ChemicalBook > CAS DataBase List > 1,4-Bis(aminomethyl)benzene

1,4-Bis(aminomethyl)benzene

Product Name
1,4-Bis(aminomethyl)benzene
CAS No.
539-48-0
Chemical Name
1,4-Bis(aminomethyl)benzene
Synonyms
1,4-Phenylenedimethanamine;P-XYLYLENEDIAMINE;Xylenediamine;1,4-xylylenediamine;PXDA;P-XYLENE DIAMINE;p-Xylylendiamine;p-Xylilenediamine;RARECHEM AL BW 0024;PARA-XYLYLENEDIAMINE
CBNumber
CB3424450
Molecular Formula
C8H12N2
Formula Weight
136.19
MOL File
539-48-0.mol
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1,4-Bis(aminomethyl)benzene Property

Melting point:
60-63 °C(lit.)
Boiling point:
230 °C10 mm Hg(lit.)
Density 
0.9458 (rough estimate)
vapor pressure 
0.26Pa at 25℃
refractive index 
1.6210 (estimate)
Flash point:
134°C
storage temp. 
Store below +30°C.
form 
powder to lump
pka
9.46±0.10(Predicted)
color 
White to Light yellow
Water Solubility 
Soluble in water.
Sensitive 
Air Sensitive
BRN 
2206190
LogP
-0.25 at 25℃
CAS DataBase Reference
539-48-0(CAS DataBase Reference)
NIST Chemistry Reference
p-Xylylenediamine(539-48-0)
EPA Substance Registry System
1,4-Benzenedimethanamine (539-48-0)
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3259 8/PG 2
WGK Germany 
3
RTECS 
PF9000000
2-10
TSCA 
Yes
HS Code 
2921 59 90
HazardClass 
8
PackingGroup 
II
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.41656
Product name
1,4-Bis(aminomethyl)-benzene
Purity
for synthesis
Packaging
10g
Price
$84.8
Updated
2025/07/31
Sigma-Aldrich
Product number
279633
Product name
p-Xylylenediamine
Purity
99%
Packaging
5g
Price
$120.65
Updated
2025/07/31
Sigma-Aldrich
Product number
279633
Product name
p-Xylylenediamine
Purity
99%
Packaging
25g
Price
$425.6
Updated
2025/07/31
TCI Chemical
Product number
D1018
Product name
p-Xylylenediamine
Purity
>99.0%(GC)(T)
Packaging
25g
Price
$105
Updated
2025/07/31
TCI Chemical
Product number
D1018
Product name
p-Xylylenediamine
Purity
>99.0%(GC)(T)
Packaging
100g
Price
$312
Updated
2025/07/31
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1,4-Bis(aminomethyl)benzene Chemical Properties,Usage,Production

Uses

p-Xylylenediamine is

Flammability and Explosibility

Not classified

Synthesis

623-26-7

10406-25-4

539-48-0

Example 5: Hydrogenation of terephthalonitrile 1. 3.2 g of terephthalonitrile, 10.4 g of homotrimethylbenzene, 10.0 g of liquid ammonia, and 2.0 g of Pd-alumina pellets (manufactured by NE Chemcat Corporation; Pd content = 5% by weight) were added to a 100 ml autoclave. 2. the internal pressure was increased to 4.9 MPa using hydrogen. 3. The autoclave was shaken at 50 °C until the pressure no longer changed. 4. Upon completion of the reaction, the reaction product solution was analyzed and showed 94.8% conversion of terephthalonitrile, 88.8% yield of 4-cyanobenzylamine and 5.8% yield of p-phenylenediamine. 5. The isolated reaction solution was added to another 100 ml autoclave along with 10.0 g of liquid ammonia and 2.0 g of Catalyst A. The reaction solution was then added to another 100 ml autoclave. 6. The internal pressure was raised to 4.9 MPa using hydrogen again. 7. The autoclave was shaken at 50°C until the pressure no longer changed. 8. Upon completion of the reaction, the reaction product solution was analyzed and showed a conversion of 100 mol% for terephthalonitrile, a yield of 0.2 mol% for 4-cyanobenzylamine, and a yield of 92.1 mol% for p-xylene diamine.

References

[1] Patent: EP1449825, 2004, A1. Location in patent: Page 5
[2] Patent: EP1449825, 2004, A1. Location in patent: Page 5

1,4-Bis(aminomethyl)benzene Preparation Products And Raw materials

Raw materials

Preparation Products

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1,4-Bis(aminomethyl)benzene Suppliers

Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9310
Advantage
66
Shanghai Qianlai Pharmaceutical Technology Co., Ltd.
Tel
021-57216911 17740831186
Email
482109853@qq.com
Country
China
ProdList
462
Advantage
58
Guangdong Shunao Chemical Reagents Co., Ltd
Tel
19928586137
Email
19928586137@163.com
Country
China
ProdList
2939
Advantage
58
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Beijing HwrkChemical Technology Co., Ltd
Tel
18515581800 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
9400
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Nanjing Chemlin Chemical Co., Ltd
Tel
025-83697070
Fax
+86-25-83453306
Email
info@chemlin.com.cn
Country
China
ProdList
16075
Advantage
64
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View Lastest Price from 1,4-Bis(aminomethyl)benzene manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
1,4-Bis(aminomethyl)benzene 539-48-0
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2024-11-13
Shanghai UCHEM Inc.
Product
p-Xylylenediamine 539-48-0
Price
US $62.00-233.00/g
Min. Order
25g
Purity
0.97
Supply Ability
25kg
Release date
2023-11-16
Chemwill Asia Co.,Ltd.
Product
p-Xylylenediamine 1,4-Bis(aminomethyl)benzene in stock Factory 539-48-0
Price
US $1.00/KG
Min. Order
1KG
Purity
TOP 3 Factory in China
Supply Ability
Top 3 production capacity Factory
Release date
2019-04-03

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