Reaction
ChemicalBook > CAS DataBase List > (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE

(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE

Reaction
Product Name
(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE
CAS No.
118949-61-4
Chemical Name
(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE
Synonyms
2,6-Bis((S);(S,S)-iPr-Pybox;-4-isopropyl-4,5-dihydrooxazol-2-yl);2,6-Bis[(4S)-4-isopropyl-2-oxazolin-2-yl]pyridine;(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE;2,6-BIS[(4S)-(-)-ISOPROPYL-2-OXAZOLIN-2-YL]PYRIDINE;(-)-2,6-BIS[(4S)-4-(I-PROPYL)-2-OXAZOLIN-2-YL]PYRIDINE;(S,S)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine >(-)-2,6-Bis[(4S)-4-(i-propyl)-2-oxazolin-2-yl]pyridine;2,6-Bis[(4S)-(-)-isopropyl-2-oxazolin-2-yl]pyridine 99%
CBNumber
CB7298752
Molecular Formula
C17H23N3O2
Formula Weight
301.38
MOL File
118949-61-4.mol
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(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE Property

Melting point:
155-157 °C(lit.)
alpha 
-120° (c 1.0, CH2Cl2)
Boiling point:
457.1±30.0 °C(Predicted)
Density 
1.23±0.1 g/cm3(Predicted)
storage temp. 
Inert atmosphere,2-8°C
pka
3.78±0.70(Predicted)
form 
crystal
color 
white
optical activity
[α]25/D 118°, c = 0.7 in methylene chloride
BRN 
5824976
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
29309090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
407151
Product name
2,6-Bis[(4S)-(?)-isopropyl-2-oxazolin-2-yl]pyridine
Purity
99%
Packaging
250mg
Price
$99
Updated
2024/03/01
Sigma-Aldrich
Product number
407151
Product name
2,6-Bis[(4S)-(?)-isopropyl-2-oxazolin-2-yl]pyridine
Purity
99%
Packaging
1g
Price
$324
Updated
2024/03/01
TCI Chemical
Product number
B2218
Product name
(S,S)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine
Purity
>98.0%(GC)
Packaging
5g
Price
$644
Updated
2024/03/01
TCI Chemical
Product number
B2218
Product name
(S,S)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine
Purity
>98.0%(GC)
Packaging
500mg
Price
$102
Updated
2024/03/01
Strem Chemicals
Product number
07-0307
Product name
(-)-2,6-Bis[(4S)-4-(i-propyl)-2-oxazolin-2-yl]pyridine, 98+% (S)-(i-Pr)-pybox
Packaging
250mg
Price
$148
Updated
2024/03/01
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(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE Chemical Properties,Usage,Production

Reaction

  1. Ligand used in the dual-catalyst system for highly enantioselective conjugate cyanation of unsaturated imides.
  2. Ligand for cross-coupling reactions of iodoalkanes with alkyl zinc halides.
  3. Ligand for asymmetric 1,4-addition reactions of 1,3-dicarbonyl compounds to nitroalkenes.
  4. Ligand for asymmetric allylation of aldehydes with b-carbonyl allylstannanes.
  5. Ligand used in the enantioselective Negishi reaction of racemic secondary benzylic halides.
  6. Ligand for osmium catalyzed enantioselective transfer hydrogenation.

Chemical Properties

White powder or crystal or chunks

Uses

Used as a ligand to prepare novel ruthenium-pyridine-carboxylate complexes as new catalytic systems for alkene epoxidation.

(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE Suppliers

Americas 1 China 116 Europe 1 Germany 2 India 2 Japan 1 Switzerland 1 United Kingdom 3 United States 11 Global 138
TCI Europe
Tel
320-37350700
Fax
+32 (0)37350701
Email
sales@tcieurope.eu
Country
Europe
ProdList
23671
Advantage
75
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View Lastest Price from (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE 118949-61-4
Price
US $0.00-0.00/KG
Min. Order
1g
Purity
99%
Supply Ability
2000tons
Release date
2019-12-31

118949-61-4, (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINERelated Search:

2,6-Bis[(4S)-4-tert-butyloxazolin-2-yl]pyridine (R,R)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE 2-[(4R)-4,5-dihydro-4-(phenylMethyl)-2-oxazolyl]- Pyridine 2,6-bis[(4S,5S)-4,5-dihydro-4,5-diphenyl-1H-imidazol-2-yl]-Pyridine 2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO& (S)-5-CF3-pyrox-tBu 2-[(4R)-4-(1,1-diMethylethyl)-4,5-dihydro-2-oxazolyl]-5-(trifluoroMethyl)-Pyridine 2,6-BIS[(4R)-4-TERT-BUTYL-2-OXAZOLIN-2YL]PYRIDINE 2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE (S,S)-2,2-BIS(4-PHENYL-2-OXAZOLIN-2-YL)PROPANE (-)-1,2-BIS((2R,5R)-2,5-DIPHENYLPHOSPHOLANO)ETHANE 2,6-BIS(2-BENZIMIDAZOLYL)PYRIDINE (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE 2,6-Pyridinedimethanol METHYL PICOLINIMIDATE PYRIDINE-2-CARBOXIMIDIC ACID ETHYL ESTER

  • 2,6-Bis[(4S)-4-isopropyl-2-oxazolin-2-yl]pyridine
  • 2,6-Bis((S)
  • -4-isopropyl-4,5-dihydrooxazol-2-yl)
  • 2,6-Bis[(4S)-isopropyl-2-oxazolin-2-yl]pyridine,99%e.e.
  • (-)-2,6-BIS[(4S)-4-(I-PROPYL)-2-OXAZOLIN-2-YL]PYRIDINE
  • 2,6-BIS[(4S)-(-)-ISOPROPYL-2-OXAZOLIN-2-YL]PYRIDINE
  • 2,6-Bis[(4S)-(-)-isopropyl-2-oxazolin-2-yl]pyridine ,99%
  • (S,S)-2,2'-(2,6-PYRIDINEDIYL)BIS(4-ISOPROPYL-2-OXAZOLINE)
  • (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE
  • (S,S)-2,2μ-(2,6-Pyridinediyl)bis(4-isopropyl-2-oxazoline), (S,S)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine
  • 2,6-Bis[(4S)-(-)-isopropyl-2-oxazolin-2-yl]pyridine 99%
  • (S, S) -2,6- bis (4-isopropyl-2-oxazoline-2-yl) pyridine
  • (-)-2,6-Bis[(4S)-4-(i-propyl)-2-oxazolin-2-yl]pyridine, 98+% (S)-(i-Pr)-pybox
  • 2,6-Bis((S)-4-isopropyl-4,5-dihydrooxazol-2-yl)pyridine
  • 2,6-Bis[(4S)-isopropyl-2-oxazolin-2-yl]pyridine, 98%, (99% ee)
  • (S,S)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine &gt
  • Pyridine, 2,6-bis[(4S)-4,5-dihydro-4-(1-methylethyl)-2-oxazolyl]-
  • (-)-2,6-Bis[(4S)-4-(i-propyl)-2-oxazolin-2-yl]pyridine,98%,99%ee
  • (S,S)-iPr-Pybox
  • (4S)-4-propan-2-yl-2-[6-[(4S)-4-propan-2-yl-4,5-dihydro-1,3-oxazol-2-yl]pyridin-2-yl]-4,5-dihydro-1,3-oxazole
  • (S,S)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine(S,S)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine
  • (-)-2,6-Bis[(4S)-4-(i-propyl)-2-oxazolin-2-yl]pyridine
  • (-)-2,6-Bis[(4S)-4-(i-propyl)-2-oxazolin-2-yl]pyridine,98%
  • 118949-61-4
  • Chiral Building Blocks
  • Chiral Catalysts, Ligands, and Reagents
  • Asymmetric Synthesis
  • Heterocyclic Building Blocks
  • Pyridines
  • PyBOX
  • Privileged Ligands
  • organic amine
  • BOX series
  • Chiral Nitrogen
  • Asymmetric Synthesis
  • Synthetic Organic Chemistry