BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE

Product Name: BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE
CAS No.: 37891-79-5
Chemical Name: BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE
Synonyms: BIS(METHYLTHIO)METHYLTRIMETHYLSILANE;TRIMETHYLBIS(METHYLTHIO)METHYLSILANE;BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE;Silane, [bis(methylthio)methyl]trimethyl-;Bis(methylthio)(trimethylsilyl)methane >Bis(methylthio)methyltrimethylsilane Trimethylbis(methylthio)methylsilane
CBNumber: CB3275106
Molecular Formula: C6H16S2Si
Formula Weight: 180.41
MOL File: 37891-79-5.mol

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BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE Property

Boiling point:: 82 °C(Press: 10.0 Torr)
Density: 0.941±0.06 g/cm3(Predicted)
refractive index: 1.5060-1.5100
solubility: insol H2O; sol organic solvents.
form: clear liquid
color: Colorless to Light yellow to Light orange

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Safety

HS Code: 2931.90.9010

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H227Combustible liquid

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical

Product number: B2004
Product name: Bis(methylthio)(trimethylsilyl)methane
Purity: >98.0%(GC)
Packaging: 1g
Price: $99
Updated: 2024/03/01

TRC

Product number: B102786
Product name: Bis(methylthio)(trimethylsilyl)methane
Packaging: 10mg
Price: $45
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB61175
Product name: Bis(methylthio)(trimethylsilyl)methane
Packaging: 250mg
Price: $100
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: ORS0001338
Product name: BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE
Purity: 95.00%
Packaging: 1G
Price: $257.46
Updated: 2021/12/16

AK Scientific

Product number: 7236AL
Product name: Bis(methylthio)(trimethylsilyl)methane
Packaging: 5g
Price: $664
Updated: 2021/12/16

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BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE Chemical Properties,Usage,Production

Physical properties

bp 67–70°C/10 mmHg.

Uses

Bis(methylthio)(trimethylsilyl)methane is a reagent used for synthesis of bis(methylthio)ketene acetals from aldehydes and ketones;acyl anion synthon for conjugate additions to enones and enoates;useful for one-carbon homologations.
The bis(methylthio)ketene acetals are useful synthetic intermediates because they are readily converted into S-methyl thioesters (eq 9) or the corresponding carboxylic acids and esters.

Preparation

prepared from lithiobis(methylthio)- methane by silylation with chlorotrimethylsilane (eq 1).Both bis(methylthio)methane and chlorotrimethylsilane are commercially available.

BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE Preparation Products And Raw materials

Raw materials

Preparation Products

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BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE Suppliers

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37891-79-5, BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANERelated Search:

BIS(TRIMETHYLSILYL) SULFIDE 2-(TRIISOPROPYLSILYL)-1 3-DITHIANE 97 BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE 2-(TERT-BUTYLDIMETHYLSILYL)-1,3-DITHIANE 2-TRIMETHYLSILYL-1,3-DITHIANE DIMETHYL-[3-(2-TRIMETHYLSILANYL-[1,3]DITHIAN-2-YL)-PROPYL]-AMINE

TRIMETHYLBIS(METHYLTHIO)METHYLSILANE

Bis(methylthio)methyltrimethylsilane Trimethylbis(methylthio)methylsilane

BIS(METHYLTHIO)METHYLTRIMETHYLSILANE

BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE

Bis(methylthio)(trimethylsilyl)methane &gt

Silane, [bis(methylthio)methyl]trimethyl-

37891-79-5

C6H16S2Si

Si-(C)4 Compounds

Si (Classes of Silicon Compounds)

Silicon Compounds (for Synthesis)

Sulfur Compounds (for Synthesis)

Si (Classes of Silicon Compounds)

Si-(C)4 Compounds

Silicon Compounds (for Synthesis)

Sulfur Compounds (for Synthesis)

Synthetic Organic Chemistry