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ChemicalBook > CAS DataBase List > (R,R)-2,2'-(2,6-PYRIDINEDIYL)BIS(4-ISOPROPYL-2-OXAZOLINE)

(R,R)-2,2'-(2,6-PYRIDINEDIYL)BIS(4-ISOPROPYL-2-OXAZOLINE)

Reaction
Product Name
(R,R)-2,2'-(2,6-PYRIDINEDIYL)BIS(4-ISOPROPYL-2-OXAZOLINE)
CAS No.
131864-67-0
Chemical Name
(R,R)-2,2'-(2,6-PYRIDINEDIYL)BIS(4-ISOPROPYL-2-OXAZOLINE)
Synonyms
(R,R)-iPr-Pybox;2,6-bis((4R)-(+)-isopropyl-2-oxazolin-2-yl)pyridi;2,6-Bis[(4R)-4-isopropyl-2-oxazolin-2-yl]pyridine;(R,R)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE;2,6-BIS[(4R)-(+)-ISOPROPYL-2-OXAZOLIN-2-YL]PYRIDINE;(R,R)-2,2'-(2,6-PYRIDINEDIYL)BIS(4-ISOPROPYL-2-OXAZOL;(+)-2,6-BIS[(4R)-4-(I-PROPYL)-2-OXAZOLIN-2-YL]PYRIDINE;(R,R)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine >(+)-2,6-Bis[(4R)-4-(i-propyl)-2-oxazolin-2-yl]pyridine;2,6-Bis[(4R)-(+)-isopropyl-2-oxazolin-2-yl]pyridine 99%
CBNumber
CB3295021
Molecular Formula
C17H23N3O2
Formula Weight
301.38
MOL File
131864-67-0.mol
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(R,R)-2,2'-(2,6-PYRIDINEDIYL)BIS(4-ISOPROPYL-2-OXAZOLINE) Property

Melting point:
154-156 °C(lit.)
alpha 
+118° (c 1.0, CH2Cl2)
Boiling point:
457.1±30.0 °C(Predicted)
Density 
1.23±0.1 g/cm3(Predicted)
refractive index 
118 ° (C=1, CH2Cl2)
storage temp. 
Inert atmosphere,Room Temperature
form 
crystal
pka
3.78±0.70(Predicted)
color 
white
optical activity
[α]20/D +118°, c = 0.7 in methylene chloride
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
29349990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
477494
Product name
2,6-Bis[(4R)-(+)-isopropyl-2-oxazolin-2-yl]pyridine
Purity
99%
Packaging
250mg
Price
$92.7
Updated
2024/03/01
Sigma-Aldrich
Product number
477494
Product name
2,6-Bis[(4R)-(+)-isopropyl-2-oxazolin-2-yl]pyridine
Purity
99%
Packaging
1g
Price
$352
Updated
2024/03/01
TCI Chemical
Product number
B2217
Product name
(R,R)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine
Purity
>98.0%(GC)
Packaging
1g
Price
$188
Updated
2024/03/01
TCI Chemical
Product number
B2217
Product name
(R,R)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine
Purity
>98.0%(GC)
Packaging
5g
Price
$669
Updated
2024/03/01
Strem Chemicals
Product number
07-1365
Product name
(R,R)-2,2'-(2,6-PYRIDINEDIYL)BIS(4-ISOPROPYL-2-OXAZOLINE)
Packaging
1g
Price
$91
Updated
2024/03/01
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(R,R)-2,2'-(2,6-PYRIDINEDIYL)BIS(4-ISOPROPYL-2-OXAZOLINE) Chemical Properties,Usage,Production

Reaction

  1. Ligand for enantioselective nitrone cycloaddition to α,β-unsaturated 2-acyl imidazoles.
  2. Highly efficient catalytic enantioselective Mannich reaction of malonates with N-tert-butoxycarbonyl imines.

Chemical Properties

White powder

Uses

C2 symmetric ligand for enantioselective catalysis. Easily forms bidentate coordination complexes due to the strong affinity of the oxazoline nitrogen for various metals.

(R,R)-2,2'-(2,6-PYRIDINEDIYL)BIS(4-ISOPROPYL-2-OXAZOLINE) Preparation Products And Raw materials

Raw materials

Preparation Products

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(R,R)-2,2'-(2,6-PYRIDINEDIYL)BIS(4-ISOPROPYL-2-OXAZOLINE) Suppliers

Tianjin Derchemist Science & Technology Co., Ltd.
Tel
22-58627059 13920586291
Fax
022-58620305
Email
zdcomcon@126.com
Country
China
ProdList
3461
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50
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
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Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
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62
TCI (Shanghai) Development Co., Ltd.
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021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
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Energy Chemical
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021-021-58432009 400-005-6266
Fax
021-58436166
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sales8178@energy-chemical.com
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China
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Nanjing Habo Medical Technology Co., Ltd.
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025-85760892 13376090521
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025-85766769
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sales@habotech.com
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China
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Shanghai Longsheng chemical Co.,Ltd.
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021-58099652-8005 13585536065
Fax
021-58099609
Email
bin.wu@shlschem.com
Country
China
ProdList
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HuiFeiChem(WuXi) PharmaTech Co.,Ltd
Tel
0510-0510-83593305
Fax
0086-510-83593305
Email
sales@huifeichem.com
Country
China
ProdList
104
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Daicel Chiral Technologies (China)CO.,LTD
Tel
021-50460086-9 15921403865
Fax
+86-21-50462321
Email
han_yajun@dctc.daicel.com
Country
China
ProdList
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Suzhou Guide Fine Material Co.Ltd.
Tel
136-16210669 13914021065
Fax
0512-66627360
Email
sales@guide-chemicals.com
Country
China
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271
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View Lastest Price from (R,R)-2,2'-(2,6-PYRIDINEDIYL)BIS(4-ISOPROPYL-2-OXAZOLINE) manufacturers

Hebei Mojin Biotechnology Co.,Ltd
Product
(R,R)-2,2'-(2,6-PYRIDINEDIYL)BIS(4-ISOPROPYL-2-OXAZOLINE) 131864-67-0
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
50000KG/month
Release date
2024-08-12
Zhuozhou Wenxi import and Export Co., Ltd
Product
(R,R)-2,2"-(2,6-PYRIDINEDIYL)BIS(4-ISOPROPYL-2-OXAZOLINE) 131864-67-0
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27

131864-67-0, (R,R)-2,2'-(2,6-PYRIDINEDIYL)BIS(4-ISOPROPYL-2-OXAZOLINE)Related Search:


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  • 131864-67-0
  • PyBOX
  • Privileged Ligands
  • Asymmetric Synthesis
  • Chiral Catalysts, Ligands, and Reagents
  • organic amine
  • BOX series
  • Chiral Nitrogen
  • Chiral Catalysts, Ligands, and Reagents
  • Privileged Ligands and Complexes
  • PyBOX
  • Asymmetric Synthesis
  • Synthetic Organic Chemistry