ChemicalBook > CAS DataBase List > Ir(dmppy)2(dtbbpy)PF6 or (Ir[Me(Me)ppy]2(dtbpy))PF6

Ir(dmppy)2(dtbbpy)PF6 or (Ir[Me(Me)ppy]2(dtbpy))PF6

Reaction

Product Name: Ir(dmppy)2(dtbbpy)PF6 or (Ir[Me(Me)ppy]2(dtbpy))PF6
CAS No.: 1607469-49-7
Chemical Name: Ir(dmppy)2(dtbbpy)PF6 or (Ir[Me(Me)ppy]2(dtbpy))PF6
Synonyms: -2-(4-methyL;-2-pyridinyL;4,4'-Bis(t-butyL;-kC]iridium hexafL;Ir(dmppy)2(dtbbpy)PF6;(IR[ME(ME)PPY]2(DTBPY))PF6;(Ir[Me(Me)ppy]?(dtbpy))PF?;-2,2'-bipyridine)bis[5-methyL;(Ir[Me(Me)ppy]₂(dtbpy))PF₆;Ir(dmppy)2(dtbbpy)PF6 or (Ir[Me(Me)ppy]2(dtbpy))PF6
CBNumber: CB33161732
Molecular Formula: C44H48F6IrN4P
Formula Weight: 970.08
MOL File: 1607469-49-7.mol

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Ir(dmppy)2(dtbbpy)PF6 or (Ir[Me(Me)ppy]2(dtbpy))PF6 Property

storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: Powder
color: yellow
Sensitive: air sensitive
InChIKey: SFJOCOJKUUPWQQ-UHFFFAOYSA-N
SMILES: [P+5]([F-])([F-])([F-])([F-])([F-])[F-].CC1=CC=C2C3=CC(C)=CC=N3[Ir+3]34([C-]5=CC(C)=CC=C5C5=CC(C)=CC=N35)(N3=CC=C(C(C)(C)C)C=C3C3=CC(C(C)(C)C)=CC=N43)[C-]2=C1

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Safety

Risk Statements: 36/37/38
Safety Statements: 26
TSCA: No

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 905917
Product name: (Ir[Me(Me)ppy]2(dtbpy))PF6
Packaging: 100mg
Price: $164
Updated: 2025/07/31

Sigma-Aldrich

Product number: 905917
Product name: (Ir[Me(Me)ppy]2(dtbpy))PF6
Packaging: 500mg
Price: $550
Updated: 2025/07/31

Strem Chemicals

Product number: 77-0218
Product name: 4,4'-Bis(t-butyl-2,2'-bipyridine]bis[5-methyl-2-(4-methyl-2-pyridinyl-kN)phenyl-kC]iridium hexafluorophosphate, 95%
Packaging: 50mg
Price: $59
Updated: 2024/03/01

Strem Chemicals

Product number: 77-0218
Product name: 4,4'-Bis(t-butyl-2,2'-bipyridine]bis[5-methyl-2-(4-methyl-2-pyridinyl-kN)phenyl-kC]iridium hexafluorophosphate, 95%
Packaging: 250mg
Price: $230
Updated: 2024/03/01

American Custom Chemicals Corporation

Product number: OGM0003695
Product name: [4,4'-BIS(TERT-BUTYL)-2,2'-BIPYRIDINE]BIS[5-METHYL-2-(4-METHYL-2-PYRIDINYL)PHENYL]IRIDIUM(III) HEXAFLUOROPHOSPHATE
Purity: 95.00%
Packaging: 5MG
Price: $500.95
Updated: 2021/12/16

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Ir(dmppy)2(dtbbpy)PF6 or (Ir[Me(Me)ppy]2(dtbpy))PF6 Chemical Properties,Usage,Production

Reaction

Catalyst used for the direct β-alkylation of aldehydes via photoredox organocatalysis.

Uses

(Ir[Me(Me)ppy]₂(dtbpy))PF₆ or Ir(dmppy)₂(dtbbpy)PF₆ is an iridium photoredox catalyst that facilitates a variety of transformations using visible light, including the α- and β-alkylation of aldehydes.

reaction suitability

core: iridium
reagent type: catalyst
reaction type: Photocatalysis

Ir(dmppy)2(dtbbpy)PF6 or (Ir[Me(Me)ppy]2(dtbpy))PF6 Preparation Products And Raw materials

Raw materials

Preparation Products

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Ir(dmppy)2(dtbbpy)PF6 or (Ir[Me(Me)ppy]2(dtbpy))PF6 Suppliers

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1607469-49-7, Ir(dmppy)2(dtbbpy)PF6 or (Ir[Me(Me)ppy]2(dtbpy))PF6Related Search:

Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-methyl-2-(4-methyl-2-pyridinyl-κN)phenyl-κC]-,(OC-6-33)-, hexafluorophosphate(1-)(1:1)

Ir(dmppy)2(dtbbpy)PF6

4,4'-BIS(T-BUTYL-2,2'-BIPYRIDINE]BIS[5-METHYL-2-(4-METHYL-2-PYRIDINYL-KN)PHENYL-KC]IRIDIUMHEXAFLUOROPHOSPHATE,95%

4,4'-Bis(t-butyl-2,2'-bipyridine]bis[5-methyl-2-(4-methyl-2-pyridinyl-kN)phenyl-kC]iridium hexafluorophosphate, 95%

(IR[ME(ME)PPY]2(DTBPY))PF6

Ir(dmppy)2(dtbbpy)PF6 or (Ir[Me(Me)ppy]2(dtbpy))PF6

Ir(DMPPY)2(DTBBPY)PF6 Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-methyl-2-(4-methyl-2-pyridinyl-κN)phenyl-κC]-,(OC-6-33)-, hexafluorophosphate(1-)(1:1)

-2,2'-bipyridine)bis[5-methyL

4,4'-Bis(t-butyL

-kC]iridium hexafL

-2-(4-methyL

-2-pyridinyL

(Ir[Me(Me)ppy]?(dtbpy))PF?

Bis[4-methyl-2-(4-methylphenyl)pyridine][4,4'-di-tert-butyl-2,2'-bipyridine] iridium(III) hexafluorophosphate

4,4'-Bis(t-butyl-2,2'-bipyridine]bis[5-methyl-2-(4-methyl-2-pyridinyl-kN)phenyl-kC]iridium exafluorophosphate

(Ir[Me(Me)ppy]<sub>2</sub>(dtbpy))PF<sub>6 </sub>

1607469-49-7

C44H48F6IrN4P