(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE

Reaction

Product Name: (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE
CAS No.: 118949-61-4
Chemical Name: (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE
Synonyms: 2,6-Bis((S);(S,S)-iPr-Pybox;-4-isopropyl-4,5-dihydrooxazol-2-yl);2,6-Bis[(4S)-4-isopropyl-2-oxazolin-2-yl]pyridine;(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE;2,6-BIS[(4S)-(-)-ISOPROPYL-2-OXAZOLIN-2-YL]PYRIDINE;(-)-2,6-BIS[(4S)-4-(I-PROPYL)-2-OXAZOLIN-2-YL]PYRIDINE;(S,S)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine >(-)-2,6-Bis[(4S)-4-(i-propyl)-2-oxazolin-2-yl]pyridine;2,6-Bis[(4S)-(-)-isopropyl-2-oxazolin-2-yl]pyridine 99%
CBNumber: CB7298752
Molecular Formula: C17H23N3O2
Formula Weight: 301.38
MOL File: 118949-61-4.mol

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(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE Property

Melting point:: 155-157 °C(lit.)
alpha: -120° (c 1.0, CH2Cl2)
Boiling point:: 457.1±30.0 °C(Predicted)
Density: 1.23±0.1 g/cm3(Predicted)
storage temp.: Inert atmosphere,2-8°C
pka: 3.78±0.70(Predicted)
form: crystal
color: white
optical activity: [α]25/D 118°, c = 0.7 in methylene chloride
BRN: 5824976

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
HS Code: 29309090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 407151
Product name: 2,6-Bis[(4S)-(?)-isopropyl-2-oxazolin-2-yl]pyridine
Purity: 99%
Packaging: 250mg
Price: $99
Updated: 2024/03/01

Sigma-Aldrich

Product number: 407151
Product name: 2,6-Bis[(4S)-(?)-isopropyl-2-oxazolin-2-yl]pyridine
Purity: 99%
Packaging: 1g
Price: $324
Updated: 2024/03/01

TCI Chemical

Product number: B2218
Product name: (S,S)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine
Purity: >98.0%(GC)
Packaging: 5g
Price: $644
Updated: 2024/03/01

TCI Chemical

Product number: B2218
Product name: (S,S)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine
Purity: >98.0%(GC)
Packaging: 500mg
Price: $102
Updated: 2024/03/01

Strem Chemicals

Product number: 07-0307
Product name: (-)-2,6-Bis[(4S)-4-(i-propyl)-2-oxazolin-2-yl]pyridine, 98+% (S)-(i-Pr)-pybox
Packaging: 250mg
Price: $148
Updated: 2024/03/01

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(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE Chemical Properties,Usage,Production

Reaction

Ligand used in the dual-catalyst system for highly enantioselective conjugate cyanation of unsaturated imides.
Ligand for cross-coupling reactions of iodoalkanes with alkyl zinc halides.
Ligand for asymmetric 1,4-addition reactions of 1,3-dicarbonyl compounds to nitroalkenes.
Ligand for asymmetric allylation of aldehydes with b-carbonyl allylstannanes.
Ligand used in the enantioselective Negishi reaction of racemic secondary benzylic halides.
Ligand for osmium catalyzed enantioselective transfer hydrogenation.

Chemical Properties

White powder or crystal or chunks

Uses

Used as a ligand to prepare novel ruthenium-pyridine-carboxylate complexes as new catalytic systems for alkene epoxidation.

(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE Suppliers

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Energy Chemical

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View Lastest Price from (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE 118949-61-4
Price: US $0.00-0.00/KG
Min. Order: 1g
Purity: 99%
Supply Ability: 2000tons
Release date: 2019-12-31

118949-61-4, (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINERelated Search:

2,6-Bis[(4S)-4-tert-butyloxazolin-2-yl]pyridine (R,R)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE 2-[(4R)-4,5-dihydro-4-(phenylMethyl)-2-oxazolyl]- Pyridine 2,6-bis[(4S,5S)-4,5-dihydro-4,5-diphenyl-1H-imidazol-2-yl]-Pyridine 2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO& (S)-5-CF3-pyrox-tBu 2-[(4R)-4-(1,1-diMethylethyl)-4,5-dihydro-2-oxazolyl]-5-(trifluoroMethyl)-Pyridine 2,6-BIS[(4R)-4-TERT-BUTYL-2-OXAZOLIN-2YL]PYRIDINE 2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE (S,S)-2,2-BIS(4-PHENYL-2-OXAZOLIN-2-YL)PROPANE (-)-1,2-BIS((2R,5R)-2,5-DIPHENYLPHOSPHOLANO)ETHANE 2,6-BIS(2-BENZIMIDAZOLYL)PYRIDINE (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE 2,6-Pyridinedimethanol METHYL PICOLINIMIDATE PYRIDINE-2-CARBOXIMIDIC ACID ETHYL ESTER

2,6-Bis[(4S)-4-isopropyl-2-oxazolin-2-yl]pyridine

2,6-Bis((S)

-4-isopropyl-4,5-dihydrooxazol-2-yl)

2,6-Bis[(4S)-isopropyl-2-oxazolin-2-yl]pyridine,99%e.e.

(-)-2,6-BIS[(4S)-4-(I-PROPYL)-2-OXAZOLIN-2-YL]PYRIDINE

2,6-BIS[(4S)-(-)-ISOPROPYL-2-OXAZOLIN-2-YL]PYRIDINE

2,6-Bis[(4S)-(-)-isopropyl-2-oxazolin-2-yl]pyridine ,99%

(S,S)-2,2'-(2,6-PYRIDINEDIYL)BIS(4-ISOPROPYL-2-OXAZOLINE)

(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE

(S,S)-2,2μ-(2,6-Pyridinediyl)bis(4-isopropyl-2-oxazoline), (S,S)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine

2,6-Bis[(4S)-(-)-isopropyl-2-oxazolin-2-yl]pyridine 99%

(S, S) -2,6- bis (4-isopropyl-2-oxazoline-2-yl) pyridine

(-)-2,6-Bis[(4S)-4-(i-propyl)-2-oxazolin-2-yl]pyridine, 98+% (S)-(i-Pr)-pybox

2,6-Bis((S)-4-isopropyl-4,5-dihydrooxazol-2-yl)pyridine

2,6-Bis[(4S)-isopropyl-2-oxazolin-2-yl]pyridine, 98%, (99% ee)

(S,S)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine &gt

Pyridine, 2,6-bis[(4S)-4,5-dihydro-4-(1-methylethyl)-2-oxazolyl]-

(-)-2,6-Bis[(4S)-4-(i-propyl)-2-oxazolin-2-yl]pyridine,98%,99%ee

(S,S)-iPr-Pybox

(4S)-4-propan-2-yl-2-[6-[(4S)-4-propan-2-yl-4,5-dihydro-1,3-oxazol-2-yl]pyridin-2-yl]-4,5-dihydro-1,3-oxazole

(S,S)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine(S,S)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine

(-)-2,6-Bis[(4S)-4-(i-propyl)-2-oxazolin-2-yl]pyridine

118949-61-4

Chiral Building Blocks

Chiral Catalysts, Ligands, and Reagents

Asymmetric Synthesis

Heterocyclic Building Blocks

Pyridines

PyBOX

Privileged Ligands

organic amine

BOX series

Chiral Nitrogen

Asymmetric Synthesis

Synthetic Organic Chemistry