GALLIUM(III) CHLORIDE

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GALLIUM(III) CHLORIDE

Product Name: GALLIUM(III) CHLORIDE
CAS No.: 13450-90-3
Chemical Name: GALLIUM(III) CHLORIDE
Synonyms: GaCl3;Nsc94002;granular;Wln: ga G3;gallium(iii);ium(III) chL;Trichlorogallium;GALLIUM CHLORIDE;trichlorogallane;Galliumtrichlorid
CBNumber: CB3275575
Molecular Formula: Cl3Ga
Formula Weight: 176.08
MOL File: 13450-90-3.mol

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GALLIUM(III) CHLORIDE Property

Melting point:: 78 °C(lit.)
Boiling point:: 35 °C
Density: 2.47 g/mL at 25 °C(lit.)
vapor pressure: 1 mm Hg ( 48 °C)
Flash point:: −26 °F
form: beads
color: White
Specific Gravity: 2.47
Water Solubility: Very soluble in water. Soluble in benzene, carbon tetrachloride and carbon disulfide
Sensitive: Moisture Sensitive
Merck: 14,4348
Stability:: Stability Stable, but reacts violently with water.
InChIKey: UPWPDUACHOATKO-UHFFFAOYSA-K
CAS DataBase Reference: 13450-90-3(CAS DataBase Reference)
EPA Substance Registry System: Gallium trichloride (13450-90-3)

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Safety

Hazard Codes: C,N,F+
Risk Statements: 14-34-51/53-12-67-65
Safety Statements: 26-27-28-36/37/39-45-61-33-29-16-62
RIDADR: UN 3260 8/PG 2
WGK Germany: 3
RTECS: LW9100000
F: 3-10
TSCA: Yes
HazardClass: 8
PackingGroup: II
HS Code: 28273990
Hazardous Substances Data: 13450-90-3(Hazardous Substances Data)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

TCI Chemical

Product number: G0359
Product name: Gallium(III) Chloride Anhydrous
Purity: >98.0%
Packaging: 5g
Price: $52
Updated: 2024/03/01

TCI Chemical

Product number: G0359
Product name: Gallium(III) Chloride Anhydrous
Purity: >98.0%
Packaging: 25g
Price: $149
Updated: 2024/03/01

Alfa Aesar

Product number: 035698
Product name: Gallium(III) chloride, ultra dry, 99.999% (metals basis)
Packaging: 25g
Price: $136
Updated: 2021/12/16

Alfa Aesar

Product number: 035698
Product name: Gallium(III) chloride, ultra dry, 99.999% (metals basis)
Packaging: 5g
Price: $50.2
Updated: 2021/12/16

Strem Chemicals

Product number: 93-3140
Product name: Gallium(III) chloride, anhydrous, granular (99.999%-Ga) PURATREM
Packaging: 5g
Price: $48
Updated: 2024/03/01

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GALLIUM(III) CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

white crystals or powder

Chemical Properties

Gallium trichloride is a colorless solid which forms needle-like crystals. Acidic odor.

Uses

Gallium(III) chloride is a catalyst for a number of transformations including the ring opening and recyclization of epoxides and the trimerization of alkynes. It is used to detect the solar neutrions.

Uses

Lewis acid catalyst in organic synthesis; reagent for generating organogallium compounds, metallic gallium, and gallium semiconductors.

Production Methods

The trichloride salt of trivalent gallium is prepared by the action of either hydrogen chloride or chlorine on the metal.

General Description

Colorless needles. Used as a raw material in the production of metallic gallium and in the processing of mono crystal semiconductor compounds.

Air & Water Reactions

Water soluble.

Reactivity Profile

GALLIUM(III) CHLORIDE acts as a weak inorganic acid. Materials in this group are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.

Health Hazard

(Non-Specific -- Gallium Compounds) In view of the toxicity of gallium and its compounds, as shown by experiments, all persons involved in work with these substances should undergo periodic medical examinations, during which special attention should be paid to the condition of the liver, respiratory organs, and skin.

Fire Hazard

Emits toxic chloride fumes when heated to decomposition. Decomposes upon sufficient heating.

reaction suitability

reagent type: catalyst
core: gallium

Potential Exposure

Used as a raw material in the produc tion of metallic gallium; and in the processing of mono crystal, semiconductor compounds.

Shipping

UN3260 Corrosive solid, acidic, inorganic, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required. UN1759 Corrosive solids, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name required.

Purification Methods

The pure compound can be obtained by redistillation in a stream of Cl2 or Cl2/N2 followed by vacuum sublimation or zone refining. It forms colourless needles which give gallium dichloride [Ga(GaCl4), m 172.4o] on heating. It dissolves in H2O with liberation of heat. It is soluble in Et2O and can be extracted from an HCl solution with Et2O. [Laubengayer & Schirmer J Am Chem Soc 62 1579 1940, D.nges in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 846 1963.]

GALLIUM(III) CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from GALLIUM(III) CHLORIDE manufacturers

Hebei Mujin Biotechnology Co.,Ltd

Product: GALLIUM(III) CHLORIDE 13450-90-3
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-10-08

Hebei Yanxi Chemical Co., Ltd.

Product: GALLIUM(III) CHLORIDE 13450-90-3
Price: US $30.00-10.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 30 tons
Release date: 2023-11-03

Shaanxi Dideu Medichem Co. Ltd

Product: Gallium Trichloride 13450-90-3
Price: US $0.10/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 1000Tons
Release date: 2024-08-21

13450-90-3, GALLIUM(III) CHLORIDERelated Search:

GALLIUM (II) CHLORIDE Gallium INDIUM(III) CHLORIDE TETRAHYDRATE TRIETHYLGALLIUM GALLIUM PHOSPHIDE GALLIUM(III) 2,4-PENTANEDIONATE Gallium arsenide GALLIUM(III) NITRATE HYDRATE GALLIUM(III) BROMIDE GALLIUM(III) TRIFLUOROMETHANESULFONATE TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)GALLIUM(III) GALLIUM(III) SULFATE HYDRATE TRIMETHYLGALLIUM Gallium(III) oxide Thulium chloride Silver chloride Bismuth trichloride POLYETHYLENE, CHLORINATED

gallium(iii)

galliumchloride(gacl3)

galliumchloride[qr]

Trichlorogallium

Galliumchlorideanhydrouswhitefusedlump

GALLIUM(III) CHLORIDE, ANHYDROUS, BEADS, -10 MESH, 99.99%

GALLIUM(III) CHLORIDE, 99.99+%

GALLIUM(III) CHLORIDE, ANHYDROUS, BEADS, -10 MESH, 99.999+%

GALLIUM CHLORIDE, 0.5M SOLUTION IN PENTANE

GALLIUM CHLORIDE, ANHYDROUS, 99.9%

GALLIUM(III) CHLORIDE, ANHYDROUS LUMP: (99.999% GA)

Gallium(III)chloride,anhydrous,granular(99.999%-Ga)PURATREM

Gallium(III)chloride,anhydrouslump(99.999%-Ga)PURATREM

gallium(iii) chloride solution

gallium(iii) chloride, ultra dry

Gallium(III) Chloride, Anhydrous

GalliuM trchloride

"Gallium(III) chloride, anhydrous/ 99.999%"

Gallium(III) chloride anhydrouss

GalliuM(III) chloride, 99.99+%, (trace Metal basis), anhydrous, beads, -10 Mesh

GalliuM(III) chloride nonahydarate

GalliuM(III) chloride, anhydrous, fused luMp (99.999%-Ga) PURATREM

GalliuM chloride(GaCl<sub>3</sub>)

GalliuM(III) chloride anhydrous, beads, -10 Mesh, 99.99% trace Metals basis

GalliuM(III) chloride beads, anhydrous, >=99.999% trace Metals basis

GALLIUM(III) CHLORID

Gallium(III) chloride solution 0.5 M in pentane

GALLIUM TRICHLORIDE

GALLIUM(III) CHLORIDE

GALLIUM CHLORIDE

GALLIUM(+3)CHLORIDE

GaCl3

Gallium chloride (GaCl3)

Gallium(III) chloride, ultra dry, 99.999% (metals basis)

Gallium(III) chloride, anhydrous lump

Nsc94002

Wln: ga G3

Gallium trichloride, 99.99%

granular

GalliuM(III) chloride, anhydrous, granular

Gallium(III) chloride, anhydrous, ampuled under argon, 99.999% trace metals basis

metel basisGallium(III chloride

ium(III) chL

Gallium(Ⅲ) Chloride, 99.9%

Gallium(III) chloride, puriss, 99.999%

Gallium(III) chloride, puriss

trichlorogallane

Gallium(III) Chloride(Granules)

Galliumtrichlorid

13450-90-3

Cl3Ga

Catalysis and Inorganic Chemistry

Gallium

metal halide

Crystal Grade Inorganics

Catalysis and Inorganic Chemistry

Chemical Synthesis

Gallium Salts