ChemicalBook > CAS DataBase List > 6,7-Dihydro-5-methyl-5(H)-cyclopentapyrazine

6,7-Dihydro-5-methyl-5(H)-cyclopentapyrazine

Product Name
6,7-Dihydro-5-methyl-5(H)-cyclopentapyrazine
CAS No.
23747-48-0
Chemical Name
6,7-Dihydro-5-methyl-5(H)-cyclopentapyrazine
Synonyms
FEMA 3306;nutty pyrazine;FEMA NUMBER 3306;5-METHYL-6,7-DIHYDROC;MAPLE LACTONE PYRAZINE;LABOTEST-BB LT00441061;METHYL DIHYDROCYCLOPENTAPYRAZINE;5-Methyl-5H-cyclopenta[b]pyrazine;5-METHYL-2,3-CYCLOPENTENOPYRAZINE;5-METHYL-6,7-DIHYDROCYCLOPENTAPYRAZINE
CBNumber
CB3348743
Molecular Formula
C8H10N2
Formula Weight
134.18
MOL File
23747-48-0.mol
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6,7-Dihydro-5-methyl-5(H)-cyclopentapyrazine Property

Melting point:
121-123 °C
Boiling point:
96-99 °C20 mm Hg(lit.)
Density 
1.055 g/mL at 25 °C(lit.)
FEMA 
3306 | 5H-5-METHYL-6,7-DIHYDROCYCLOPENTA(B)PYRAZINE
refractive index 
n20/D 1.527(lit.)
Flash point:
174 °F
storage temp. 
Inert atmosphere,Room Temperature
form 
clear liquid
pka
1.85±0.40(Predicted)
color 
Colorless to Light yellow to Light orange
Odor
nutty, roasted odor
Odor Type
earthy
Water Solubility 
insoluble
JECFA Number
781
InChIKey
YZEFQPIMXZVPKP-UHFFFAOYSA-N
LogP
1.33
NIST Chemistry Reference
5H-5-methyl-6,7-dihydrocyclopentapyrazine(23747-48-0)
EPA Substance Registry System
5H-Cyclopentapyrazine, 6,7-dihydro-5-methyl- (23747-48-0)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
WGK Germany 
3
TSCA 
Yes
HS Code 
29339900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W330604
Product name
5H-5-Methyl-6,7-dihydrocyclopenta[b]pyrazine
Purity
≥97%, FG
Packaging
sample-k
Price
$54.6
Updated
2024/03/01
Sigma-Aldrich
Product number
W330604
Product name
5H-5-Methyl-6,7-dihydrocyclopenta[b]pyrazine
Purity
≥97%, FG
Packaging
100g
Price
$312
Updated
2024/03/01
Sigma-Aldrich
Product number
W330604
Product name
5H-5-Methyl-6,7-dihydrocyclopenta[b]pyrazine
Purity
≥97%, FG
Packaging
1kg
Price
$2020
Updated
2024/03/01
Sigma-Aldrich
Product number
W330604
Product name
5H-5-Methyl-6,7-dihydrocyclopenta[b]pyrazine
Purity
≥97%, FG
Packaging
25g
Price
$138
Updated
2023/01/07
TCI Chemical
Product number
M1086
Product name
5H-5-Methyl-6,7-dihydrocyclopentapyrazine
Purity
>97.0%(GC)(T)
Packaging
5mL
Price
$88
Updated
2024/03/01
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6,7-Dihydro-5-methyl-5(H)-cyclopentapyrazine Chemical Properties,Usage,Production

Description

5H-5-Methyl-6,7-dihydrocyclopenta(-b)pyrazine has an earthy, baked potato, peanut, roasted odor. It may be prepared from condensation of 2-hydroxy-3-methyl-2-cyclopentene-l-one and ethylene diamine; by condensing a cyclopentenolone with alkylenediamines, or alternatively, an aliphatic α-diketone with 1,2-diamino cyclopentane; the resulting product is dehydrogenated in the presence of palladium over activated charcoal or copper chromite.

Chemical Properties

5H-5-Methyl-6,7-dihydrocyclopenta(b)pyrazine has an earthy, peanut, roasted odor

Chemical Properties

clear yellow to yellow-orange to brown liquid

Occurrence

Reported found in peanuts, filberts, asparagus, potato wheat and rye bread, cooked beef, pork, pork liver, beer, cocoa, coffee, green tea, barley, filberts, almond, sesame seed, malt and wort

Uses

5-Methyl-6,7-dihydrocyclopentapyrazine can be used for drug storage packaging and antibacterial composition.

Definition

ChEBI: 6,7-Dihydro-5-methyl-5H-cyclopenta[b]pyrazine is a member of pyrazines.

Preparation

From condensation of 2-hydroxy-3-methyl-2-cyclopentene-1-one and ethylene diamine; by condensing a cyclopentenolone with alkylenediamines, or alternatively, and aliphatic α-diketone with 1,2-diamino cyclopentane; the resulting product is dehydrogenated in the presence of palladium over activated charcoal or copper chromite.

Aroma threshold values

Aroma characteristics at 1.0%: sweet, nutty, roasted, toasted, grainy, coffee and corn with savory, meaty nuances.

Taste threshold values

Taste characteristics at 15 ppm: nut skin, brown, roasted, oily with a cocoa and coffee nuance, musty, nutty, and grainy

General Description

5H-5-Methyl-6,7-dihydrocyclopenta[b]pyrazine is the major flavor compound of palm sugar. It is also found in coffee and cooked meat.

6,7-Dihydro-5-methyl-5(H)-cyclopentapyrazine Preparation Products And Raw materials

Raw materials

Preparation Products

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6,7-Dihydro-5-methyl-5(H)-cyclopentapyrazine Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
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China
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94657
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Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
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TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
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Energy Chemical
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021-021-58432009 400-005-6266
Fax
021-58436166
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sales8178@energy-chemical.com
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China
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jiliang chemicals
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21-62165282 15801962796;
Fax
021 61153784
Email
bidingchem@163.com
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China
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XiaoGan ShenYuan ChemPharm co,ltd
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15527768850
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1791901229@qq.com
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China
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8836
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Tianjin heowns Biochemical Technology Co., Ltd.
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400 638 7771
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sales@heowns.com
Country
China
ProdList
14435
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Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
4008-755-333 18080918076
Fax
028-86757656
Email
800078821@qq.com
Country
China
ProdList
9718
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T&W GROUP
Tel
021-61551611 13296011611
Fax
+86 21-50676805
Email
contact@trustwe.com
Country
China
ProdList
9895
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Qingdao Free Trade Zone United International Co.,Ltd.
Tel
0532-83893697 18561902820
Fax
83893695
Email
sissili@unitedint.com
Country
China
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View Lastest Price from 6,7-Dihydro-5-methyl-5(H)-cyclopentapyrazine manufacturers

Hebei Chuanghai Biotechnology Co,.LTD
Product
6, 7-Dihydro-5-Methyl-5 (H) -Cyclopentapyrazine 23747-48-0
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-23
JINING XINHE CHEMICAL CO., LTD
Product
6,7-Dihydro-5-methyl-5(H)-cyclopentapyrazine 23747-48-0
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10ton
Release date
2024-07-15
Henan Fengda Chemical Co., Ltd
Product
6,7-Dihydro-5-methyl-5(H)-cyclopentapyrazine 23747-48-0
Price
US $34.00-1.10/kg
Min. Order
1kg
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-25

23747-48-0, 6,7-Dihydro-5-methyl-5(H)-cyclopentapyrazineRelated Search:


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  • nutty pyrazine
  • 23747-48-0
  • C8H10N2C8H10N2C8H10N2
  • Alphabetical Listings
  • Flavors and Fragrances
  • M-N