ChemicalBook > CAS DataBase List > [(S,S)-Teth-TsDpen RuCl]

[(S,S)-Teth-TsDpen RuCl]

Product Name
[(S,S)-Teth-TsDpen RuCl]
CAS No.
851051-43-9
Chemical Name
[(S,S)-Teth-TsDpen RuCl]
Synonyms
[(S,S)-Teth-TsDpen RuCl];[(S,S)-Teth-TsDPEN-RuCl], Ru 16.3%;(S,S)-TETH-TSDPEN RUCL WILLS CATALYST;chloro-[[1,2-diphenyl-2-(3-phenylpropylamino)ethyl]-(p-tolylsulfonyl)amino]ruthenium;6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN')-ethyl-2-amino-;{N-[3-(·:6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN')-ethyl-2-amino-;N-[(1S,2S)-1,2-Diphenyl-2-[(3-phenylpropyl)amino]ethyl]-4-methylphenylsulfonamido]ruthenium(II) Chloride;Chloro[N-[(1S,2S)-1,2-diphenyl-2-[[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]ruthenium;{N-[3-(η6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN)-ethyl-2-amino-(kN)]}ruthenium(II);Chloro[N-[(1S,2S)-1,2-diphenyl-2-[(R)-[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]ruthenium StereoisomerC30 H31ClN2O2RuS
CBNumber
CB32620041
Molecular Formula
C30H25ClN2O2RuS
Formula Weight
614.12
MOL File
851051-43-9.mol
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[(S,S)-Teth-TsDpen RuCl] Property

Melting point:
260-268℃
storage temp. 
2-8°C
form 
Powder
color 
orange
optical activity
[α]22/D +339°, c = 0.5% in chloroform
Sensitive 
Air & Moisture Sensitive
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Safety

WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
752800
Product name
[(S,S)-Teth-TsDpen RuCl]
Packaging
100mg
Price
$77.4
Updated
2024/03/01
Sigma-Aldrich
Product number
752800
Product name
[(S,S)-Teth-TsDpen RuCl]
Packaging
500mg
Price
$276
Updated
2024/03/01
Strem Chemicals
Product number
44-0110
Product name
{N-[3-(η6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN)-ethyl-2-amino-(kN)]}ruthenium(II) (S,S)-Teth-TsDpen RuCl WILLS CATALYST
Packaging
100mg
Price
$97
Updated
2024/03/01
Strem Chemicals
Product number
44-0110
Product name
{N-[3-(η6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN)-ethyl-2-amino-(kN)]}ruthenium(II) (S,S)-Teth-TsDpen RuCl WILLS CATALYST
Packaging
500mg
Price
$235
Updated
2024/03/01
TRC
Product number
C378025
Product name
Chloro[N-[(1S,2S)-1,2-diphenyl-2-[(R)-[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]rutheniumStereoisomerC30H31ClN2O2RuS
Packaging
1g
Price
$760
Updated
2021/12/16
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[(S,S)-Teth-TsDpen RuCl] Chemical Properties,Usage,Production

Uses

Catalyst for the asymmetric transfer hydrogenation of ketones

Uses

Chloro[N-[(1S,2S)-1,2-diphenyl-2-[(R)-[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]ruthenium StereoisomerC30 H31ClN2O2RuS is a catalyst for Asymmetric Transfer Hydrogenations of Ketones.

Uses

[(S,S)-Teth-TsDpen RuCl] is a catalyst for the asymmetric hydrogenation of ketones. It can be used as a catalyst:

  • In the reduction of a ketone intermediate for the synthesis of esketamine.
  • In asymmetric hydrogenation of acetylenic ketones.
  • For the preparation of (3S,6S)-1,8-diphenylocta-1,7-diyne-3,6-diol starting from 1,8-diphenylocta-1,7-diyne-3,6-dione.

Reactions

Catalyst used for asymmetric -transfer hydrogenation.

[(S,S)-Teth-TsDpen RuCl] Preparation Products And Raw materials

Raw materials

Preparation Products

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[(S,S)-Teth-TsDpen RuCl] Suppliers

Shaoxing Zejun Pharmaceuticals Co.,Ltd
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0575-82126188 15395856318
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China
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J & K SCIENTIFIC LTD.
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86-10-82849933
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jkinfo@jkchemical.com
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400-6106006
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021-67582001/03/05
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021-50460086-9 15921403865
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851051-43-9, [(S,S)-Teth-TsDpen RuCl]Related Search:


  • [(S,S)-Teth-TsDPEN-RuCl], Ru 16.3%
  • {N-[3-(η6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-MethylbenzenesulfonylaMidato(kN -ethyl-2-aMino-(kN)]}rutheniuM(II) (S,S)-Teth-TsDpen RuCl WILLS CATALYST
  • [(S,S)-Teth-TsDpen RuCl]
  • {N-[3-(·:6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN')-ethyl-2-amino-
  • 6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN')-ethyl-2-amino-(kN)]}ruthenium(II) (S,S)-Teth-TsDpen RuCl WILLS CATALYST
  • (S,S)-TETH-TSDPEN RUCL WILLS CATALYST
  • Chloro[N-[(1S,2S)-1,2-diphenyl-2-[(R)-[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]ruthenium StereoisomerC30 H31ClN2O2RuS
  • 6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN')-ethyl-2-amino-
  • {N-[3-(η6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN)-ethyl-2-amino-(kN)]}ruthenium(II)
  • (S,S)-Teth-TsDpen RuCl WILLS CATALYST/{N-[3-(η6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN')-ethyl-2-amino-(kN)]}ruthenium(II)
  • N-[(1S,2S)-1,2-Diphenyl-2-[(3-phenylpropyl)amino]ethyl]-4-methylphenylsulfonamido]ruthenium(II) Chloride
  • Chloro[N-[(1S,2S)-1,2-diphenyl-2-[[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]ruthenium
  • chloro-[[1,2-diphenyl-2-(3-phenylpropylamino)ethyl]-(p-tolylsulfonyl)amino]ruthenium
  • 851051-43-9
  • Ru
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