1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE
- Product Name
- 1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE
- CAS No.
- 17082-61-0
- Chemical Name
- 1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE
- Synonyms
- 1,2-BIS(TRIMETHYLSILOXY)CYCLOBUTENE;1,2-Bis((triMethylsilyl)oxy)cyclobut-1-ene;DK105;DK578;obutene;DKSI111;95+%(gc);oxy)cycL;Hexacosanoic acid ≥4-Aminomethylindole &ge
- CBNumber
- CB3400436
- Molecular Formula
- C10H22O2Si2
- Formula Weight
- 230.45
- MOL File
- 17082-61-0.mol
1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE Property
- Boiling point:
- 58-59 °C2 mm Hg(lit.)
- Density
- 0.897 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.435(lit.)
- Flash point:
- 142 °F
- storage temp.
- Inert atmosphere,2-8°C
- solubility
- sol hydrocarbons and ethers.
- form
- clear liquid
- color
- Colorless to Light yellow
- Specific Gravity
- 0.87
- Hydrolytic Sensitivity
- 7: reacts slowly with moisture/water
- BRN
- 1367530
- InChI
- InChI=1S/C10H22O2Si2/c1-13(2,3)11-9-7-8-10(9)12-14(4,5)6/h7-8H2,1-6H3
- InChIKey
- WOBRFSDEZREQAB-UHFFFAOYSA-N
- SMILES
- C1(O[Si](C)(C)C)CCC=1O[Si](C)(C)C
- CAS DataBase Reference
- 17082-61-0(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 293830
- Product name
- 1,2-Bis(trimethylsiloxy)cyclobutene
- Purity
- ≥95%
- Packaging
- 5g
- Price
- $148
- Updated
- 2023/01/07
- Product number
- B1768
- Product name
- 1,2-Bis(trimethylsilyloxy)cyclobutene
- Purity
- >94.0%(GC)
- Packaging
- 1g
- Price
- $54
- Updated
- 2025/07/31
- Product number
- B1768
- Product name
- 1,2-Bis(trimethylsilyloxy)cyclobutene
- Purity
- >94.0%(GC)
- Packaging
- 5g
- Price
- $158
- Updated
- 2025/07/31
- Product number
- B535288
- Product name
- 1,2-Bis(trimethylsilyloxy)cyclobutene
- Packaging
- 500mg
- Price
- $65
- Updated
- 2021/12/16
- Product number
- B535288
- Product name
- 1,2-Bis(trimethylsilyloxy)cyclobutene
- Packaging
- 100mg
- Price
- $45
- Updated
- 2021/12/16
1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE Chemical Properties,Usage,Production
Chemical Properties
clear colorless liquid
Uses
1,2-Bis(trimethylsilyloxy)cyclobutene is a useful chemical reactant used in the preparation and biological activity of serine and threonine β-lactones as inhibitors of hepatitis A virus 3C cysteine proteinase.
Application
Used as a suitable reagent for annulation processes and 4-keto ester synthesis.
General Description
Photocycloaddition of 2-cyclohexenones to 1,2-bis(trimethyl-siloxy)cyclobutene has been studied. It undergoes Aldol condensation reaction with carbonyl compounds. It reacts with Br2 to give cyclobutanedione.
Synthesis
1,2-Bis(trimethylsilyloxy)cyclobutene is prepared as a colorless liquid by acyloin condensation of Diethyl Succinate (dispersed Na in toluene or Et2O, reflux) using Chlorotrimethylsilane as trapping agent.
storage
Use in a fume hood; the compound is stable for years if stored in a tightly screw-capped bottle. Prolonged exposure to moist air leads to decomposition.
1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE manufacturers
- Product
- 1,2-Bis(trimethylsiloxy)cyclobutene >=95% 17082-61-0
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27
- Product
- 1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE 17082-61-0
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100
- Release date
- 2019-06-28