Reaction
ChemicalBook > CAS DataBase List > Ir(dmppy)2(dtbbpy)PF6 or (Ir[Me(Me)ppy]2(dtbpy))PF6

Ir(dmppy)2(dtbbpy)PF6 or (Ir[Me(Me)ppy]2(dtbpy))PF6

Reaction
Product Name
Ir(dmppy)2(dtbbpy)PF6 or (Ir[Me(Me)ppy]2(dtbpy))PF6
CAS No.
1607469-49-7
Chemical Name
Ir(dmppy)2(dtbbpy)PF6 or (Ir[Me(Me)ppy]2(dtbpy))PF6
Synonyms
-2-(4-methyL;-2-pyridinyL;4,4'-Bis(t-butyL;-kC]iridium hexafL;Ir(dmppy)2(dtbbpy)PF6;(IR[ME(ME)PPY]2(DTBPY))PF6;(Ir[Me(Me)ppy]?(dtbpy))PF?;-2,2'-bipyridine)bis[5-methyL;(Ir[Me(Me)ppy]2(dtbpy))PF6 ;Ir(dmppy)2(dtbbpy)PF6 or (Ir[Me(Me)ppy]2(dtbpy))PF6
CBNumber
CB33161732
Molecular Formula
C44H48F6IrN4P
Formula Weight
970.08
MOL File
1607469-49-7.mol
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Ir(dmppy)2(dtbbpy)PF6 or (Ir[Me(Me)ppy]2(dtbpy))PF6 Property

storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Powder
color 
yellow
Sensitive 
air sensitive
InChIKey
SFJOCOJKUUPWQQ-UHFFFAOYSA-N
SMILES
[P+5]([F-])([F-])([F-])([F-])([F-])[F-].CC1=CC=C2C3=CC(C)=CC=N3[Ir+3]34([C-]5=CC(C)=CC=C5C5=CC(C)=CC=N35)(N3=CC=C(C(C)(C)C)C=C3C3=CC(C(C)(C)C)=CC=N43)[C-]2=C1
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Safety

Risk Statements 
36/37/38
Safety Statements 
26
TSCA 
No
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
905917
Product name
(Ir[Me(Me)ppy]2(dtbpy))PF6
Packaging
100mg
Price
$164
Updated
2025/07/31
Sigma-Aldrich
Product number
905917
Product name
(Ir[Me(Me)ppy]2(dtbpy))PF6
Packaging
500mg
Price
$550
Updated
2025/07/31
Strem Chemicals
Product number
77-0218
Product name
4,4'-Bis(t-butyl-2,2'-bipyridine]bis[5-methyl-2-(4-methyl-2-pyridinyl-kN)phenyl-kC]iridium hexafluorophosphate, 95%
Packaging
50mg
Price
$59
Updated
2024/03/01
Strem Chemicals
Product number
77-0218
Product name
4,4'-Bis(t-butyl-2,2'-bipyridine]bis[5-methyl-2-(4-methyl-2-pyridinyl-kN)phenyl-kC]iridium hexafluorophosphate, 95%
Packaging
250mg
Price
$230
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
OGM0003695
Product name
[4,4'-BIS(TERT-BUTYL)-2,2'-BIPYRIDINE]BIS[5-METHYL-2-(4-METHYL-2-PYRIDINYL)PHENYL]IRIDIUM(III) HEXAFLUOROPHOSPHATE
Purity
95.00%
Packaging
5MG
Price
$500.95
Updated
2021/12/16
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Ir(dmppy)2(dtbbpy)PF6 or (Ir[Me(Me)ppy]2(dtbpy))PF6 Chemical Properties,Usage,Production

Reaction

Catalyst used for the direct β-alkylation of aldehydes via photoredox organocatalysis.

Uses

(Ir[Me(Me)ppy]2(dtbpy))PF6 or Ir(dmppy)2(dtbbpy)PF6 is an iridium photoredox catalyst that facilitates a variety of transformations using visible light, including the α- and β-alkylation of aldehydes.

reaction suitability

core: iridium
reagent type: catalyst
reaction type: Photocatalysis

Ir(dmppy)2(dtbbpy)PF6 or (Ir[Me(Me)ppy]2(dtbpy))PF6 Preparation Products And Raw materials

Raw materials

Preparation Products

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Ir(dmppy)2(dtbbpy)PF6 or (Ir[Me(Me)ppy]2(dtbpy))PF6 Suppliers

Yunnan Precious Metals Laboratory Co., Ltd
Tel
871-15559856 15559856215
Fax
0871-68329797
Email
yujuan@ipm.com.cn
Country
China
ProdList
225
Advantage
58
Beijing HwrkChemical Technology Co., Ltd
Tel
18515581800 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
9400
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Shanghai Jiyi Biological Technology Co., LTD
Tel
021-54135696 18516235431
Fax
50815371
Email
shgegenetech@163.com
Country
China
ProdList
469
Advantage
55
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
39966
Advantage
60
Cool Pharm, Ltd
Tel
021-60455363 18019463053
Fax
50966098
Email
sales@coolpharm.com
Country
China
ProdList
12346
Advantage
58
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51395
Advantage
80
Alfa Chemistry
Tel
1-516-6625404
Fax
1-516-927-0118
Email
support@alfa-chemistry.com
Country
United States
ProdList
9171
Advantage
60
Shanghai Haozhixiang Biotechnology Co., Ltd
Tel
526763801 13301653310
Fax
+86-21-51619052
Email
526763801@qq.com
Country
China
ProdList
9274
Advantage
55
Shanghai YuanYe Biotechnology Co., Ltd.
Tel
021-61312847; 18021002903
Fax
QQ:3008007432
Email
3008007409@qq.com
Country
China
ProdList
71826
Advantage
60

1607469-49-7, Ir(dmppy)2(dtbbpy)PF6 or (Ir[Me(Me)ppy]2(dtbpy))PF6Related Search:


  • Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-methyl-2-(4-methyl-2-pyridinyl-κN)phenyl-κC]-,(OC-6-33)-, hexafluorophosphate(1-)(1:1)
  • Ir(dmppy)2(dtbbpy)PF6
  • 4,4'-BIS(T-BUTYL-2,2'-BIPYRIDINE]BIS[5-METHYL-2-(4-METHYL-2-PYRIDINYL-KN)PHENYL-KC]IRIDIUMHEXAFLUOROPHOSPHATE,95%
  • 4,4'-Bis(t-butyl-2,2'-bipyridine]bis[5-methyl-2-(4-methyl-2-pyridinyl-kN)phenyl-kC]iridium hexafluorophosphate, 95%
  • (IR[ME(ME)PPY]2(DTBPY))PF6
  • Ir(dmppy)2(dtbbpy)PF6 or (Ir[Me(Me)ppy]2(dtbpy))PF6
  • Ir(DMPPY)2(DTBBPY)PF6 Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-methyl-2-(4-methyl-2-pyridinyl-κN)phenyl-κC]-,(OC-6-33)-, hexafluorophosphate(1-)(1:1)
  • -2,2'-bipyridine)bis[5-methyL
  • 4,4'-Bis(t-butyL
  • -kC]iridium hexafL
  • -2-(4-methyL
  • -2-pyridinyL
  • (Ir[Me(Me)ppy]?(dtbpy))PF?
  • Bis[4-methyl-2-(4-methylphenyl)pyridine][4,4'-di-tert-butyl-2,2'-bipyridine] iridium(III) hexafluorophosphate
  • 4,4'-Bis(t-butyl-2,2'-bipyridine]bis[5-methyl-2-(4-methyl-2-pyridinyl-kN)phenyl-kC]iridium exafluorophosphate
  • (Ir[Me(Me)ppy]<sub>2</sub>(dtbpy))PF<sub>6 </sub>
  • 1607469-49-7
  • C44H48F6IrN4P