ChemicalBook > CAS DataBase List > 4-(TRIFLUOROMETHOXY)BENZYLAMINE

4-(TRIFLUOROMETHOXY)BENZYLAMINE

Product Name
4-(TRIFLUOROMETHOXY)BENZYLAMINE
CAS No.
93919-56-3
Chemical Name
4-(TRIFLUOROMETHOXY)BENZYLAMINE
Synonyms
RARECHEM AL BW 0449;P-TRIFLUOROMETHOXYBENZYL AMINE;4-trifluoromethoxylbenzylamine;4-(TRIFLUOROMETHOXY)BENZYLAMINE;4-(Trifluoromethoxy)benzylamine97%;4-(Trifluoromethoxy)benzylamine 97%;P-(TrifluoroMethoxy)benzeneMethanaMine;4-(Trifluoromethoxy)benzenemethanamine;[4-(Trifluoromethoxy)phenyl]methylamine;Benzenemethanamine, 4-(trifluoromethoxy)-
CBNumber
CB3277524
Molecular Formula
C8H8F3NO
Formula Weight
191.15
MOL File
93919-56-3.mol
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4-(TRIFLUOROMETHOXY)BENZYLAMINE Property

Boiling point:
57-60 °C10 mm Hg(lit.)
Density 
1.252 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.452(lit.)
Flash point:
172 °F
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
pka
8.75±0.10(Predicted)
form 
Liquid
Specific Gravity
1.252
color 
Clear colorless to light yellow
Sensitive 
Air Sensitive
BRN 
8200624
CAS DataBase Reference
93919-56-3(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,C
Risk Statements 
36/37/38
Safety Statements 
26-36/37/39-37/39
RIDADR 
UN2735
WGK Germany 
3
Hazard Note 
Corrosive
HazardClass 
8
PackingGroup 
III
HS Code 
29222990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
340987
Product name
4-(Trifluoromethoxy)benzylamine
Purity
95%
Packaging
1g
Price
$41.13
Updated
2025/07/31
TRC
Product number
T895935
Product name
p-Trifluoromethoxybenzylamine
Packaging
50g
Price
$100
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0022375
Product name
4-(TRIFLUOROMETHOXY)BENZYLAMINE
Purity
95.00%
Packaging
5G
Price
$779.63
Updated
2021/12/16
SynQuest Laboratories
Product number
4630-3-54
Product name
4-(Trifluoromethoxy)benzylamine
Purity
97%
Packaging
25g
Price
$95
Updated
2021/12/16
AK Scientific
Product number
J54026
Product name
4-(Trifluoromethoxy)benzylamine
Packaging
25g
Price
$40
Updated
2021/12/16
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4-(TRIFLUOROMETHOXY)BENZYLAMINE Chemical Properties,Usage,Production

Chemical Properties

clear colorless to light yellow liquid

Uses

4-(Trifluoromethoxy)benzylamine may be used in chemical synthesis.

Synthesis

332-25-2

93919-56-3

A tetrahydrofuran (30 mL) solution of 4-(trifluoromethoxy)benzyl cyanide (5.0 g, 26.72 mmol) was slowly added dropwise to a tetrahydrofuran (30 mL) solution of lithium aluminum tetrahydroxide (3.0 g, 88.44 mmol) at 0 °C. After the dropwise addition was completed, the reaction mixture was warmed to room temperature and stirred for 3 hours. Upon completion of the reaction, the mixture was cooled to 4 °C and diluted with tetrahydrofuran (50 mL). Subsequently, the reaction was quenched by sequentially adding water (3 mL), 15% sodium hydroxide solution (3 mL) and water (3 mL). After quenching, the mixture was stirred at room temperature for 15 minutes. The mixture was filtered through diatomaceous earth and the filtrate was dried with anhydrous magnesium sulfate. Finally, the filtrate was concentrated under reduced pressure to give 4-(trifluoromethoxy)benzylamine (3.1 g, 61% yield).

References

[1] Patent: WO2017/139414, 2017, A1. Location in patent: Paragraph 00215-00216

4-(TRIFLUOROMETHOXY)BENZYLAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-(TRIFLUOROMETHOXY)BENZYLAMINE Suppliers

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View Lastest Price from 4-(TRIFLUOROMETHOXY)BENZYLAMINE manufacturers

Career Henan Chemical Co
Product
4-(TRIFLUOROMETHOXY)BENZYLAMINE 93919-56-3
Price
US $3.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
200KG
Release date
2020-01-09

93919-56-3, 4-(TRIFLUOROMETHOXY)BENZYLAMINERelated Search:


  • 4-(TRIFLUOROMETHOXY)BENZYLAMINE
  • 1-[4-(TRIFLUOROMETHOXY)PHENYL]METHANAMINE
  • P-TRIFLUOROMETHOXYBENZYL AMINE
  • RARECHEM AL BW 0449
  • 4-(Trifluoromethoxy)benzylamine 97%
  • 4-(Trifluoromethoxy)benzylamine97%
  • [4-(Trifluoromethoxy)phenyl]methylamine
  • 4-(Trifluoromethoxy)benzenemethanamine
  • [4-(Trifluoromethoxy)phenyl]methylamine, 4-(Aminomethyl)-alpha,alpha,alpha-trifluoroanisole
  • P-(TrifluoroMethoxy)benzeneMethanaMine
  • Benzenemethanamine, 4-(trifluoromethoxy)-
  • 4-trifluoromethoxylbenzylamine
  • 93919-56-3
  • CF3OC6H4CH2NH2
  • C8H9F3NO
  • Amines
  • Building Blocks
  • C8
  • AMINE
  • Nitrogen Compounds
  • Organic Building Blocks
  • Fluorine series
  • Amine
  • Amines
  • C8
  • Nitrogen Compounds