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MANGANESE (III) OXIDE

Product Name
MANGANESE (III) OXIDE
CAS No.
1317-34-6
Chemical Name
MANGANESE (III) OXIDE
Synonyms
manganicoxide;manganesetrioxide;manganese(3+)oxide;manganesemanganate;dimanganesetrioxide;manganesesisquioxide;MANGANESE SESQUIOXIDE;MANGANESE (III) OXIDE;manganeseoxide(mn2o3);Manganese(III)oxide,99%
CBNumber
CB3275540
Molecular Formula
Mn2O3
Formula Weight
157.87
MOL File
1317-34-6.mol
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MANGANESE (III) OXIDE Property

Melting point:
1080°C (dec.)
Density 
4.5 g/mL at 25 °C(lit.)
solubility 
insoluble in H2O
form 
Powder
color 
Black
Specific Gravity
4.5
Water Solubility 
Soluble in acid and ammonium chloride. Insoluble in water, alcohol and acetone.
Merck 
14,5737
Exposure limits
ACGIH: TWA 0.02 mg/m3; TWA 0.1 mg/m3
OSHA: Ceiling 5 mg/m3
NIOSH: IDLH 500 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3
InChIKey
GEYXPJBPASPPLI-UHFFFAOYSA-N
CAS DataBase Reference
1317-34-6(CAS DataBase Reference)
EPA Substance Registry System
Manganese(III) oxide (1317-34-6)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
RTECS 
OP0915000
TSCA 
Yes
Toxicity
mouse,LD50,subcutaneous,616mg/kg (616mg/kg),Zhurnal Vsesoyuznogo Khimicheskogo Obshchestva im. D.I. Mendeleeva. Journal of the D.I. Mendeleeva All-Union Chemical Society. Vol. 19, Pg. 186, 1974.
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
377457
Product name
Manganese(III) oxide
Purity
325 mesh, 99%
Packaging
250g
Price
$152
Updated
2024/03/01
Sigma-Aldrich
Product number
377457
Product name
Manganese(III) oxide
Purity
325 mesh, 99%
Packaging
1kg
Price
$472
Updated
2024/03/01
Alfa Aesar
Product number
087791
Product name
Manganese(III) oxide, 98%
Packaging
500g
Price
$174
Updated
2024/03/01
Alfa Aesar
Product number
087791
Product name
Manganese(III) oxide, 98%
Packaging
2kg
Price
$658
Updated
2024/03/01
Strem Chemicals
Product number
93-2522
Product name
Manganese(III) oxide, 99%
Packaging
250g
Price
$92
Updated
2024/03/01
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MANGANESE (III) OXIDE Chemical Properties,Usage,Production

Chemical Properties

manganese(III) oxide is a black, lustrous powder, sometimes tinged brown. Very hard.decomposes at 1080℃. Soluble in cold hydrochloric acid; not soluble in nitric acid (decomposes), hot sulfuric acid; insoluble in water. Noncombustible.

manganese(III) oxide is obtained by igniting manganese(IV) oxide or a manganese(II) salt in air at 800°C. It reacts slowly with cold dilute acids to form manganese(III) salts. Manganese(III) oxide occurs in nature as braunite (3Mn2O3.MnSiO3 ) and the monohydrate (Mn2O 3.H2O) occurs in the mineral manganite. The manganese(III) oxide crystal lattice contains Mn3+ and O2– ions. With concentrated alkalis, it undergoes disproportionation to give manganese(II) and manganese(IV) ions.

Uses

Manganese(III) oxide is used to produce ceramic magnets and semiconductors. Further, it serves as a precursor to lithium manganese oxide. In addition to this, it acts as a useful battery cathode.

Definition

In nature as manganite, a manganese ore.

Preparation

Anhydrous manganese(III) oxide is found as the mineral braunite, Mn2O3, while a hydrated form, Mn2O3.H2O, which is chemically more reactive, occurs as manganite. Manganese forms both anions and cations in oxidation state +3. Simple salts of tervalent manganese are not stable. However, complexes are more stable, the hexacyanomanganates(III) being an example: K3Mn(CN)6 is a red crystalline solid, isomorphous with potassium hexacyanoferrate(III) and slowly hydrolysed.
Manganese(III) oxide is formed as a grey solid by heating manganese(IV) oxide to 700°C for several hours:
4MnO2 ---> 2Mn203 + O2
It is converted into trimanganese tetroxide when heated above 940°C in air or reduced by hydrogen above 230°C. Hot concentrated hydrochloric acid is oxidized to chlorine by manganese(III) oxide:
Mn203 (s) + 6H + + 2e- ==2Mn2+ + 3H2O
Mn203 (s) + 6H + + 2Cl- ---> 2Mn2+ + 3H2O + Cl2

Hazard

Flammable in finely divided form. Toxic by inhalation of dust.

Flammability and Explosibility

Not classified

Safety Profile

Moderately toxic by subcutaneous and intratracheal routes. See also MANGANESE COMPOUNDS.

MANGANESE (III) OXIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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MANGANESE (III) OXIDE Suppliers

Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
4008-755-333 18080918076
Fax
028-86757656
Email
800078821@qq.com
Country
China
ProdList
9718
Advantage
55
Hubei Wande Chemical Co., Ltd
Tel
027-59210159 15377098680
Fax
027-59210159
Email
1148280011@qq.com
Country
China
ProdList
9965
Advantage
58
Fubang Jiaxin Technology Co., Ltd
Tel
19207487233 18823293917
Email
3574468540@qq.com
Country
China
ProdList
20
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15839
Advantage
69
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8415
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18738
Advantage
57
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View Lastest Price from MANGANESE (III) OXIDE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
Manganese(III) oxide 1317-34-6
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
10000KG
Release date
2024-09-04
Shanghai CRM New Material Technology Co., LTD
Product
Manganese(III) oxide 1317-34-6
Price
US $10.00-15.00/g
Min. Order
10g
Purity
99%
Supply Ability
2546245
Release date
2022-11-07
Career Henan Chemical Co
Product
MANGANESE (III) OXIDE 1317-34-6
Price
US $1.00/KG
Min. Order
1KG
Purity
85.0-99.8%
Supply Ability
200kg
Release date
2019-08-30

1317-34-6, MANGANESE (III) OXIDERelated Search:


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