ChemicalBook > CAS DataBase List > 4-Bromo-1-(bromomethyl)-2-iodobenzene, alpha,4-Dibromo-2-iodotoluene

4-Bromo-1-(bromomethyl)-2-iodobenzene, alpha,4-Dibromo-2-iodotoluene

Product Name
4-Bromo-1-(bromomethyl)-2-iodobenzene, alpha,4-Dibromo-2-iodotoluene
CAS No.
885681-96-9
Chemical Name
4-Bromo-1-(bromomethyl)-2-iodobenzene, alpha,4-Dibromo-2-iodotoluene
Synonyms
4-Bromo-2-Iodobenzyl Bromide;4-Bromo-2-iodobenzylbromide97%;4-Bromo-2-iodobenzyl bromide 97%;4-Bromo-1-(bromomethyl)-2-iodobenzene;Benzene, 4-bromo-1-(bromomethyl)-2-iodo-;4-Bromo-1-(bromomethyl)-2-iodobenzene, alpha,4-Dibromo-2-iodotoluene
CBNumber
CB32696695
Molecular Formula
C7H5Br2I
Formula Weight
375.83
MOL File
885681-96-9.mol
More
Less

4-Bromo-1-(bromomethyl)-2-iodobenzene, alpha,4-Dibromo-2-iodotoluene Property

storage temp. 
2-8°C(protect from light)
form 
crystalline powder
color 
Off white to cream
InChI
InChI=1S/C7H5Br2I/c8-4-5-1-2-6(9)3-7(5)10/h1-3H,4H2
InChIKey
IHHHQROJDZQCQH-UHFFFAOYSA-N
SMILES
C1(CBr)=CC=C(Br)C=C1I
More
Less

Safety

HS Code 
2903998090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

More
Less

N-Bromosuccinimide Price

Apolloscientific
Product number
OR40663
Product name
4-Bromo-2-iodobenzylbromide
Purity
97%
Packaging
250mg
Price
$58
Updated
2021/12/16
SynQuest Laboratories
Product number
1700-S-03
Product name
4-Bromo-2-iodobenzyl bromide
Purity
97%
Packaging
250mg
Price
$64
Updated
2021/12/16
Apolloscientific
Product number
OR40663
Product name
4-Bromo-2-iodobenzylbromide
Purity
97%
Packaging
1g
Price
$160
Updated
2021/12/16
SynQuest Laboratories
Product number
1700-S-03
Product name
4-Bromo-2-iodobenzyl bromide
Purity
97%
Packaging
1g
Price
$176
Updated
2021/12/16
Apolloscientific
Product number
OR40663
Product name
4-Bromo-2-iodobenzylbromide
Purity
97%
Packaging
5g
Price
$472
Updated
2021/12/16
More
Less

4-Bromo-1-(bromomethyl)-2-iodobenzene, alpha,4-Dibromo-2-iodotoluene Chemical Properties,Usage,Production

Synthesis

260558-15-4

885681-96-9

General procedure for the synthesis of 4-bromo-1-(bromomethyl)-2-iodobenzene (15b) from 4-bromo-2-iodo-1-methylbenzene: 4-bromo-2-iodotoluene (3.94 g, 13.3 mmol) was dissolved in 1,2-dichloroethane (19 mL) under nitrogen protection in a 50 mL two-necked round-bottomed flask and stirred at room temperature. Benzoyl peroxide (164 mg, 0.663 mmol) and N-bromosuccinimide (NBS, 2.63 g, 14.6 mmol) were then added sequentially and the reaction mixture was heated to reflux for 5 hours. After completion of the reaction, it was cooled to room temperature, the precipitate was collected by filtration and washed with hexane. The filtrate was dried over anhydrous magnesium sulfate (MgSO4), filtered and concentrated under reduced pressure to give an orange solid. The solid was washed with cold methanol to give an off-white solid product (3.27 g, 8.75 mmol, 66% yield), which could be used for subsequent reactions without further purification. The structure of the product was confirmed by 1H-NMR (400 MHz, CDCl3): δ 8.01 (d, 1H, J = 2.0 Hz), 7.47 (dd, 1H, J = 8.3, 2.0 Hz), 7.33 (d, 1H, J = 8.3 Hz), 4.54 (s, 2H); High-resolution Mass Spectrometry (HRMS, EI) m/z calculated value C7H5Br2I [M+]: 377.7762, measured value: 377.7759.

References

[1] Patent: TW2016/9616, 2016, A. Location in patent: Paragraph 0162
[2] Journal of Organic Chemistry, 2011, vol. 76, # 7, p. 2227 - 2239
[3] Synthesis, 2011, # 15, p. 2387 - 2391
[4] Patent: WO2011/127383, 2011, A2. Location in patent: Page/Page column 74
[5] Angewandte Chemie - International Edition, 2014, vol. 53, # 7, p. 1841 - 1844

4-Bromo-1-(bromomethyl)-2-iodobenzene, alpha,4-Dibromo-2-iodotoluene Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

4-Bromo-1-(bromomethyl)-2-iodobenzene, alpha,4-Dibromo-2-iodotoluene Suppliers

China 51 India 2 United Kingdom 1 United States 3 Global 57
Shanghai Hongle Biotechnology Co., Ltd
Tel
021-56145923; 4001631568
Email
sales@honglebiotech.com
Country
China
ProdList
920
Advantage
58
Shanghai Jiezhen Pharmaceutical Technology Co., Ltd.
Tel
15995055116
Fax
815229059
Email
815229059@qq.com
Country
China
ProdList
142
Advantage
58
Shanghai Synmedia Chemical Co., Ltd.
Tel
021-38681880 13817889927
Fax
0213390-8196
Email
sales@synmedia-chem.com
Country
China
ProdList
249
Advantage
58
Jilin Chinese Academy of Sciences - Yanshen Technology Co., Ltd
Tel
0431-0431-80514535 19917294565
Email
et@chemextension.com
Country
China
ProdList
3936
Advantage
55
Shanghai SuperLan Chemcial Technique Centre
Tel
0-2022843681 15618226720
Fax
+86-21-51601218
Email
chaolaichem@foxmail.com
Country
China
ProdList
12475
Advantage
58
Shanghai Pingguo Pharmaceutical Co., Ltd.
Tel
021-20432229
Fax
QQ2412110556
Email
2412110556@qq.com
Country
China
ProdList
6017
Advantage
55
Zhengzhou Huiju Chemical Co., Ltd.
Tel
0371-55900031 18137872243
Fax
QQ：2853979815
Email
2853979815@qq.com
Country
China
ProdList
9996
Advantage
55
Jiaxing Deyi Chemical Co., Ltd.
Tel
86-0573-85866609 13325730825
Fax
0573-85866609
Email
945717149@qq.com
Country
China
ProdList
8595
Advantage
58
Aikon International Limited
Tel
025-58851090 15955137747
Fax
(6)02557626880
Email
sales01@aikonchem.com
Country
China
ProdList
15949
Advantage
58
Rhawn Reagent
Tel
400-400-1332688 18019345275
Fax
400-133-2688
Email
amy@rhawn.cn
Country
China
ProdList
14948
Advantage
58
Zhengzhou Ruke Biological Co., Ltd.
Tel
15981811963
Fax
QQ：1410472904
Email
1410472904@qq.com
Country
China
ProdList
5825
Advantage
58
Shanghai SPAR pharmaceutical technology co., LTD
Tel
021-000000
Email
admin@jingshipharmatech.com
Country
China
ProdList
9853
Advantage
58
Shanghai silk sail pharmaceutical technology co., LTD
Tel
18916696128
Email
service@snowpharm.com
Country
China
ProdList
1369
Advantage
58
Shanghai Union Medical Technology Co. Ltd.
Tel
13120563767
Fax
15669989863
Email
chemchen925@outlook.com
Country
China
ProdList
987
Advantage
58
Suzhou Rovathin Foreign Trade Co.,Ltd
Tel
0512-65816829 18662214788
Fax
0512-65816829
Email
info@rovathin.com.cn
Country
China
ProdList
9987
Advantage
58
Henan Lien Chemical Products Co., Ltd.
Tel
03716091-9097 13383857418
Fax
03716091-9097
Email
1520689222@qq.com
Country
China
ProdList
4862
Advantage
58
Henan Alfa Chemical Co., Ltd
Tel
+8615838112936
Email
alfa10@alfachem.cn
Country
China
ProdList
12921
Advantage
58
Shanghai Daeyeon Chemicals Co., Ltd
Tel
021-64478606 +8615900664856
Email
daeyeon001@vip.163.com
Country
China
ProdList
2062
Advantage
58
Hefei TNJ Chemical Industry Co.,Ltd.
Tel
+86-0551-65418684 +8618949823763
Fax
0086-551-65418684
Email
sales@tnjchem.com
Country
China
ProdList
25356
Advantage
58
Labnetwork lnc.
Tel
+86-27-50766799 +8618062016861
Email
contact@labnetwork.com
Country
China
ProdList
19987
Advantage
58
Jilin Chinese Academy of Sciences - Yanshen Technology Co., Ltd.
Tel
0431-80514535 13634302652
Fax
0431-88607838
Email
Extension@chemextension.com
Country
CHINA
ProdList
967
Advantage
58
Shanghai Jiange Chemical Co., Ltd.
Tel
15921040873
Email
1434142450@qq.com
Country
CHINA
ProdList
7649
Advantage
58
Zhengzhou Edward Biology Co.,Ltd
Tel
0371-63682289 15538176268
Fax
QQ：1875164801
Email
jacschem@163.com
Country
China
ProdList
9926
Advantage
58
Jurong Coupling Biotechnology Co., Ltd.
Tel
13656108824
Email
coupling278191416@hotmail.com
Country
CHINA
ProdList
184
Advantage
58
career henan chemical co
Tel
+86-0371-86658258 +8613203830695
Fax
0086-371-86658258
Email
factory@coreychem.com
Country
China
ProdList
29798
Advantage
58
Jilin Chinese Academy of Sciences - Yanshen Technology Co., Ltd
Tel
0431-80534350 15044023330
Email
caoy@chemextension.com
Country
China
ProdList
2016
Advantage
58
Nanjing Shizhou Biology Technology Co.,Ltd
Tel
025-025-85560043 17301488900
Fax
025-85563444
Email
info@synzest.com
Country
China
ProdList
9286
Advantage
58
Shanghai Fine Biotech Co.，Ltd
Tel
18717800556
Email
sales@finebiotech.com
Country
China
ProdList
2182
Advantage
58
Shanghai Hongju Pharmaceutical Technology Co., LTD
Tel
18001895509
Fax
QQ2934193566;
Email
986383309@qq.com
Country
China
ProdList
2680
Advantage
58
Shanghai Sunway Pharmaceutical Technology Co.,Ltd.
Tel
021-51816796-820 13611835272
Fax
021-5161 3951
Email
sales2@sunwaypharm.com
Country
China
ProdList
44119
Advantage
58
TCI (Shanghai) Chemical Trading Co., Ltd.
Tel
021-61109150
Fax
021-61105897
Email
sales@tcisct.com
Country
China
ProdList
29668
Advantage
58
Shanghai Haohong Pharmaceutical Co., Ltd.
Tel
400-8210725 4008210725
Email
malulu@leyan.com
Country
China
ProdList
40000
Advantage
58
Beijing Stronger Science Co., Ltd.
Tel
0531-88924771 15614660963
Email
elsa.hang@strongerscience.com
Country
China
ProdList
10623
Advantage
58
Hefei Mokai Pharmaceutical Technology Co., Ltd
Tel
18130062233
Email
3362556465@qq.com
Country
China
ProdList
8100
Advantage
58
Bide Pharmatech Ltd.
Tel
400-1647117 13681763483
Email
product02@bidepharm.com
Country
China
ProdList
59936
Advantage
58
Nanjing Shizhou Biology Technology Co.,Ltd
Tel
18351873721
Email
helen.zhang@synzest.com
Country
China
ProdList
8295
Advantage
58
Bide Pharmatech Ltd.
Tel
400-6005915
Email
sales@picasso-e.com
Country
China
ProdList
39665
Advantage
58
Huangshi Jingchi?Medicine?Co.,?Ltd
Tel
17771967576; 17771967576
Email
234107690@qq.com
Country
China
ProdList
609
Advantage
58
Shaanxi Xihua Chemical Industry Co., Ltd
Tel
029-029-81123119 17391733320
Email
1021@dideu.com
Country
China
ProdList
9989
Advantage
58
Shanghai Easy CDMO Co.,Ltd
Tel
021-61734564 13854185395;
Email
info@easycdmo.com
Country
China
ProdList
10024
Advantage
58
Beijing Solarbio Science & Tecnology Co., Ltd.
Tel
010-50973130 17801761073
Email
Gsiyu@solarbio.com
Country
China
ProdList
50464
Advantage
58
Hangzhou Bingochem Co., Ltd.
Tel
0571-8512-5372
Email
sales@bingochem.com
Country
China
ProdList
21669
Advantage
58
Biosynth Biological Technology (Suzhou) Co Ltd
Tel
51288865780
Email
sales@biosynth.com
Country
China
ProdList
6051
Advantage
58
Shanghai Dingshi Pharmaceutical Technology Co., Ltd
Tel
15921634331
Email
1509836518@qq.com
Country
China
ProdList
120
Advantage
58
Nanjing Xinmeihe Pharmaceutical Co., Ltd.
Tel
025-57672321 13739186949
Fax
025-57672123
Email
yuanming@huashineltd.com
Country
China
ProdList
424
Advantage
58
ATK CHEMICAL COMPANY LIMITED
Tel
+undefined-21-51877795
Fax
+86 21 5161 9052/ 5187 7796
Email
ivan@atkchemical.com
Country
China
ProdList
33024
Advantage
60
Compound Net Biotechnology Inc.
Tel
+8615303909093
Email
sales@compound-net.com
Country
China
ProdList
2914
Advantage
58
SUZHOU SENFEIDA CHEMICAL CO.,LTD
Tel
+86-0512-83500002 +8618662433356
Email
3899766280@qq.com
Country
China
ProdList
26362
Advantage
58
Jilin Chinese Academy of Sciences-yanshen Technology
Tel
+undefined18143011203
Email
info@chemextension.com
Country
China
ProdList
42056
Advantage
58
Coresyn Pharmatech Co., Ltd.
Tel
+86-571-86626709 +86-18157142896
Email
cbc@coresyn.com
Country
China
ProdList
9984
Advantage
58
More
Less

View Lastest Price from 4-Bromo-1-(bromomethyl)-2-iodobenzene, alpha,4-Dibromo-2-iodotoluene manufacturers

Career Henan Chemical Co
Product
4-Bromo-1-(bromomethyl)-2-iodobenzene, alpha,4-Dibromo-2-iodotoluene 885681-96-9
Price
US $9.80/KG
Min. Order
1g
Purity
≥99%
Supply Ability
100kg
Release date
2020-01-08

885681-96-9, 4-Bromo-1-(bromomethyl)-2-iodobenzene, alpha,4-Dibromo-2-iodotolueneRelated Search:

Silver iodide

  • 4-Bromo-1-(bromomethyl)-2-iodobenzene, alpha,4-Dibromo-2-iodotoluene
  • 4-Bromo-2-iodobenzyl bromide 97%
  • 4-Bromo-2-iodobenzylbromide97%
  • 4-Bromo-2-Iodobenzyl Bromide
  • 4-Bromo-1-(bromomethyl)-2-iodobenzene
  • Benzene, 4-bromo-1-(bromomethyl)-2-iodo-
  • 885681-96-9