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GALLIUM(III) CHLORIDE

Product Name
GALLIUM(III) CHLORIDE
CAS No.
13450-90-3
Chemical Name
GALLIUM(III) CHLORIDE
Synonyms
GaCl3;Nsc94002;granular;Wln: ga G3;gallium(iii);ium(III) chL;Trichlorogallium;GALLIUM CHLORIDE;trichlorogallane;GalliuM trchloride
CBNumber
CB3275575
Molecular Formula
Cl3Ga
Formula Weight
176.08
MOL File
13450-90-3.mol
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GALLIUM(III) CHLORIDE Property

Melting point:
78 °C(lit.)
Boiling point:
35 °C
Density 
2.47 g/mL at 25 °C(lit.)
vapor pressure 
1 mm Hg ( 48 °C)
Flash point:
−26 °F
form 
beads
color 
White
Specific Gravity
2.47
Water Solubility 
Very soluble in water. Soluble in benzene, carbon tetrachloride and carbon disulfide
Sensitive 
Moisture Sensitive
Merck 
14,4348
Stability:
Stability Stable, but reacts violently with water.
InChIKey
UPWPDUACHOATKO-UHFFFAOYSA-K
CAS DataBase Reference
13450-90-3(CAS DataBase Reference)
EPA Substance Registry System
Gallium trichloride (13450-90-3)
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Safety

Hazard Codes 
C,N,F+
Risk Statements 
14-34-51/53-12-67-65
Safety Statements 
26-27-28-36/37/39-45-61-33-29-16-62
RIDADR 
UN 3260 8/PG 2
WGK Germany 
3
RTECS 
LW9100000
3-10
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
28273990
Hazardous Substances Data
13450-90-3(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

TCI Chemical
Product number
G0359
Product name
Gallium(III) Chloride Anhydrous
Purity
>98.0%
Packaging
5g
Price
$52
Updated
2024/03/01
TCI Chemical
Product number
G0359
Product name
Gallium(III) Chloride Anhydrous
Purity
>98.0%
Packaging
25g
Price
$149
Updated
2024/03/01
Alfa Aesar
Product number
035698
Product name
Gallium(III) chloride, ultra dry, 99.999% (metals basis)
Packaging
25g
Price
$136
Updated
2021/12/16
Alfa Aesar
Product number
035698
Product name
Gallium(III) chloride, ultra dry, 99.999% (metals basis)
Packaging
5g
Price
$50.2
Updated
2021/12/16
Strem Chemicals
Product number
93-3140
Product name
Gallium(III) chloride, anhydrous, granular (99.999%-Ga) PURATREM
Packaging
5g
Price
$48
Updated
2024/03/01
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GALLIUM(III) CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

white crystals or powder

Chemical Properties

Gallium trichloride is a colorless solid which forms needle-like crystals. Acidic odor.

Uses

Gallium(III) chloride is a catalyst for a number of transformations including the ring opening and recyclization of epoxides and the trimerization of alkynes. It is used to detect the solar neutrions.

Uses

Lewis acid catalyst in organic synthesis; reagent for generating organogallium compounds, metallic gallium, and gallium semiconductors.

Production Methods

The trichloride salt of trivalent gallium is prepared by the action of either hydrogen chloride or chlorine on the metal.

General Description

Colorless needles. Used as a raw material in the production of metallic gallium and in the processing of mono crystal semiconductor compounds.

Air & Water Reactions

Water soluble.

Reactivity Profile

GALLIUM(III) CHLORIDE acts as a weak inorganic acid. Materials in this group are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.

Health Hazard

(Non-Specific -- Gallium Compounds) In view of the toxicity of gallium and its compounds, as shown by experiments, all persons involved in work with these substances should undergo periodic medical examinations, during which special attention should be paid to the condition of the liver, respiratory organs, and skin.

Fire Hazard

Emits toxic chloride fumes when heated to decomposition. Decomposes upon sufficient heating.

Potential Exposure

Used as a raw material in the produc tion of metallic gallium; and in the processing of mono crystal, semiconductor compounds.

Shipping

UN3260 Corrosive solid, acidic, inorganic, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required. UN1759 Corrosive solids, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name required.

Purification Methods

The pure compound can be obtained by redistillation in a stream of Cl2 or Cl2/N2 followed by vacuum sublimation or zone refining. It forms colourless needles which give gallium dichloride [Ga(GaCl4), m 172.4o] on heating. It dissolves in H2O with liberation of heat. It is soluble in Et2O and can be extracted from an HCl solution with Et2O. [Laubengayer & Schirmer J Am Chem Soc 62 1579 1940, D.nges in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 846 1963.]

GALLIUM(III) CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from GALLIUM(III) CHLORIDE manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
GALLIUM(III) CHLORIDE 13450-90-3
Price
US $30.00-10.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
30 tons
Release date
2023-11-03
Hebei Mojin Biotechnology Co., Ltd
Product
GALLIUM(III) CHLORIDE 13450-90-3
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-10-08
Hebei Best Biological Technology Co., Ltd
Product
Gallium trichloride 13450-90-3
Price
US $200.00/g
Min. Order
10g
Purity
99%
Supply Ability
1000t/month
Release date
2023-06-07

13450-90-3, GALLIUM(III) CHLORIDERelated Search:


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