ChemicalBook > CAS DataBase List > Methyl 2-methyl-3-nitrobenzoate

Methyl 2-methyl-3-nitrobenzoate

Product Name
Methyl 2-methyl-3-nitrobenzoate
CAS No.
59382-59-1
Chemical Name
Methyl 2-methyl-3-nitrobenzoate
Synonyms
DK835;Methyl 2-methyl-3-;Lenalidoide Ipurity 23;METHYL 3-NITRO-O-TOLUATE;2-Methyl-3-nitrobenzoate;METHYL 2-METHYL-3-NITROBENZOATE;Methyl 3-nitro-2-methylbenzoate;Methyl 2-Methyl-3-Nitro-Benzoatee;Methyl2-Methyl-3-nitrobenzoate>3-NITRO-0-TOLUIC ACID METHYL ESTER
CBNumber
CB3328974
Molecular Formula
C9H9NO4
Formula Weight
195.17
MOL File
59382-59-1.mol
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Methyl 2-methyl-3-nitrobenzoate Property

Melting point:
62-65 °C (lit.)
Boiling point:
286.6±20.0 °C(Predicted)
Density 
1?+-.0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
solubility 
Soluble in methanol.
form 
Solid
color 
Pale Beige
BRN 
1964020
CAS DataBase Reference
59382-59-1(CAS DataBase Reference)
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Safety

Safety Statements 
24/25
WGK Germany 
3
HS Code 
29163990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
366765
Product name
Methyl 2-methyl-3-nitrobenzoate
Purity
97%
Packaging
25g
Price
$71.8
Updated
2024/03/01
TCI Chemical
Product number
M2144
Product name
Methyl 2-Methyl-3-nitrobenzoate
Purity
>98.0%(GC)
Packaging
5g
Price
$21
Updated
2024/03/01
TCI Chemical
Product number
M2144
Product name
Methyl 2-Methyl-3-nitrobenzoate
Purity
>98.0%(GC)
Packaging
25g
Price
$42
Updated
2024/03/01
Alfa Aesar
Product number
H60242
Product name
Methyl 2-methyl-3-nitrobenzoate, 97%
Packaging
5g
Price
$34.65
Updated
2024/03/01
Alfa Aesar
Product number
H60242
Product name
Methyl 2-methyl-3-nitrobenzoate, 97%
Packaging
25g
Price
$129.65
Updated
2024/03/01
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Methyl 2-methyl-3-nitrobenzoate Chemical Properties,Usage,Production

Description

Methyl 2-methyl-3-nitrobenzoate is an important organic synthetic material and pharmaceutical intermediate compound. It can be used for the preparation of the anticancer drug lenalidomide as well as other organic compounds (e.g., indole-4-carboxylic acid methyl ester, 5-nitroisocoumarin, 5-aminoisoquinolin-1(2H)-one, etc.).

Chemical Properties

White crystalline powder

Uses

Methyl 2-methyl-3-nitrobenzoate may be used in the synthesis of methyl indole-4-carboxylate, 5-aminoisoquinolin-1(2H)-one, 5-nitroisocoumarin and [2-(4-fluorophenyl)-1H-indol-4-yl]-1-pyrrolidinylmethanone. It may also be used in the preparation of substituted nitrostyrene benzoic acids, via reaction with aromatic aldehydes in the presence of DBU in DMSO; and 4-(hydroxymethyl)-1-tosylindole, via Batcho-Leimgruber modification of the Reissert indole synthesis.

Uses

Methyl 2-methyl-3-nitrobenzoate may be used in the synthesis of:

  • methyl indole-4-carboxylate
  • 5-aminoisoquinolin-1(2H)-one
  • 5-nitroisocoumarin
  • substituted nitrostyrene benzoic acids, via reaction with aromatic aldehydes in the presence of DBU in DMSO
  • 4-(hydroxymethyl)-1-tosylindole, via Batcho-Leimgruber modification of the Reissert indole synthesis
  • [2-(4-fluorophenyl)-1H-indol-4-yl]-1-pyrrolidinylmethanone

Solubility in organics

Soluble in methanol.

Methyl 2-methyl-3-nitrobenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 2-methyl-3-nitrobenzoate Suppliers

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View Lastest Price from Methyl 2-methyl-3-nitrobenzoate manufacturers

Asia Chem I and E (Jiangsu) Co Ltd
Product
Methyl 2-methyl-3-nitrobenzoate 59382-59-1
Price
US $67.81/Kg/Drum
Min. Order
5KG
Purity
99.0%min
Supply Ability
5tons/momth
Release date
2022-01-11
WUHAN FORTUNA CHEMICAL CO., LTD
Product
Methyl 2-methyl-3-nitrobenzoate 59382-59-1
Price
US $0.00-0.00/Kg/Drum
Min. Order
1KG
Purity
99%min
Supply Ability
500kg
Release date
2021-10-22
Career Henan Chemical Co
Product
Methyl 2-methyl-3-nitrobenzoate 59382-59-1
Price
US $1.00/KG
Min. Order
1KG
Purity
98-100%
Supply Ability
100KG
Release date
2018-08-20

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