ChemicalBook > CAS DataBase List > 4-IODO-2-METHYLPHENOL

4-IODO-2-METHYLPHENOL

Product Name
4-IODO-2-METHYLPHENOL
CAS No.
60577-30-2
Chemical Name
4-IODO-2-METHYLPHENOL
Synonyms
NISTC60577302;4-IODO-O-CRESOL;4-iodine-2-cresol;4-IODO-2-METHYLPHENOL;Phenol, 4-iodo-2-Methyl-;4-Iodo-2-Methylphenol 97%
CBNumber
CB3428160
Molecular Formula
C7H7IO
Formula Weight
234.03
MOL File
60577-30-2.mol
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4-IODO-2-METHYLPHENOL Property

Melting point:
67-68 °C(lit.)
Boiling point:
105-110 °C2 mm Hg(lit.)
Density 
1.7904 (estimate)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
pka
9.70±0.18(Predicted)
Appearance
Off-white to light brown Solid
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
337358
Product name
4-Iodo-2-methylphenol
Purity
97%
Packaging
10g
Price
$102.5
Updated
2025/07/31
TRC
Product number
I737138
Product name
4-Iodo-2-methylphenol
Packaging
500mg
Price
$60
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0066676
Product name
4-IODO-2-METHYLPHENOL
Purity
95.00%
Packaging
5G
Price
$868.1
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0066676
Product name
4-IODO-2-METHYLPHENOL
Purity
95.00%
Packaging
10G
Price
$1232.93
Updated
2021/12/16
AK Scientific
Product number
9048AB
Product name
4-Iodo-2-methylphenol
Packaging
1g
Price
$114
Updated
2021/12/16
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4-IODO-2-METHYLPHENOL Chemical Properties,Usage,Production

Uses

4-Iodo-2-methylphenol was used as starting reagent in the synthesis of an agonist for the peroxisome proliferator-activated receptor δ (PPARδ) GW501516, a potential antiobesity drug.

General Description

4-Iodo-2-methylphenol was prepared by direct iodination of 2-methylphenol in aqueous alcohol solvents by the action of a reagent prepared in situ from sodium hypochlorite and sodium iodide.

Synthesis

95-48-7

60577-30-2

General procedure for the synthesis of 4-iodo-2-cresol from o-cresol: to a stirred solution of o-cresol (1 mmol) in dichloromethane (CH2Cl2) or 1,2-dichloroethane ((CH2Cl)2) (0.1 M) was sequentially added Ph3PAuNTf2 (0.025 mmol, 19 mg; if using a 2:1 Ph3PAuNTf2 with toluene complex with toluene) and N-iodosuccinimide (NIS, 1.1 mmol, 248 mg). The reaction mixture was stirred at room temperature or reacted under reflux conditions until complete conversion of o-cresol was confirmed by thin layer chromatography (TLC) monitoring. Upon completion of the reaction, the solvent was evaporated under reduced pressure and the resulting crude product was purified by fast column chromatography using different ratios of hexane and ethyl acetate (EtOAc) as eluents, resulting in pure 4-iodo-2-cresol.

References

[1] Synlett, 2014, vol. 25, # 3, p. 399 - 402
[2] Chemistry - A European Journal, 2013, vol. 19, # 7, p. 2442 - 2449
[3] Asian Journal of Chemistry, 2018, vol. 30, # 7, p. 1659 - 1663
[4] Journal of Chemical Research, 2004, # 4, p. 294 - 295
[5] Chinese Chemical Letters, 2012, vol. 23, # 3, p. 261 - 264

4-IODO-2-METHYLPHENOL Preparation Products And Raw materials

Raw materials

Preparation Products

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4-IODO-2-METHYLPHENOL Suppliers

Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Adamas Reagent, Ltd.
Tel
400-6009262 16621234537
Fax
021-64823266
Email
chenyj@titansci.com
Country
China
ProdList
14101
Advantage
59
Nanjing Chemlin Chemical Co., Ltd
Tel
025-83697070
Fax
+86-25-83453306
Email
info@chemlin.com.cn
Country
China
ProdList
16075
Advantage
64
Wuhan ariel chemical Co., LTD.
Tel
18986259541
Fax
027-87840182
Email
sales@3stc.com
Country
China
ProdList
3764
Advantage
58
Hangzhou Sage Chemical Co., Ltd.
Tel
+86057186818502 13588463833
Fax
Pls mail us for more information!
Email
info@sagechem.com
Country
China
ProdList
10266
Advantage
58
SuZhou ShiYa Biopharmaceuticals, Inc.
Tel
86(512)5235 8471 17715136450
Fax
86(512)5235 6881
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sales@shiyabiopharm.com
Country
China
ProdList
4169
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58
Candia Thamtech Company Limited
Tel
0371-86615086 18203638366 0371-86159066 13526786601
Fax
0371-86159066
Country
China
ProdList
2015
Advantage
60
Jalor-Chem co.,LTD
Tel
0510-0510-86396359 13382276200
Email
sales@jalor-chem.com
Country
China
ProdList
997
Advantage
56
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
39966
Advantage
60
Hefei Yucheng Pharmaceutical Technology Co., Ltd.
Tel
15385513552
Email
2904539281@qq.com
Country
China
ProdList
277
Advantage
60
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View Lastest Price from 4-IODO-2-METHYLPHENOL manufacturers

Career Henan Chemical Co
Product
4-Iodo-2-methylphenol 60577-30-2
Price
US $1.00/g
Min. Order
1g
Purity
95-99%
Supply Ability
1ton
Release date
2020-01-09

60577-30-2, 4-IODO-2-METHYLPHENOLRelated Search:


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  • NISTC60577302
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  • 4-Iodo-2-Methylphenol 97%
  • 4-iodine-2-cresol
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  • ALCOHOL
  • Oxygen Compounds
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  • Aromatic Halides (substituted)