ChemicalBook > CAS DataBase List > LINAMARIN

LINAMARIN

Product Name: LINAMARIN
CAS No.: 554-35-8
Chemical Name: LINAMARIN
Synonyms: LINAMARIN;Linamarine;PHASEOLUNATIN;Phaseolunatine;Linamarin min. 99%;LINAMARIN(RG) 10mg;Phaseolunatin =Linamarin;Linamarin 100 μg/ml Acetonitrile;α-Hydroxyisobutyronitrile β-D-Glucose;alpha-hydroxyisobutyronitrile-beta-d-glucose
CBNumber: CB3399987
Molecular Formula: C10H17NO6
Formula Weight: 247.25
MOL File: 554-35-8.mol

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LINAMARIN Property

Melting point:: 142-143°C
alpha: D18 -29°
Boiling point:: 390.28°C (rough estimate)
Density: 1.2868 (rough estimate)
refractive index: 1.4610 (estimate)
storage temp.: 2-8°C
solubility: Soluble in DMSO, Methanol, and Ethanol
form: solid
pka: 12.73±0.70(Predicted)
color: White or off-white
optical activity: [α]/D -26.5±2.0°, c = 1 in H2O
Stability:: Acid Sensitive
InChI: InChI=1/C10H17NO6/c1-10(2,4-11)17-9-8(15)7(14)6(13)5(3-12)16-9/h5-9,12-15H,3H2,1-2H3/t5-,6-,7+,8-,9+/s3
InChIKey: QLTCHMYAEJEXBT-QHXZDXPMNA-N
SMILES: [C@H]1(OC(C)(C)C#N)[C@H](O)[C@H]([C@H](O)[C@@H](CO)O1)O |&1:0,7,9,10,12,r|

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Safety

Hazard Codes: Xn
Risk Statements: 20/22-36/37/38
Safety Statements: 26-36
WGK Germany: 3
RTECS: TZ4850000
HS Code: 29400090
Hazardous Substances Data: 554-35-8(Hazardous Substances Data)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 68264
Product name: α-Hydroxyisobutyronitrile β-D-glucopyranoside
Purity: ≥98.0% (HPLC)
Packaging: 50mg
Price: $413
Updated: 2025/07/31

Cayman Chemical

Product number: 20532
Product name: Linamarin
Purity: ≥98%
Packaging: 1mg
Price: $32
Updated: 2024/03/01

Cayman Chemical

Product number: 20532
Product name: Linamarin
Purity: ≥98%
Packaging: 5mg
Price: $63
Updated: 2024/03/01

Cayman Chemical

Product number: 20532
Product name: Linamarin
Purity: ≥98%
Packaging: 10mg
Price: $109
Updated: 2024/03/01

Cayman Chemical

Product number: 20532
Product name: Linamarin
Purity: ≥98%
Packaging: 25mg
Price: $230
Updated: 2024/03/01

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LINAMARIN Chemical Properties,Usage,Production

Description

Linamarin is a glucoside of acetone cyanohydrin found in the leaves and roots of cassava, lima beans, and flax. It is thought to function in the transport of nitrogen from plant leaves to roots in young plants but also serves as a plant defense mechanism. Linamarin is converted to toxic hydrocyanic acid or prussic acid when it comes into contact with linamarase, an enzyme that is released when the cells of cassava roots are ruptured.

Chemical Properties

White Crystalline Solid

Uses

Can be found in the seed skins and embryos of flax.

Definition

ChEBI: Linamarin is a beta-D-glucoside. It is functionally related to a 2-hydroxy-2-methylpropanenitrile.

References

[1] Convergent evolution in biosynthesis if cyanogenic defense compounds in plants
[2] EDUARDO RIVADENEYRA-DOMÍNGUEZ . Neurotoxic effect of linamarin in rats associated with cassava (Manihot esculenta Crantz) consumption[J]. Food and Chemical Toxicology, 2013, 59: Pages 230-235. DOI:10.1016/j.fct.2013.06.004
[3] S KIMANI. Memory deficits associated with sublethal cyanide poisoning relative to cyanate toxicity in rodents.[J]. Metabolic brain disease, 2014, 29 1: 105-112. DOI:10.1007/s11011-013-9459-2

LINAMARIN Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from LINAMARIN manufacturers

Career Henan Chemical Co

Product: LINAMARIN 554-35-8
Price: US $7.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100KG
Release date: 2020-01-09

554-35-8, LINAMARINRelated Search:

Mupirocin ETHYLENE GLYCOL MONO-TERT-BUTYL ETHER Acetone cyanohydrin 1-TERT-BUTOXY-2-PROPANOL LINAMARIN Methoxyacetonitrile 3-Ethoxypropionitrile 2-HYDROXYPROPIONITRILE (+/-)-1-TERT-BUTYLGLYCEROL T-BUTYL D-GLUCOSIDE (S)-(-)-2-METHOXYPROPIONITRILE 2,3,4,6-TETRA-O-ACETYL LINAMARIN LINUSTATIN 3-TERT.-BUTYLOXY-1-PROPANOL LOTAUSTRALIN NEOLINUSTATIN LINAMARIN(RG) 2-(á-D-GLUCOPYRANOSYLOXY)-2-METHYL-PROPANENITRILE; PHASEOLUNATIN =LINAMARIN

Phaseolunatin =Linamarin

alpha-hydroxyisobutyronitrile-beta-d-glucose

2-(?D-Glucopyranosyloxy)-2-methyl-propanenitrile

2-(alpha-D-Glucopyranosyloxy)-2-methylpropanenitrile

Linamarine

Phaseolunatine

2-(b-D-Glucopyranosyloxy)-2-methyl-propanenitrile

2-(D-GLUCOPYRANOSYLOXY)-2-METHYL-PROPANENITRILE,PHASEOLUNATIN=LINAMARIN

2-(beta-d-glucopyranosyloxy)-2-methyl-propanenitril

2-(beta-d-glucopyranosyloxy)isobutyronitrile

ALPHA-HYDROXYISOBUTYRONITRILE-BETA-D-GLUCOPYRANOSIDE

2-(BETA-D-GLUCOPYRANOSYLOXY)-2-METHYL-PROPANENITRILE

LINAMARIN

α-Hydroxyisobutyronitrile β-D-glucopyranoside

α-Hydroxyisobutyronitrile β-D-glucose, 2-(β-D-Glucopyranosyloxy)-2-methylpropionitrile, Linamarin

2-methyl-2-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxypropanenitrile

2-methyl-2-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-propanenitrile

2-methyl-2-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-methylol-tetrahydropyran-2-yl]oxy-propionitrile

α-Hydroxyisobutyronitrile β-D-Glucose

2-(beta-D-Glucopyranosyloxy)-2-methyl-propanenitrile, Phaseolunatin

Linamarin min. 99%

2-(β-D-Glucopyranosyloxy)-2-methylpropionitrile

PHASEOLUNATIN

Propanenitrile, 2-(β-D-glucopyranosyloxy)-2-methyl-

α-Hydroxyisobutyronitrile-beta-D-glucopyranoside

Linamarin 100 μg/ml Acetonitrile

LINAMARIN(RG) 10mg

554-35-8

CH32CCNOC6H11O5

Carbohydrates & Derivatives