2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL

ChemicalBook > CAS DataBase List > 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL

Reaction

Product Name: 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
CAS No.: 84783-64-2
Chemical Name: 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
Synonyms: BIPHEP;98% BIPHEP;2,2'-Bis(diphenyL;phosphino)-1,1'-biphenyL;2,2'-Bis(diphenylphosphino)-1;2,2'-Bis(diphenylphosphino)bip;2,2'-BIS(DIPHENYLPHOSPHINO)BIPHENYL;2,2'-Bis(diphenylphosphino)biphenyl;2,2'-Bis(diphenylphosphino)biphenyl >2,2’-Bis(diphenylphospino)-1,1’-biphenyl
CBNumber: CB3357299
Molecular Formula: C36H28P2
Formula Weight: 522.55
MOL File: 84783-64-2.mol

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2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Property

Melting point:: 210-214 °C
Boiling point:: 635.5±48.0 °C(Predicted)
solubility: soluble in Toluene
form: crystal
color: white

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38-36
Safety Statements: 37/39-26
TSCA: No
HS Code: 29310099

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word: Warning
Hazard statements: H319Causes serious eye irritation
Precautionary statements: P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: CDS020234
Product name: 2,2′-Bis(diphenylphosphino)-1,1′-biphenyl
Purity: AldrichCPR
Packaging: 25MG
Price: $70.9
Updated: 2024/03/01

TCI Chemical

Product number: B2630
Product name: 2,2'-Bis(diphenylphosphino)biphenyl
Purity: >98.0%(GC)
Packaging: 1g
Price: $163
Updated: 2024/03/01

TCI Chemical

Product number: B2630
Product name: 2,2'-Bis(diphenylphosphino)biphenyl
Purity: >98.0%(GC)
Packaging: 100mg
Price: $29
Updated: 2024/03/01

Alfa Aesar

Product number: H31306
Product name: 2,2'-Bis(diphenylphosphino)biphenyl, 98%
Packaging: 1g
Price: $178.65
Updated: 2024/03/01

Alfa Aesar

Product number: H31306
Product name: 2,2'-Bis(diphenylphosphino)biphenyl, 98%
Packaging: 5g
Price: $583.65
Updated: 2024/03/01

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2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Chemical Properties,Usage,Production

Reaction

Supporting ligand in a chiral diamine-ruthenium system for the enantioselective hydrogenation of ketones.
Useful ligand for palladium-catalyzed amination and Kumada cross-coupling reactions
Useful ligand for palladium-catalyzed synthesis of butatrenes.
Useful ligand for iridium-catalyzed C-C cross-coupling of allenes with primary alcohols via transfer hydrogenation.
Useful ligand for iridium-catalyzed C-C cross-coupling of dienes with primary alcohols via transfer hydrogenation.
Useful ligand for iridium-catalyzed C-C cross-coupling of allylic gem-dicarboxylates with aldehydes via transfer hydrogenation.
Useful ligand for the palladium-catalyzed synthesis of chiral allenylsilanes.
Ruthenium-catalyzed synthesis of indoles.
Ruthenium-catalyzed oxidative cyclization.
Rhodium-catalyzed boron arylation.

Chemical Properties

white crystalline powder or crystals

Uses

2,2''-Bis(diphenylphosphino)-1,1’-biphenyl (CAS# 84783-64-2) is a chelating phosphine and has been used to study the effects of bite angles on the chemical and physical properties of transition metal complexes. 2,2''-Bis(diphenylphosphino)-1,1’-biphenyl appears as a catalytic ligand in Ni- and Pd-Catalyzed cross-electrophile coupling reactions to form highly substituted 1,3-dienes.

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Preparation Products And Raw materials

Raw materials

Preparation Products

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2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Suppliers

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View Lastest Price from 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: 2,2'-Bis(diphenylphosphino)biphenyl 84783-64-2
Price: US $1.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 tons
Release date: 2020-01-16

Hebei Guanlang Biotechnology Co., Ltd.

Product: 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL 84783-64-2
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 mt
Release date: 2023-04-07

84783-64-2, 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYLRelated Search:

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL R-(+)-2,2''-BIS(DIPHENYLPHOSPHINO)-1,1''-BIPHENYL (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) [(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II) chloride (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& 3',6'-BIS(DIETHYLAMINO)-2-(4-NITROPHENYL)SPIRO[ISOINDOLE-1,9'-XANTHENE]-3-ONE Diphenylphosphine DICHLORO[(R)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(R)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II) PHOSPHINE OXIDE, [1,1'-BINAPHTHALENE]-2,2'-DIYLBIS DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) DICHLORO[(S)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(S)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II) (R)-H8-BINAP (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE (R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Chloro[(R)-(+)-5,5'-dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl](p-cymene)ruthenium(II)chlorideCH2Cl2adduct

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL

2,2'-BIS(DIPHENYLPHOSPHINO)BIPHENYL

BIPHEP

[2-(2-diphenylphosphinophenyl)phenyl]-diphenylphosphine

2,2'-Bis(diphenylphosphino)-1,1'-biphenyl,98%BIPHEP

2,2'-Bis(diphenylphosphino)-1,1'-biphenyl, (BIPHEP)

2,2’-Bis(diphenylphospino)-1,1’-biphenyl

PHOSPHINE, 1,1''-[[1,1''-BIPHENYL]-2,2''-DIYL]BIS[1,1-DIPHENYL-

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL,98%

2,2'-Bis(diphenylphosphino)bip

{2-[2-(diphenylphosphanyl)phenyl]phenyl}diphenylphosphane

98% BIPHEP

1,1'-[[1,1'-Biphenyl]-2,2'-diyl]bis[1,1-diphenylphosphine]

2,2'-Bis(diphenylphosphino)-1

2,2'-Bis(diphenylphosphino)biphenyl &gt

2,2'-Bis(diphenyL

phosphino)-1,1'-biphenyL

2,2'-Bis(diphenylphosphino)biphenyl

2,2'-Bis(diphenylphosphino)-1,1'-biphenyl

84783-64-2

C36H28P2

Phosphine Ligands

Achiral Phosphine

Aryl Phosphine

Phosphines

Biphenyl & Diphenyl ether

Phosphine Ligands

Synthetic Organic Chemistry