ChemicalBook > CAS DataBase List > 2-BROMO-6-CHLORO-BENZOTHIAZOLE

2-BROMO-6-CHLORO-BENZOTHIAZOLE

Product Name
2-BROMO-6-CHLORO-BENZOTHIAZOLE
CAS No.
3507-17-3
Chemical Name
2-BROMO-6-CHLORO-BENZOTHIAZOLE
Synonyms
2-BROMO-6-CHLORO-BENZOTHIAZOLE;2-Bromo-6-chlorobenzo[d]thiazole;Benzothiazole, 2-bromo-6-chloro-;2-bromo-6-chloro-1,3-benzothiazole
CBNumber
CB3333886
Molecular Formula
C7H3BrClNS
Formula Weight
248.53
MOL File
3507-17-3.mol
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2-BROMO-6-CHLORO-BENZOTHIAZOLE Property

Melting point:
99-100 °C
Boiling point:
330.5±34.0 °C(Predicted)
Density 
1.849±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
-0.87±0.10(Predicted)
Appearance
Light yellow to light brown Solid
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Safety

HS Code 
29342000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
B699815
Product name
2-Bromo-6-chlorobenzo[d]thiazole
Packaging
50mg
Price
$60
Updated
2021/12/16
TRC
Product number
B699815
Product name
2-Bromo-6-chlorobenzo[d]thiazole
Packaging
100mg
Price
$75
Updated
2021/12/16
Oakwood
Product number
077017
Product name
2-Bromo-6-chlorobenzo[d]thiazole
Purity
95+%
Packaging
250mg
Price
$44
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB151894
Product name
2-Bromo-6-chloro-benzothiazole
Packaging
250mg
Price
$52.5
Updated
2021/12/16
Oakwood
Product number
077017
Product name
2-Bromo-6-chlorobenzo[d]thiazole
Purity
95+%
Packaging
1g
Price
$88
Updated
2021/12/16
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2-BROMO-6-CHLORO-BENZOTHIAZOLE Chemical Properties,Usage,Production

Synthesis

95-24-9

7787-70-4

3507-17-3

(Step 1) Synthesis of 2-bromo-6-chlorobenzothiazole: Copper(I) bromide (1.40 g, 9.76 mmol) was suspended in acetonitrile (25 ml). To this suspension tert-butyl nitrite (1.45 ml, 12.2 mmol) was added dropwise, followed by stirring the reaction mixture at 60 °C for 15 min. Next, 2-amino-6-chlorobenzothiazole (1.50 g, 8.12 mmol) was added to the reaction system and stirring was continued at 60°C for 30 minutes. After completion of the reaction, the mixture was cooled to room temperature and diluted with ethyl acetate. The resulting organic phase was washed sequentially with 1N hydrochloric acid and saturated brine and dried over anhydrous sodium sulfate. After the solvent was removed by distillation under reduced pressure, the residue was purified by silica gel column chromatography using hexane/ethyl acetate (7:1, v/v) as eluent to afford 2-bromo-6-chlorobenzothiazole (1.39 g, 69% yield) as a yellow solid.1H-NMR (CDCl3) δ: 7.42-7.46 (m, 1H), 7.76-7.90 (m, 2H).

References

[1] Patent: EP1346982, 2003, A1

2-BROMO-6-CHLORO-BENZOTHIAZOLE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-BROMO-6-CHLORO-BENZOTHIAZOLE Suppliers

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View Lastest Price from 2-BROMO-6-CHLORO-BENZOTHIAZOLE manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
2-Bromo-6-chlorobenzo[d]thiazole 3507-17-3
Price
US $1.10-9.90/KG
Min. Order
1KG
Purity
99% min
Supply Ability
100kg
Release date
2025-08-18
Shaanxi Dideu Medichem Co. Ltd
Product
2-Bromo-6-chlorobenzo[d]thiazole 3507-17-3
Price
US $1.00/Kg
Min. Order
1Kg
Purity
98%
Supply Ability
20T
Release date
2024-07-11
Zhuozhou Wenxi import and Export Co., Ltd
Product
2-BROMO-6-CHLORO-BENZOTHIAZOLE 3507-17-3
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-11