1,1,1-Trifluoro-2,3-epoxypropane
- Product Name
- 1,1,1-Trifluoro-2,3-epoxypropane
- CAS No.
- 359-41-1
- Chemical Name
- 1,1,1-Trifluoro-2,3-epoxypropane
- Synonyms
- 2-(TRIFLUOROMETHYL)OXIRANE;uoro-2,3-epoxypropane;(Trifluoromethyl)oxirane;3,3,3-trifluoropropene oxide;Oxirane, 2-(trifluoromethyl)-;3,3,3-Trifluoropropane epoxide;1,2-EPOXY-3,3,3-TRIFLUOROPROPA;3,3,3-Tifluoro-1,2-epoxypropane;3,3,3-TRIFLUORO-1,2-EPOXYPROPANE;1,1,1-TRIFLUORO-2,3-EPOXYPROPANE
- CBNumber
- CB3368693
- Molecular Formula
- C3H3F3O
- Formula Weight
- 112.05
- MOL File
- 359-41-1.mol
1,1,1-Trifluoro-2,3-epoxypropane Property
- Boiling point:
- 38 °C
- Density
- 1,3 g/cm3
- refractive index
- 1.2997
- Flash point:
- -40°C
- storage temp.
- Inert atmosphere,Store in freezer, under -20°C
- Specific Gravity
- 1.3068
- Water Solubility
- Not miscible with water.
- Sensitive
- Moisture Sensitive
- BRN
- 103730
- InChI
- InChI=1S/C3H3F3O/c4-3(5,6)2-1-7-2/h2H,1H2
- InChIKey
- AQZRARFZZMGLHL-UHFFFAOYSA-N
- SMILES
- O1CC1C(F)(F)F
- CAS DataBase Reference
- 359-41-1(CAS DataBase Reference)
- NIST Chemistry Reference
- 3,3,3-Trifluoro-1,2-epoxypropane(359-41-1)
Safety
- Hazard Codes
- F,T
- Risk Statements
- 11-20/21/22-36/37/38
- Safety Statements
- 16-26-36-36/37-9
- RIDADR
- 1993
- Hazard Note
- Flammable/Toxic/Keep Cold
- HazardClass
- 3
- PackingGroup
- II
- HS Code
- 29109000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H302Harmful if swallowed
H312Harmful in contact with skin
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- L09869
- Product name
- 1,2-Epoxy-3,3,3-trifluoropropane, 98%
- Packaging
- 1g
- Price
- $74.65
- Updated
- 2024/03/01
- Product number
- L09869
- Product name
- 1,2-Epoxy-3,3,3-trifluoropropane, 98%
- Packaging
- 5g
- Price
- $249.65
- Updated
- 2024/03/01
- Product number
- T898545
- Product name
- 1,1,1-Trifluoro-2,3-Epoxypropane
- Packaging
- 500mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- 2109-3-02
- Product name
- 2-(Trifluoromethyl)oxirane
- Purity
- 98%
- Packaging
- 5G
- Price
- $35
- Updated
- 2021/12/16
- Product number
- PC7296
- Product name
- 3,3,3-Trifluoro-1,2-propenoxide
- Purity
- 98%
- Packaging
- 5g
- Price
- $36
- Updated
- 2021/12/16
1,1,1-Trifluoro-2,3-epoxypropane Chemical Properties,Usage,Production
Uses
1,2-Epoxy-3,3,3-trifluoropropane is used for the synthesis of trifluorolactic acid. It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and Dyestuff.
Synthesis
31g of sodium hydroxide (3.28equiv.: 0.781mol)-water 60ml solution under ice-cooling, 50g bromohydrin form obtained in Example 6 (0.238mol) was added and the internal temperature was raised to 61 oC gas generated was collected outside the reactor, condensed in a trap cooled to -78 oC, 1,1,1-trifluoro-2 ,3-epoxypropane was obtained in 84% yield. This was analyzed by 1H-NMR, 19F-NMR. 19F-NMR: (acetone weight):-86.90ppm (3F, d) 1H-NMR: (acetone weight): 2.90ppm (1H, m) 2.96ppm (1H, d d), 3.40ppm (1H, m)
Synthesis
To an autoclave (stainless steel, volume:1L) equipped with a mixing tank and a stirrer, C4F9I which compound (1) flow rate 25mL/min, CF2=CF2 (tetrafluoroethylene) which compound (2) flow rate 0.37g/min, (C2F5COO)2 (10 and half hour life temperature: 31°C) which compound (4) flow rate 0.052 mmol/min were supplied, the mixture was prepared by mixing at stirrer. Temperature in the autoclave was 10°C, residence time of the mixture in the autoclave was 10 minutes. The molar ratio (C4F9I/CF2=CF2)of C4F9I and CF2=CF2 in the mixed solution was 41, the amount of (C2F5COO)2 with respect to C4F9I was 0.034 mol%. Only the mixture from the bottom of the autoclave was withdrawn in the absence of gas phase, the mixture was fed to the bottom of tubular reactor (Tankan-shiki, volume: 0.5L). The mixture was not seperated by gas-liquid separation, the mixture was flow towards the outlet from the inlet of the reaction tube in the tube reactor. The temperature of the reaction tube, and a 70°C, the residence time of the mixture in the tubular reactor was set to 20 minutes. The mixture containing a compound (3) C6F13I was obtained.
1,1,1-Trifluoro-2,3-epoxypropane Preparation Products And Raw materials
Raw materials
Preparation Products
1,1,1-Trifluoro-2,3-epoxypropane Suppliers
- Tel
- 571-89189769 15168342188
- Fax
- 0571-86205065
- Country
- China
- ProdList
- 281
- Advantage
- 62
- Tel
- 021-021-65170832 13331983812
- qinba_2@163.com
- Country
- China
- ProdList
- 301
- Advantage
- 58
- Tel
- 010-82848833 400-666-7788
- Fax
- 86-10-82849933
- jkinfo@jkchemical.com
- Country
- China
- ProdList
- 96815
- Advantage
- 76
- Tel
- 400-6106006
- Fax
- 021-67582001/03/05
- saleschina@alfa-asia.com
- Country
- China
- ProdList
- 30132
- Advantage
- 84
- Tel
- 021-021-58432009 400-005-6266
- Fax
- 021-58436166
- sales8178@energy-chemical.com
- Country
- China
- ProdList
- 44751
- Advantage
- 61
- Tel
- 0573-85285100 18627885956
- Fax
- 0573-85285100
- isenchem@163.com
- Country
- China
- ProdList
- 9551
- Advantage
- 66
- Tel
- 021-58099652-8005 13585536065
- Fax
- 021-58099609
- bin.wu@shlschem.com
- Country
- China
- ProdList
- 9816
- Advantage
- 59
- Tel
- 025-83697070
- Fax
- +86-25-83453306
- info@chemlin.com.cn
- Country
- China
- ProdList
- 17987
- Advantage
- 64
- Tel
- 0086-21-58956006
- Fax
- 0086-21-58956100
- Country
- China
- ProdList
- 7815
- Advantage
- 57
- Tel
- +8618575662672 18575662672
- Fax
- 021 51613951
- mzeng@3wpharm.com
- Country
- China
- ProdList
- 9747
- Advantage
- 57
View Lastest Price from 1,1,1-Trifluoro-2,3-epoxypropane manufacturers
- Product
- 1,1,1-Trifluoro-2,3-epoxypropane 359-41-1
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-10-08
- Product
- 1,1,1-Trifluoro-2,3-epoxypropane 359-41-1
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98.7%
- Supply Ability
- 100 tons
- Release date
- 2022-02-18
- Product
- 1,1,1-Trifluoro-2,3-epoxypropane 359-41-1
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 95%
- Supply Ability
- 500KG
- Release date
- 2018-08-19