3,5-DIMETHOXYBENZYL BROMIDE

Uses

Product Name: 3,5-DIMETHOXYBENZYL BROMIDE
CAS No.: 877-88-3
Chemical Name: 3,5-DIMETHOXYBENZYL BROMIDE
Synonyms: 3,5-DIMETHOXYBENZYLBROMID;3,5-DIMETHOXYBENZYL BROMIDE;α-BroMo-3,5-diMethoxytoluene;3,5-DimethoxybenzylBromide>3,5-Dimethoxybenzyl bromide 95+%;ALPHA-BROMO-3,5-DIMETHOXYTOLUENE;3,5-Dimethoxybenzyl bromide, 98%;3,5-Dimethoxybenzylamine Bromide;1-(Bromomethyl)-3,5-dimethoxybenzene;5-(BroMoMethyl)-1,3-diMethoxybenzene
CBNumber: CB3320488
Molecular Formula: C9H11BrO2
Formula Weight: 231.09
MOL File: 877-88-3.mol

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3,5-DIMETHOXYBENZYL BROMIDE Property

Melting point:: 69-70 °C (lit.)
Boiling point:: 292.1±25.0 °C(Predicted)
Density: 1.384±0.06 g/cm3(Predicted)
storage temp.: 2-8°C
solubility: soluble in Methanol
form: Crystalline Powder
color: White to brown
InChI: InChI=1S/C9H11BrO2/c1-11-8-3-7(6-10)4-9(5-8)12-2/h3-5H,6H2,1-2H3
InChIKey: BTHIGJGJAPYFSJ-UHFFFAOYSA-N
SMILES: C1(CBr)=CC(OC)=CC(OC)=C1
CAS DataBase Reference: 877-88-3(CAS DataBase Reference)

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Safety

Hazard Codes: C
Risk Statements: 34
Safety Statements: 26-27-36/37/39-45
RIDADR: UN 3261 8/PG 2
WGK Germany: 3
HazardClass: 8
PackingGroup: II
HS Code: 29093090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 480622
Product name: 3,5-Dimethoxybenzyl bromide
Purity: 95%
Packaging: 5g
Price: $157
Updated: 2025/07/31

TCI Chemical

Product number: D2657
Product name: 3,5-Dimethoxybenzyl Bromide
Purity: >97.0%(GC)
Packaging: 5g
Price: $90
Updated: 2025/07/31

TCI Chemical

Product number: D2657
Product name: 3,5-Dimethoxybenzyl Bromide
Purity: >97.0%(GC)
Packaging: 25g
Price: $334
Updated: 2025/07/31

TRC

Product number: D460835
Product name: 3,5-Dimethoxybenzyl bromide
Packaging: 50g
Price: $575
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0027883
Product name: 3,5-DIMETHOXYBENZYL BROMIDE
Purity: 95.00%
Packaging: 1G
Price: $603.7
Updated: 2021/12/16

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3,5-DIMETHOXYBENZYL BROMIDE Chemical Properties,Usage,Production

Uses

3,5-Dimethoxybenzyl bromide may be used in various organic synthesis such as 3,4,3′,5′-tetramethoxystilbene; 3,5-dimethoxyphenylacetic acid; 1-(3,5-dimethoxyphenyl)-4-pentene etc., and 3,5-Dimethoxybenzyl bromide may be used as starting material in the multi-step synthesis of resveratroland 3,5-dimethoxyhomophthalic acid.

Chemical Properties

3,5-DIMETHOXYBENZYL BROMIDE is White Solid

Uses

3,5-DIMETHOXYBENZYL BROMIDE is used in dimethoxybenzene alkyl addition.

Uses

3,5-Dimethoxybenzyl bromide may be used in the synthesis of:

3,4,3′,5′-tetramethoxystilbene
3,5-dimethoxyphenylacetic acid
1-(3,5-dimethoxyphenyl)-4-pentene

It may be used as starting material in the multi-step synthesis of resveratrol and 3,5-dimethoxyhomophthalic acid.

General Description

3,5-Dimethoxybenzyl bromide is an aromatic bromide.

Synthesis

705-76-0

877-88-3

General procedure for the synthesis of 3,5-dimethoxybenzyl bromide from 3,5-dimethoxybenzyl alcohol: 3,5-dimethoxybenzyl alcohol (1 mmol) was dissolved in anhydrous benzene (15 mL) under anhydrous conditions and phosphorus tribromide (0.5 mL) was added. The reaction mixture was stirred at room temperature until the reaction was complete. The target product 3,5-dimethoxybenzyl bromide was obtained in quantitative yield by conventional post-treatment.

References

[1] Journal of Steroid Biochemistry and Molecular Biology, 2013, vol. 137, p. 332 - 344
[2] Journal of Asian Natural Products Research, 2011, vol. 13, # 4, p. 290 - 296
[3] Patent: WO2016/164703, 2016, A1. Location in patent: Page/Page column 41
[4] Bioorganic and Medicinal Chemistry Letters, 2012, vol. 22, # 24, p. 7683 - 7687
[5] Medicinal Chemistry Research, 2016, vol. 25, # 4, p. 627 - 643

3,5-DIMETHOXYBENZYL BROMIDE Preparation Products And Raw materials

Raw materials

Sodium borohydride Methanol 3,5-Dimethoxybenzaldehyde Phosphorus tribromide

Preparation Products

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3,5-DIMETHOXYBENZYL BROMIDE Suppliers

Americas 1 Belgium 1 Canada 2 China 176 Europe 3 Germany 5 India 8 Japan 3 Switzerland 2 Ukraine 1 United Kingdom 17 United States 35 Global 254

J & K SCIENTIFIC LTD.

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View Lastest Price from 3,5-DIMETHOXYBENZYL BROMIDE manufacturers

Hebei Chuanghai Biotechnology Co., Ltd

Product: 3,5-DIMETHOXYBENZYL BROMIDE 877-88-3
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 mt
Release date: 2024-11-15

Baoji Guokang Healthchem Co., Ltd.

Product: 3,5-DIMETHOXYBENZYL BROMIDE 877-88-3
Price: US $1340.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1-200mt
Release date: 2021-06-09

Honest Joy Holdings Limited

Product: 3,5-Dimethoxybenzyl bromide 877-88-3
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98.3%
Supply Ability: 100 tons
Release date: 2022-02-18

877-88-3, 3,5-DIMETHOXYBENZYL BROMIDERelated Search:

3,5-DIMETHOXYPHENYLMAGNESIUM BROMIDE 3 4 5-TRIFLUOROPHENYLMAGNESIUM BROMIDE 3 5-DIMETHYOXYPHENYLMAGNESIUM CHLORIDE 3,4-DIFLUOROPHENYLMAGNESIUM BROMIDE 3,4-DIMETHOXYPHENYLMAGNESIUM BROMIDE 3,5-DICHLOROPHENYLMAGNESIUM BROMIDE 3,5-DIFLUOROPHENYLMAGNESIUM BROMIDE 3,4-DIMETHOXYBENZYL BROMIDE 3,5-DIMETHOXYBENZYL BROMIDE 3,5-Dimethoxytoluene 2-Bromo-4,5-Dimethoxybenzyl Bromide 5-BROMOMETHYL-1,2,3-TRIMETHOXY-BENZENE 3,5-BIS(BENZYLOXY)BENZYL BROMIDE 3,5-BIS[3,5-BIS(BENZYLOXY)BENZYLOXY]BENZYL BROMIDE 3,5-BIS(3,5-DIMETHOXYBENZYLOXY)BENZYL BROMIDE 1-(bromomethyl)-3,5-diethoxybenzene 4-BROMO-3,5-DIMETHOXYBENZYL BROMIDE 2,3-DIBROMO-1-(2-NITROPHENYL)-3-(3,4,5-TRIMETHOXYPHENYL)PROPAN-1-ONE

3,5-DIMETHOXYBENZYL BROMIDE

ALPHA-BROMO-3,5-DIMETHOXYTOLUENE

1-(Bromomethyl)-3,5-dimethoxybenzene

3,5-DIMETHOXYBENZYLBROMID

Benzene, 1-(bromomethyl)-3,5-dimethoxy-

3,5-Dimethoxybenzylamine Bromide

5-(BroMoMethyl)-1,3-diMethoxybenzene

α-BroMo-3,5-diMethoxytoluene

1-(Bromomethyl)-3,5-dimethoxybenzene, 5-(Bromomethyl)resorcinol dimethyl ether, alpha-Bromo-3,5-dimethoxytoluene

3,5-Dimethoxybenzyl bromide 95+%

3,5-DimethoxybenzylBromide&gt

TIANFUCHEM--877-88-3---3,5-DIMETHOXYBENZYL BROMIDE

3,5-Dimethoxybenzyl bromide, 98%

877-88-3

887-88-3

C9H11BrO2

C9H11O2Br

CH3O2C6H3CH2Br

BENZYL HALIDE

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Oxygen Compounds

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C9

Chemical Synthesis

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