sigma-Aldrich
- Product number
- 752800
- Product name
- [(S,S)-Teth-TsDpen RuCl]
- Packaging
- 500mg
- Price
- $285
- Updated
- 2025/07/31
Strem Chemicals
- Product number
- 44-0110
- Product name
- {N-[3-(η6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN)-ethyl-2-amino-(kN)]}ruthenium(II) (S,S)-Teth-TsDpen RuCl WILLS CATALYST
- Packaging
- 100mg
- Price
- $97
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 44-0110
- Product name
- {N-[3-(η6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN)-ethyl-2-amino-(kN)]}ruthenium(II) (S,S)-Teth-TsDpen RuCl WILLS CATALYST
- Packaging
- 500mg
- Price
- $235
- Updated
- 2024/03/01
TRC
- Product number
- C378025
- Product name
- Chloro[N-[(1S,2S)-1,2-diphenyl-2-[(R)-[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]rutheniumStereoisomerC30H31ClN2O2RuS
- Packaging
- 1g
- Price
- $760
- Updated
- 2021/12/16
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[(S,S)-Teth-TsDpen RuCl] Chemical Properties,Usage,Production
Uses
Catalyst for the asymmetric transfer hydrogenation of ketones
Uses
Chloro[N-[(1S,2S)-1,2-diphenyl-2-[(R)-[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]ruthenium StereoisomerC30 H31ClN2O2RuS is a catalyst for Asymmetric Transfer Hydrogenations of Ketones.
Uses
[(S,S)-Teth-TsDpen RuCl] is a catalyst for the asymmetric hydrogenation of ketones. It can be used as a catalyst:
- In the reduction of a ketone intermediate for the synthesis of esketamine.
- In asymmetric hydrogenation of acetylenic ketones.
- For the preparation of (3S,6S)-1,8-diphenylocta-1,7-diyne-3,6-diol starting from 1,8-diphenylocta-1,7-diyne-3,6-dione.
Reactions
Catalyst used for asymmetric -transfer hydrogenation.
reaction suitability
core: ruthenium
reagent type: catalyst
[(S,S)-Teth-TsDpen RuCl] Preparation Products And Raw materials
Raw materials
Preparation Products
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