ChemicalBook > CAS DataBase List > Methyl 2-furoate

Methyl 2-furoate

Product Name
Methyl 2-furoate
CAS No.
611-13-2
Chemical Name
Methyl 2-furoate
Synonyms
METHYL FURAN-2-CARBOXYLATE;2-FURANCARBOXYLIC ACID METHYL ESTER;MEFAT;FEMA 2703;2-METHYLFUROATE;Methyle furoate;METHYL 2-FUROATE;METHYL PYROMUCATE;Methyl 2-furanoate;RARECHEM AL BF 0007
CBNumber
CB3306772
Molecular Formula
C6H6O3
Formula Weight
126.11
MOL File
611-13-2.mol
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Methyl 2-furoate Property

Boiling point:
181 °C (lit.)
Density 
1.179 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.487(lit.)
FEMA 
2703 | METHYL 2-FUROATE
Flash point:
164 °F
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Liquid
color 
Clear pale yellow to brown
Odor
fruity, mushroom-like odor
Odor Type
fungal
Water Solubility 
slightly soluble
Sensitive 
Lachrymatory
JECFA Number
746
Merck 
14,4307
BRN 
111110
LogP
0.99
CAS DataBase Reference
611-13-2(CAS DataBase Reference)
NIST Chemistry Reference
Methyl 2-furoate(611-13-2)
EPA Substance Registry System
2-Furancarboxylic acid, methyl ester (611-13-2)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
36/37/38-21/22-22
Safety Statements 
26-36-36/37/39
RIDADR 
UN 2810 6.1/PG 3
WGK Germany 
3
RTECS 
LV1950000
Hazard Note 
Irritant
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
III
HS Code 
29321900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W270318
Product name
Methyl 2-furoate
Purity
≥98%, FG
Packaging
sample-k
Price
$54.6
Updated
2024/03/01
Sigma-Aldrich
Product number
W270318
Product name
Methyl 2-furoate
Purity
≥98%, FG
Packaging
100g
Price
$75.3
Updated
2024/03/01
Sigma-Aldrich
Product number
W270318
Product name
Methyl 2-furoate
Purity
≥98%, FG
Packaging
1kg
Price
$212
Updated
2024/03/01
Sigma-Aldrich
Product number
W270318
Product name
Methyl 2-furoate
Purity
≥98%, FG
Packaging
5kg
Price
$480
Updated
2024/03/01
Sigma-Aldrich
Product number
129852
Product name
Methyl 2-furoate
Purity
98%
Packaging
25g
Price
$35.4
Updated
2024/03/01
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Methyl 2-furoate Chemical Properties,Usage,Production

Description

Methyl 2-furoate has a pleasant, fruity odor similar to mushroom, fungus or tobacco with a sweet, tart, fruity taste that is quite heavy. May be prepared from 2-furoic acid in methanol solution in the presence of HCL as catalyst (oxidation or Carmizzaro reaction).

Chemical Properties

Methyl furoate has a pleasant, fruity odor similar to mushroom, fungus or tobacco with a sweet, tart, fruity taste that is quite heavy

Chemical Properties

Colorless to light yellow liqui

Occurrence

Reported found in cranberry, guava, baked potato, raisin, papaya, blackberry, baked potato, tomato, cognac, coffee, filbert, peanut, cocoa, passion fruit, almonds, tamarind, soursop, dried bonito, kiwifruit, mountain papaya, wild rice, okra, grape brandy and roasted hazelnut.

Uses

Solvent, organic synthesis.

Uses

Methyl 2-furoate (Methyl furan-2-carboxylate, Methyl pyromucate) was used to synthesize cis-fused 5-oxofuro[2,3-b]furans. It was also used in the preparation of sesquiterpene lactone.

Preparation

From 2-furoic acid in methanol solution in the presence of HCl as catalyst (oxidation or Carmizzaro reaction)

Definition

ChEBI: Methyl 2-Furancarboxylate is a carboxylic ester. It is functionally related to a 2-furoic acid.

Aroma threshold values

Aroma characteristics at 1.0%: musty, sweet caramel, fruity, cocoa, bready and slightly rubbery.

Taste threshold values

Taste characteristics at 20 ppm: brothy, yeasty, caramellic and burnt with a sweet bready, acetoin, buttery nuance

Synthesis Reference(s)

Chemical and Pharmaceutical Bulletin, 37, p. 3225, 1989 DOI: 10.1248/cpb.37.3225

General Description

Methyl 2-furoate has been identified as one of the volatile flavor compounds in tequila, okra, berrycactus and black currant juice.

Safety Profile

Poison by intraperitoneal route. A skin irritant and lachrymator. When heated to decomposition it emits acrid smoke and irritating fumes.

Methyl 2-furoate Preparation Products And Raw materials

Raw materials

2-Furoic acid

Preparation Products

METHYL 5-NITRO-2-FUROATE
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Methyl 2-furoate Suppliers

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View Lastest Price from Methyl 2-furoate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Methyl 2-Furoate 611-13-2
Price
US $75.00-20.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-06-03
Hebei Weibang Biotechnology Co., Ltd
Product
Methyl 2-furoate 611-13-2
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-31
Hebei Yanxi Chemical Co., Ltd.
Product
Methyl 2-furoate 611-13-2
Price
US $20.00-1.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-11-03

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