2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL

ChemicalBook > CAS DataBase List > 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL

Reaction

Product Name: 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
CAS No.: 84783-64-2
Chemical Name: 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
Synonyms: BIPHEP;98% BIPHEP;2,2'-Bis(diphenyL;phosphino)-1,1'-biphenyL;2,2'-Bis(diphenylphosphino)-1;2,2'-Bis(diphenylphosphino)bip;2,2'-Bis(diphenylphosphino)biphenyl;2,2'-Bis(diphenylphosphino)biphenyl >2,2’-Bis(diphenylphospino)-1,1’-biphenyl;2,2'-Bis(diphenylphosphino)-1,1'-biphenyl
CBNumber: CB3357299
Molecular Formula: C36H28P2
Formula Weight: 522.55
MOL File: 84783-64-2.mol

Less

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Property

Melting point:: 210-214 °C
Boiling point:: 635.5±48.0 °C(Predicted)
solubility: soluble in Toluene
form: crystal
color: white

Less

Safety

Hazard Codes: Xi
Risk Statements: 36/37/38-36
Safety Statements: 37/39-26
TSCA: No
HS Code: 29310099

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word: Warning
Hazard statements: H319Causes serious eye irritation
Precautionary statements: P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: CDS020234
Product name: 2,2′-Bis(diphenylphosphino)-1,1′-biphenyl
Purity: AldrichCPR
Packaging: 25MG
Price: $70.9
Updated: 2024/03/01

TCI Chemical

Product number: B2630
Product name: 2,2'-Bis(diphenylphosphino)biphenyl
Purity: >98.0%(GC)
Packaging: 1g
Price: $163
Updated: 2024/03/01

TCI Chemical

Product number: B2630
Product name: 2,2'-Bis(diphenylphosphino)biphenyl
Purity: >98.0%(GC)
Packaging: 100mg
Price: $29
Updated: 2024/03/01

Alfa Aesar

Product number: H31306
Product name: 2,2'-Bis(diphenylphosphino)biphenyl, 98%
Packaging: 1g
Price: $178.65
Updated: 2024/03/01

Alfa Aesar

Product number: H31306
Product name: 2,2'-Bis(diphenylphosphino)biphenyl, 98%
Packaging: 5g
Price: $583.65
Updated: 2024/03/01

Less

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Chemical Properties,Usage,Production

Reaction

Supporting ligand in a chiral diamine-ruthenium system for the enantioselective hydrogenation of ketones.
Useful ligand for palladium-catalyzed amination and Kumada cross-coupling reactions
Useful ligand for palladium-catalyzed synthesis of butatrenes.
Useful ligand for iridium-catalyzed C-C cross-coupling of allenes with primary alcohols via transfer hydrogenation.
Useful ligand for iridium-catalyzed C-C cross-coupling of dienes with primary alcohols via transfer hydrogenation.
Useful ligand for iridium-catalyzed C-C cross-coupling of allylic gem-dicarboxylates with aldehydes via transfer hydrogenation.
Useful ligand for the palladium-catalyzed synthesis of chiral allenylsilanes.
Ruthenium-catalyzed synthesis of indoles.
Ruthenium-catalyzed oxidative cyclization.
Rhodium-catalyzed boron arylation.

Chemical Properties

white crystalline powder or crystals

Uses

2,2''-Bis(diphenylphosphino)-1,1’-biphenyl (CAS# 84783-64-2) is a chelating phosphine and has been used to study the effects of bite angles on the chemical and physical properties of transition metal complexes. 2,2''-Bis(diphenylphosphino)-1,1’-biphenyl appears as a catalytic ligand in Ni- and Pd-Catalyzed cross-electrophile coupling reactions to form highly substituted 1,3-dienes.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Preparation Products And Raw materials

Raw materials

Preparation Products

Less

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Suppliers

Americas 1 Belgium 1 China 99 Europe 1 Germany 3 India 2 Japan 2 Norway 1 Russia 1 The Netherlands 1 United Kingdom 2 United States 6 Global 120

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Beijing Donghualituo Techonlogy Development Co.,Ltd.

Tel: 010-88425576
Fax: (+86)-10-88425546
Email: sales@dhltchem.com
Country: China
ProdList: 793
Advantage: 59

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

ShangHai DEMO Chemical Co.,Ltd

Tel: 400-021-7337 2355568890
Fax: 0086-21-50182339
Email: sales@demochem.com
Country: China
ProdList: 2572
Advantage: 57

Beijing HwrkChemical Technology Co., Ltd

Tel: 010-89508211 18501085097
Fax: 010-89508210
Email: sales.bj@hwrkchemical.com
Country: China
ProdList: 9371
Advantage: 55

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44733
Advantage: 61

Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Email: sales@capotchem.com
Country: China
ProdList: 18207
Advantage: 66

Chengdu Ai Keda Chemical Technology Co., Ltd.

Tel: 4008-755-333 18080918076
Fax: 028-86757656
Email: 800078821@qq.com
Country: China
ProdList: 9718
Advantage: 55

T&W GROUP

Tel: 021-61551611 13296011611
Fax: ＋86 21-50676805
Email: contact@trustwe.com
Country: China
ProdList: 9895
Advantage: 58

Shanghai civi chemical technology co.,Ltd

Tel: 86-21-34053660
Fax: 86-21-34053661
Email: sale@labgogo.com
Country: China
ProdList: 9865
Advantage: 52

Thermo Fisher Scientific

Tel: 800-810-5118
Fax: +86-10-84193589
Email: cnchemical@thermofisher.com
Country: China
ProdList: 17770
Advantage: 75

Shanghai T&W Pharmaceutical Co., Ltd.

Tel: +86 21 61551611
Fax: +86 21 50676805
Country: China
ProdList: 9891
Advantage: 58

Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.

Tel: 025-66099280 17798518460
Fax: (1)02557626880
Email: cfzhang@aikonchem.com
Country: China
ProdList: 19915
Advantage: 55

Shanghai Jian Chao Chemical Technology Co., Ltd.

Tel: 0-1502103-5486 18017383231
Fax: qq：2817624287
Email: 983544897@qq.com
Country: China
ProdList: 9347
Advantage: 55

Shanghai Incat Chemtech Co.,Ltd.

Tel: 021-57603038 13601791340
Fax: 021-57603057
Email: 307593986@qq.com
Country: China
ProdList: 475
Advantage: 58

9ding chemical ( Shanghai) Limited

Tel: 4009209199
Fax: 86-021-52271987
Email: sales@9dingchem.com
Country: China
ProdList: 22514
Advantage: 55

Shanghai Aladdin Bio-Chem Technology Co.,LTD

Tel: 400-6206333 1316706386
Fax: 021-50323701
Email: anhua.mao@aladdin-e.com
Country: China
ProdList: 25003
Advantage: 65

The future of Shanghai Industrial Co., Ltd.

Tel: 021-61552785
Fax: 021-55660885
Email: sales@shshiji.com
Country: China
ProdList: 9545
Advantage: 55

Huainan Kedi Chemical Factory

Tel: 0554-2106669
Fax: 0554-2666215
Email: sales1@kedichem.com
Country: China
ProdList: 4924
Advantage: 55

Bide Pharmatech Ltd.

Tel: 400-164-7117 13681763483
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 41457
Advantage: 60

Chengdu HuaXia Chemical Reagent Co. Ltd

Tel: 400-1166-196 13458535857
Fax: QQ：800101999
Email: cdhxsj@163.com
Country: China
ProdList: 13350
Advantage: 58

Codow Chemical Co.,Ltd.

Tel: 18620099427
Fax: +86-20-62619665
Email: amy@howeipharm.com
Country: China
ProdList: 17687
Advantage: 55

Shanghai YuanYe Biotechnology Co., Ltd.

Tel: 021-61312847; 18021002903
Fax: QQ:3008007432
Email: 3008007409@qq.com
Country: China
ProdList: 71829
Advantage: 60

Shanghai SuperLan Chemcial Technique Centre

Tel: 021-2022843681 15618226720
Fax: +86-21-51601218
Email: lucy@atkchemical.com
Country: China
ProdList: 10979
Advantage: 58

Beijing Solarbio Science & Tecnology Co., Ltd.

Tel: 010-50973130 4009686088
Email: 3193328036@qq.com
Country: China
ProdList: 29763
Advantage: 68

Amadis Chemical Company Limited

Tel: 571-89925085
Fax: 0086-571-89925065
Email: sales@amadischem.com
Country: China
ProdList: 131957
Advantage: 58

Guangdong wengjiang Chemical Reagent Co., Ltd.

Tel: 0751-2886750 13927877953
Fax: 0751-2886750
Email: 3005811397@qq.com
Country: China
ProdList: 13320
Advantage: 58

Beijing Jin Ming Biotechnology Co., Ltd.

Tel: 010-60605840 18892239720
Fax: 010-60605840
Email: psaitong@jm-bio.com
Country: China
ProdList: 12306
Advantage: 58

LaaJoo

Tel: 021-60702684 18516024827
Email: huang.jiayi@sinocompound.com
Country: China
ProdList: 2291
Advantage: 58

Amatek Scientific Co. Ltd.

Tel: 0512-56316828
Fax: 0512-56316826
Email: info@amateksci.com
Country: China
ProdList: 28804
Advantage: 58

Shanghai Haohong Pharmaceutical Co., Ltd.

Tel: 400-8210725 18016230971
Fax: 021-58955996
Email: malulu@leyan.com
Country: China
ProdList: 24987
Advantage: 58

Domole Scientific

Tel: 13275595566 13275595566
Fax: -
Email: domole.infsci@outlook.com
Country: China
ProdList: 300
Advantage: 58

3A Chemicals

Tel: 400-668-9898
Fax: 010-51582189
Email: service@3achem.com
Country: China
ProdList: 20557
Advantage: 58

Shanghai Anyinuo Biomedical Technology Co., Ltd.

Tel: 021-34625901
Email: 420970979@qq.com
Country: China
ProdList: 5826
Advantage: 58

Shanghai neon biological technology co., LTD

Tel: 021-54252912-8903
Email: leona.xin@forneeds.cn
Country: China
ProdList: 4759
Advantage: 58

Shanghai Jizhi Biochemical Technology Co. Ltd.

Tel: 4009004166/18616739031 18616739031
Email: 3007523370@qq.com
Country: China
ProdList: 52693
Advantage: 58

Henan Alfa Chemical Co., Ltd

Tel
Country: China
ProdList: 13194
Advantage: 58

Hefei TNJ Chemical Industry Co.,Ltd.

Tel: +86-0551-65418684 +8618949823763
Fax: 0086-551-65418684
Email: sales@tnjchem.com
Country: China
ProdList: 25356
Advantage: 58

CD Chemical Group Limited

Tel: +8615986615575
Fax: 0086-13651442114
Email: info@codchem.com
Country: China
ProdList: 20342
Advantage: 58

Dayang Chem (Hangzhou) Co.,Ltd.

Tel: 571-88938639 +8617705817739
Fax: +86-571-88938652，+86-571- 88492614
Email: info@dycnchem.com
Country: China
ProdList: 52849
Advantage: 58

HUNAN CHEMFISH SCIENTIFIC CO.,LTD

Tel: 0731-+86-0731-85567275 18932438858
Fax: QQ:3554193828
Email: sales05@chemfish.com
Country: China
ProdList: 6660
Advantage: 58

Henan Weituxi Chemical Technology Co., Ltd.

Tel: 0371-63284658 18135795563
Fax: QQ:2885349392
Email: 2885349392@qq.com
Country: China
ProdList: 9978
Advantage: 58

Chemwill Asia Co.,Ltd.

Tel: 86-21-51086038
Fax: 86-21-51861608
Email: chemwill_asia@126.com
Country: CHINA
ProdList: 23912
Advantage: 58

Hubei Jusheng Technology Co.,Ltd.

Tel: 18871490254
Fax: 027-59599243
Email: linda@hubeijusheng.com
Country: CHINA
ProdList: 28172
Advantage: 58

Hebei Chuanghai Biotechnology Co., Ltd

Tel: +86-15531157085 +86-15531157085
Fax: whatapp+8619930503282
Email: abby@chuanghaibio.com
Country: China
ProdList: 8809
Advantage: 58

Shanghai Jiange Chemical Co., Ltd.

Tel: 15921040873
Email: 1434142450@qq.com
Country: CHINA
ProdList: 7649
Advantage: 58

Henan Lien Chemical Products Co., Ltd.

Tel: 0371-63357898 15378766539
Email: 535046669@qq.com
Country: China
ProdList: 4027
Advantage: 58

Zhengzhou Edward Biology Co.,Ltd

Tel: 0371-63682289 15538176268
Fax: QQ：1875164801
Email: jacschem@163.com
Country: China
ProdList: 9971
Advantage: 58

Less

View Lastest Price from 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL manufacturers

Hebei Chuanghai Biotechnology Co., Ltd

Product: 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL 84783-64-2
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 mt
Release date: 2024-11-14

Shaanxi Dideu Medichem Co. Ltd

Product: 2,2'-Bis(diphenylphosphino)biphenyl 84783-64-2
Price: US $1.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 tons
Release date: 2020-01-16

84783-64-2, 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYLRelated Search:

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL R-(+)-2,2''-BIS(DIPHENYLPHOSPHINO)-1,1''-BIPHENYL (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) [(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II) chloride (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& 3',6'-BIS(DIETHYLAMINO)-2-(4-NITROPHENYL)SPIRO[ISOINDOLE-1,9'-XANTHENE]-3-ONE Diphenylphosphine DICHLORO[(R)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(R)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II) PHOSPHINE OXIDE, [1,1'-BINAPHTHALENE]-2,2'-DIYLBIS DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) DICHLORO[(S)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(S)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II) (R)-H8-BINAP (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE (R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Chloro[(R)-(+)-5,5'-dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl](p-cymene)ruthenium(II)chlorideCH2Cl2adduct

BIPHEP

[2-(2-diphenylphosphinophenyl)phenyl]-diphenylphosphine

2,2'-Bis(diphenylphosphino)-1,1'-biphenyl,98%BIPHEP

2,2'-Bis(diphenylphosphino)-1,1'-biphenyl, (BIPHEP)

2,2’-Bis(diphenylphospino)-1,1’-biphenyl

PHOSPHINE, 1,1''-[[1,1''-BIPHENYL]-2,2''-DIYL]BIS[1,1-DIPHENYL-

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL,98%

2,2'-Bis(diphenylphosphino)bip

{2-[2-(diphenylphosphanyl)phenyl]phenyl}diphenylphosphane

98% BIPHEP

1,1'-[[1,1'-Biphenyl]-2,2'-diyl]bis[1,1-diphenylphosphine]

2,2'-Bis(diphenylphosphino)-1

2,2'-Bis(diphenylphosphino)biphenyl &gt

2,2'-Bis(diphenyL

phosphino)-1,1'-biphenyL

2,2'-Bis(diphenylphosphino)biphenyl

2,2'-Bis(diphenylphosphino)-1,1'-biphenyl

2,2'-Bis(diphenylphosphino)-1,1'-biphenyl,98% BIPHEP

2,2''-Bis(diphenylphosphino)-1,1''-biphenyl

84783-64-2

C36H28P2

Phosphine Ligands

Achiral Phosphine

Aryl Phosphine

Phosphines

Biphenyl & Diphenyl ether

Phosphine Ligands

Synthetic Organic Chemistry