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Tetrachlorophthalic anhydride

Product Name
Tetrachlorophthalic anhydride
CAS No.
117-08-8
Chemical Name
Tetrachlorophthalic anhydride
Synonyms
TCPA;4,5,6,7-Tetrachloroisobenzofuran-1,3-dione;tetrachlorophthalic;,5,6,7-Tetrachloro-isobenzofuran-1,3-dione;cp626;NIATHAL;TETRATHAL;orophthaL;Niagathal;NCI-C61585
CBNumber
CB3313062
Molecular Formula
C8Cl4O3
Formula Weight
285.9
MOL File
117-08-8.mol
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Tetrachlorophthalic anhydride Property

Melting point:
253-257 °C(lit.)
Boiling point:
371 °C(lit.)
Density 
1.49
vapor pressure 
0.16 mm Hg ( 145 °C)
Flash point:
362°C
storage temp. 
Store below +30°C.
solubility 
Chloroform (Slightly, Heated), DMSO (Heated), Methanol (Slightly, Heated)
form 
Flakes
pka
3.01[at 20 ℃]
color 
White to off-white
Water Solubility 
0.8 mg/L (21 ºC)
Sensitive 
Moisture Sensitive
BRN 
211560
Exposure limits
ACGIH: TWA 0.002 mg/m3 (Skin)
Stability:
Stable. Reacts with water. Combustible. Incompatible with strong oxidizing agents. Air and moisture sensitive.
InChIKey
AUHHYELHRWCWEZ-UHFFFAOYSA-N
LogP
3.2 at 25℃
CAS DataBase Reference
117-08-8(CAS DataBase Reference)
NIST Chemistry Reference
1,3-Isobenzofurandione, 4,5,6,7-tetrachloro-(117-08-8)
EPA Substance Registry System
Tetrachlorophthalic anhydride (117-08-8)
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Safety

Hazard Codes 
T,N,Xn
Risk Statements 
45-41-42/43-50/53-48/22
Safety Statements 
53-22-24-26-37/39-45-60-61-36/37/39
RIDADR 
UN 3077 9/PG 3
WGK Germany 
2
RTECS 
TI3450000
10-21
TSCA 
Yes
HazardClass 
9
PackingGroup 
III
HS Code 
29173990
Hazardous Substances Data
117-08-8(Hazardous Substances Data)
Toxicity
LD50 orally in Rabbit: > 15800 mg/kg LD50 dermal Rabbit > 5000 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H317May cause an allergic skin reaction

H318Causes serious eye damage

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

H350May cause cancer

H373May cause damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P201Obtain special instructions before use.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
131865
Product name
Tetrachlorophthalic anhydride
Purity
96%
Packaging
100g
Price
$45
Updated
2024/03/01
Sigma-Aldrich
Product number
8.00741
Product name
Tetrachlorophthalic anhydride
Purity
for synthesis
Packaging
100g
Price
$50.7
Updated
2024/03/01
Sigma-Aldrich
Product number
131865
Product name
Tetrachlorophthalic anhydride
Purity
96%
Packaging
500g
Price
$112
Updated
2024/03/01
Alfa Aesar
Product number
A17404
Product name
Tetrachlorophthalic anhydride
Purity
98%
Packaging
500g
Price
$52.6
Updated
2024/03/01
Alfa Aesar
Product number
A17404
Product name
Tetrachlorophthalic anhydride
Purity
98%
Packaging
2500g
Price
$153.65
Updated
2024/03/01
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Tetrachlorophthalic anhydride Chemical Properties,Usage,Production

Chemical Properties

white needle-like crystals or powder

Uses

Intermediate in dyes, pharmaceuticals, plasticizers, and other organic materials; flame-retardant in epoxy resins.

Uses

Tetrachlorophthalic Anhydride is used in the synthesis of nucleoside analogues with a specific structure as apoptosis inducing active compounds. Also used in the synthesis of carbonic anhydrase inhbitors. Chlorinated Reactive Flame Retardant Intermediate

Definition

ChEBI: A cyclic dicarboxylic anhydride that is phthalic anhydride chlorinated at the 4-, 5-, 6- and 7-positions.

General Description

Odorless needle-like crystals or white powder.

Air & Water Reactions

Sensitive to air and moisture.

Reactivity Profile

4,5,6,7-Tetrachloro-1,3-isobenzofurandione reacts exothermically with water. This reaction is expected to be slow, but can become vigorous if local heating accelerates it. Reaction with water is accelerated by acids. Incompatible with acids, strong oxidizing agents, alcohols, amines, and bases.

Fire Hazard

Flash point data for 4,5,6,7-Tetrachloro-1,3-isobenzofurandione are not available. 4,5,6,7-Tetrachloro-1,3-isobenzofurandione is probably combustible.

Flammability and Explosibility

Not classified

Purification Methods

Crystallise the anhydride from chloroform or *benzene, then sublime it in a vacuum. [Beilstein 17/11 V 260.]

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Tetrachlorophthalic anhydride Suppliers

kemikalieimport
Tel
--
Fax
--
Email
Sales@kemikalieimport.dk
Country
Europe
ProdList
6685
Advantage
47
Camida
Tel
--
Fax
--
Email
info@camida.com
Country
Europe
ProdList
3704
Advantage
71
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View Lastest Price from Tetrachlorophthalic anhydride manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
Tetrachlorophthalic anhydride 117-08-8
Price
US $30.00-10.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-11-23
Chemwill Asia Co.,Ltd.
Product
Tetrachlorophthalic anhydride 117-08-8 117-08-8
Price
US $12.50/KG
Min. Order
1KG
Purity
99.0% in stock
Supply Ability
1500 MT per month
Release date
2019-08-14
Chemwill Asia Co.,Ltd.
Product
4,5,6,7-Tetrachloro-1,3-isobenzofurandione 117-08-8 117-08-8
Price
US $15.50/KG
Min. Order
1KG
Purity
99.0% in stock
Supply Ability
1600 MT per month
Release date
2019-08-14

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