[(S,S)-Teth-TsDpen RuCl]

Product Name: [(S,S)-Teth-TsDpen RuCl]
CAS No.: 851051-43-9
Chemical Name: [(S,S)-Teth-TsDpen RuCl]
Synonyms: [(S,S)-Teth-TsDpen RuCl];[(S,S)-Teth-TsDPEN-RuCl], Ru 16.3%;(S,S)-TETH-TSDPEN RUCL WILLS CATALYST;chloro-[[1,2-diphenyl-2-(3-phenylpropylamino)ethyl]-(p-tolylsulfonyl)amino]ruthenium;6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN')-ethyl-2-amino-;{N-[3-(·:6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN')-ethyl-2-amino-;N-[(1S,2S)-1,2-Diphenyl-2-[(3-phenylpropyl)amino]ethyl]-4-methylphenylsulfonamido]ruthenium(II) Chloride;Chloro[N-[(1S,2S)-1,2-diphenyl-2-[[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]ruthenium;{N-[3-(η6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN)-ethyl-2-amino-(kN)]}ruthenium(II);Chloro[N-[(1S,2S)-1,2-diphenyl-2-[(R)-[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]ruthenium StereoisomerC30 H31ClN2O2RuS
CBNumber: CB32620041
Molecular Formula: C30H25ClN2O2RuS
Formula Weight: 614.12
MOL File: 851051-43-9.mol

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[(S,S)-Teth-TsDpen RuCl] Property

Melting point:: 260-268℃
storage temp.: 2-8°C
form: Powder
color: orange
optical activity: [α]22/D +339°, c = 0.5% in chloroform
Sensitive: Air & Moisture Sensitive

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Safety

WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 752800
Product name: [(S,S)-Teth-TsDpen RuCl]
Packaging: 100mg
Price: $77.4
Updated: 2024/03/01

Sigma-Aldrich

Product number: 752800
Product name: [(S,S)-Teth-TsDpen RuCl]
Packaging: 500mg
Price: $276
Updated: 2024/03/01

Strem Chemicals

Product number: 44-0110
Product name: {N-[3-(η6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN)-ethyl-2-amino-(kN)]}ruthenium(II) (S,S)-Teth-TsDpen RuCl WILLS CATALYST
Packaging: 100mg
Price: $97
Updated: 2024/03/01

Strem Chemicals

Product number: 44-0110
Product name: {N-[3-(η6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN)-ethyl-2-amino-(kN)]}ruthenium(II) (S,S)-Teth-TsDpen RuCl WILLS CATALYST
Packaging: 500mg
Price: $235
Updated: 2024/03/01

TRC

Product number: C378025
Product name: Chloro[N-[(1S,2S)-1,2-diphenyl-2-[(R)-[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]rutheniumStereoisomerC30H31ClN2O2RuS
Packaging: 1g
Price: $760
Updated: 2021/12/16

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[(S,S)-Teth-TsDpen RuCl] Chemical Properties,Usage,Production

Uses

Catalyst for the asymmetric transfer hydrogenation of ketones

Uses

Chloro[N-[(1S,2S)-1,2-diphenyl-2-[(R)-[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]ruthenium StereoisomerC30 H31ClN2O2RuS is a catalyst for Asymmetric Transfer Hydrogenations of Ketones.

Uses

[(S,S)-Teth-TsDpen RuCl] is a catalyst for the asymmetric hydrogenation of ketones. It can be used as a catalyst:

In the reduction of a ketone intermediate for the synthesis of esketamine.
In asymmetric hydrogenation of acetylenic ketones.
For the preparation of (3S,6S)-1,8-diphenylocta-1,7-diyne-3,6-diol starting from 1,8-diphenylocta-1,7-diyne-3,6-dione.

Reactions

Catalyst used for asymmetric -transfer hydrogenation.

[(S,S)-Teth-TsDpen RuCl] Preparation Products And Raw materials

Raw materials

Preparation Products

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[(S,S)-Teth-TsDpen RuCl] Suppliers

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851051-43-9, [(S,S)-Teth-TsDpen RuCl]Related Search:

[(S,S)-Teth-TsDPEN-RuCl], Ru 16.3%

{N-[3-(η6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-MethylbenzenesulfonylaMidato(kN -ethyl-2-aMino-(kN)]}rutheniuM(II) (S,S)-Teth-TsDpen RuCl WILLS CATALYST

[(S,S)-Teth-TsDpen RuCl]

{N-[3-(·:6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN')-ethyl-2-amino-

6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN')-ethyl-2-amino-(kN)]}ruthenium(II) (S,S)-Teth-TsDpen RuCl WILLS CATALYST

(S,S)-TETH-TSDPEN RUCL WILLS CATALYST

Chloro[N-[(1S,2S)-1,2-diphenyl-2-[(R)-[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]ruthenium StereoisomerC30 H31ClN2O2RuS

6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN')-ethyl-2-amino-

{N-[3-(η6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN)-ethyl-2-amino-(kN)]}ruthenium(II)

(S,S)-Teth-TsDpen RuCl WILLS CATALYST/{N-[3-(η6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN')-ethyl-2-amino-(kN)]}ruthenium(II)

N-[(1S,2S)-1,2-Diphenyl-2-[(3-phenylpropyl)amino]ethyl]-4-methylphenylsulfonamido]ruthenium(II) Chloride

Chloro[N-[(1S,2S)-1,2-diphenyl-2-[[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]ruthenium

chloro-[[1,2-diphenyl-2-(3-phenylpropylamino)ethyl]-(p-tolylsulfonyl)amino]ruthenium

851051-43-9

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