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ChemicalBook > CAS DataBase List > 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL

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Product Name
2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
CAS No.
84783-64-2
Chemical Name
2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
Synonyms
BIPHEP;98% BIPHEP;2,2'-Bis(diphenyL;phosphino)-1,1'-biphenyL;2,2'-Bis(diphenylphosphino)-1;2,2'-Bis(diphenylphosphino)bip;2,2'-BIS(DIPHENYLPHOSPHINO)BIPHENYL;2,2'-Bis(diphenylphosphino)biphenyl;2,2'-Bis(diphenylphosphino)biphenyl >2,2’-Bis(diphenylphospino)-1,1’-biphenyl
CBNumber
CB3357299
Molecular Formula
C36H28P2
Formula Weight
522.55
MOL File
84783-64-2.mol
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2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Property

Melting point:
210-214 °C
Boiling point:
635.5±48.0 °C(Predicted)
solubility 
soluble in Toluene
form 
crystal
color 
white
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-36
Safety Statements 
37/39-26
TSCA 
No
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H319Causes serious eye irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
CDS020234
Product name
2,2′-Bis(diphenylphosphino)-1,1′-biphenyl
Purity
AldrichCPR
Packaging
25MG
Price
$70.9
Updated
2024/03/01
TCI Chemical
Product number
B2630
Product name
2,2'-Bis(diphenylphosphino)biphenyl
Purity
>98.0%(GC)
Packaging
1g
Price
$163
Updated
2024/03/01
TCI Chemical
Product number
B2630
Product name
2,2'-Bis(diphenylphosphino)biphenyl
Purity
>98.0%(GC)
Packaging
100mg
Price
$29
Updated
2024/03/01
Alfa Aesar
Product number
H31306
Product name
2,2'-Bis(diphenylphosphino)biphenyl, 98%
Packaging
1g
Price
$178.65
Updated
2024/03/01
Alfa Aesar
Product number
H31306
Product name
2,2'-Bis(diphenylphosphino)biphenyl, 98%
Packaging
5g
Price
$583.65
Updated
2024/03/01
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2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Chemical Properties,Usage,Production

Reaction

  1. Supporting ligand in a chiral diamine-ruthenium system for the enantioselective hydrogenation of ketones.
  2. Useful ligand for palladium-catalyzed amination and Kumada cross-coupling reactions
  3. Useful ligand for palladium-catalyzed synthesis of butatrenes.
  4. Useful ligand for iridium-catalyzed C-C cross-coupling of allenes with primary alcohols via transfer hydrogenation.
  5. Useful ligand for iridium-catalyzed C-C cross-coupling of dienes with primary alcohols via transfer hydrogenation.
  6. Useful ligand for iridium-catalyzed C-C cross-coupling of allylic gem-dicarboxylates with aldehydes via transfer hydrogenation.
  7. Useful ligand for the palladium-catalyzed synthesis of chiral allenylsilanes.
  8. Ruthenium-catalyzed synthesis of indoles.
  9. Ruthenium-catalyzed oxidative cyclization.
  10. Rhodium-catalyzed boron arylation. 


Chemical Properties

white crystalline powder or crystals

Uses

2,2''-Bis(diphenylphosphino)-1,1’-biphenyl (CAS# 84783-64-2) is a chelating phosphine and has been used to study the effects of bite angles on the chemical and physical properties of transition metal complexes. 2,2''-Bis(diphenylphosphino)-1,1’-biphenyl appears as a catalytic ligand in Ni- and Pd-Catalyzed cross-electrophile coupling reactions to form highly substituted 1,3-dienes.

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Preparation Products And Raw materials

Raw materials

Preparation Products

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2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
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Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
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40228
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Beijing Donghualituo Techonlogy Development Co.,Ltd.
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010-88425576
Fax
(+86)-10-88425546
Email
sales@dhltchem.com
Country
China
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793
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Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
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TCI (Shanghai) Development Co., Ltd.
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021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
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24529
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ShangHai DEMO Chemical Co.,Ltd
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400-021-7337 2355568890
Fax
0086-21-50182339
Email
sales@demochem.com
Country
China
ProdList
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Beijing HwrkChemical Technology Co., Ltd
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010-89508211 18501085097
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010-89508210
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sales.bj@hwrkchemical.com
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China
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Energy Chemical
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021-021-58432009 400-005-6266
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021-58436166
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sales8178@energy-chemical.com
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China
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44689
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Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
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Nanjin Cynthia chemicals Technology Co.,Ltd
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0550-5618439 15951861180
Fax
0550-5610690
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cynthiachem@163.com
Country
China
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View Lastest Price from 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL 84783-64-2
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2024-11-14
Shaanxi Dideu Medichem Co. Ltd
Product
2,2'-Bis(diphenylphosphino)biphenyl 84783-64-2
Price
US $1.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 tons
Release date
2020-01-16

84783-64-2, 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYLRelated Search:


  • 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
  • 2,2'-BIS(DIPHENYLPHOSPHINO)BIPHENYL
  • BIPHEP
  • [2-(2-diphenylphosphinophenyl)phenyl]-diphenylphosphine
  • 2,2'-Bis(diphenylphosphino)-1,1'-biphenyl,98%BIPHEP
  • 2,2'-Bis(diphenylphosphino)-1,1'-biphenyl, (BIPHEP)
  • 2,2’-Bis(diphenylphospino)-1,1’-biphenyl
  • PHOSPHINE, 1,1''-[[1,1''-BIPHENYL]-2,2''-DIYL]BIS[1,1-DIPHENYL-
  • 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL,98%
  • 2,2'-Bis(diphenylphosphino)bip
  • {2-[2-(diphenylphosphanyl)phenyl]phenyl}diphenylphosphane
  • 98% BIPHEP
  • 1,1'-[[1,1'-Biphenyl]-2,2'-diyl]bis[1,1-diphenylphosphine]
  • 2,2'-Bis(diphenylphosphino)-1
  • 2,2'-Bis(diphenylphosphino)biphenyl &gt
  • 2,2'-Bis(diphenyL
  • phosphino)-1,1'-biphenyL
  • 2,2'-Bis(diphenylphosphino)biphenyl
  • 2,2'-Bis(diphenylphosphino)-1,1'-biphenyl
  • 2,2'-Bis(diphenylphosphino)-1,1'-biphenyl,98% BIPHEP
  • 84783-64-2
  • C36H28P2
  • Phosphine Ligands
  • Achiral Phosphine
  • Aryl Phosphine
  • Phosphines
  • Biphenyl & Diphenyl ether
  • Phosphine Ligands
  • Synthetic Organic Chemistry