Methyl 2-bromobenzoate
- Product Name
- Methyl 2-bromobenzoate
- CAS No.
- 610-94-6
- Chemical Name
- Methyl 2-bromobenzoate
- Synonyms
- Pramipexol 65;Methyl2-obenzoate;RARECHEM AL BF 0014;Methyl 2-broMobenzo;Methyl o-broMophenyl;Methyl 2-bromobenzoa;METHYL O-BROMOBENZOATE;METHYL 2-BROMOBENZOATE;METHYL 2-BROMOBENZPATE;Methyl2-bromobenzoate,99%
- CBNumber
- CB0327815
- Molecular Formula
- C8H7BrO2
- Formula Weight
- 215.04
- MOL File
- 610-94-6.mol
Methyl 2-bromobenzoate Property
- Melting point:
- 252°C
- Boiling point:
- 252 °C (lit.)
- Density
- 1.532 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.559(lit.)
- Flash point:
- >230 °F
- storage temp.
- Sealed in dry,Room Temperature
- form
- Liquid
- Specific Gravity
- 1.532
- color
- Clear light yellow
- Water Solubility
- insoluble
- BRN
- 1862501
- InChI
- 1S/C8H7BrO2/c1-11-8(10)6-4-2-3-5-7(6)9/h2-5H,1H3
- InChIKey
- SWGQITQOBPXVRC-UHFFFAOYSA-N
- SMILES
- COC(=O)c1ccccc1Br
- CAS DataBase Reference
- 610-94-6(CAS DataBase Reference)
- NIST Chemistry Reference
- Methyl-2-bromobenzoate(610-94-6)
- EPA Substance Registry System
- Benzoic acid, 2-bromo-, methyl ester (610-94-6)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H361Suspected of damaging fertility or the unborn child
- Precautionary statements
-
P201Obtain special instructions before use.
P202Do not handle until all safety precautions have been read and understood.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P308+P313IF exposed or concerned: Get medical advice/attention.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- 387851
- Product name
- Methyl 2-bromobenzoate
- Purity
- 98%
- Packaging
- 5ml
- Price
- $34.1
- Updated
- 2026/03/19
- Product number
- 387851
- Product name
- Methyl 2-bromobenzoate
- Purity
- 98%
- Packaging
- 25ml
- Price
- $65.6
- Updated
- 2026/03/19
- Product number
- B0555
- Product name
- Methyl 2-Bromobenzoate
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $42
- Updated
- 2026/03/19
- Product number
- B0555
- Product name
- Methyl 2-Bromobenzoate
- Purity
- >98.0%(GC)
- Packaging
- 250g
- Price
- $240
- Updated
- 2026/03/19
- Product number
- 283378
- Product name
- Methyl 2-bromobenzoate
- Packaging
- 100g
- Price
- $402
- Updated
- 2021/12/16
Methyl 2-bromobenzoate Chemical Properties,Usage,Production
Chemical Properties
CLEAR LIGHT YELLOW LIQUID
Uses
Methyl 2-bromobenzoate under Heck reaction with acrylonitrile results in lactonization to give the benzofuran-2-one 3-(cyanomethyl)-2-coumaranone. It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals
Synthesis
Preparation of methyl o-bromobenzoate: In a 250 ml three-necked flask, add 0.04 mol of methyl benzoate and 100 ml of acetic acid, stir to dissolve, and then cool to 0 C using an ice-salt bath. Dissolve 0.05 mol of Br2 in 50 ml of acetic acid, and slowly add the bromine-acetic acid solution dropwise to the above reaction system. After the addition is complete, control the temperature at 20-25 C and stir the reaction for 12 hours. Take a sample for TLC; no raw material I1-3 remains. After the reaction is complete, add NaOH aqueous solution to neutralize the reaction solution, add dichloromethane for extraction, separate the layers, filter the organic phase, distill the filtrate under reduced pressure until no fraction remains, and pass it through a neutral silica gel column to obtain the intermediate methyl o-bromobenzoate.
Purification Methods
A solution of the ester in ether is washed with 10% aqueous Na 2CO3, water, then dried and distilled. [Beilstein 9
Methyl 2-bromobenzoate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Methyl 2-bromobenzoate manufacturers
- Product
- Methyl 2-bromobenzoate 610-94-6
- Price
- US $3.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 10000
- Release date
- 2024-09-10
- Product
- Methyl 2-bromobenzoate 610-94-6
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2025-03-14
- Product
- Methyl 2-bromobenzoate 610-94-6
- Price
- US $20.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10000kg
- Release date
- 2024-08-16