ChemicalBook > CAS DataBase List > 2-PHENYL-1,3-INDANDIONE

2-PHENYL-1,3-INDANDIONE

Product Name
2-PHENYL-1,3-INDANDIONE
CAS No.
83-12-5
Chemical Name
2-PHENYL-1,3-INDANDIONE
Synonyms
PHENINDIONE;PID;Indion;MTA2;Hedulin;2-Phenyl-1H-indene-1,3(2H)-dione;Indon;Bindan;Indema;MTA1L1
CBNumber
CB3429480
Molecular Formula
C15H10O2
Formula Weight
222.24
MOL File
83-12-5.mol
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2-PHENYL-1,3-INDANDIONE Property

Melting point:
144-148 °C(lit.)
Boiling point:
243.3 °C (0.3 mmHg)
Density 
1.1404 (rough estimate)
refractive index 
1.6600 (estimate)
Flash point:
208 °C
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Very slightly soluble in water; slightly soluble in ethanol (96%) and in ether. Solutions are yellow to red.
form 
powder to crystal
pka
pKa 4.09(H2O,t =25,I=0.1) (Uncertain)
color 
White to Light yellow
Merck 
14,7234
CAS DataBase Reference
83-12-5(CAS DataBase Reference)
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Safety

Hazard Codes 
T
Risk Statements 
25-43
Safety Statements 
36/37/39-45
RIDADR 
UN 2811 6.1/PG 3
WGK Germany 
3
RTECS 
NK6125000
HS Code 
2914.39.9000
HazardClass 
6.1(b)
PackingGroup 
III
Hazardous Substances Data
83-12-5(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

H317May cause an allergic skin reaction

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P272Contaminated work clothing should not be allowed out of the workplace.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

P363Wash contaminated clothing before reuse.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
P1029
Product name
2-Phenyl-1,3-indandione
Purity
>98.0%(GC)
Packaging
25g
Price
$70
Updated
2024/03/01
TCI Chemical
Product number
P1029
Product name
2-Phenyl-1,3-indandione
Purity
>98.0%(GC)
Packaging
250g
Price
$361
Updated
2021/12/16
Cayman Chemical
Product number
30060
Product name
Phenindione
Packaging
25mg
Price
$73
Updated
2024/03/01
Cayman Chemical
Product number
30060
Product name
Phenindione
Packaging
50mg
Price
$116
Updated
2024/03/01
Cayman Chemical
Product number
30060
Product name
Phenindione
Packaging
100mg
Price
$217
Updated
2024/03/01
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2-PHENYL-1,3-INDANDIONE Chemical Properties,Usage,Production

Description

Phenindione is an anticoagulant and vitamin K antagonist. It inhibits the reduction of vitamin K1 epoxide to vitamin K1 by vitamin K1 epoxide reductase in rat liver homogenates in a concentration-dependent manner. In vivo, phenindione (500 mg/kg) inhibits prothrombin synthesis and conversion of vitamin K1 epoxide to vitamin K1 in rats by 50 and 57%, respectively. Dietary administration of phenindione (4 mg/kg per day) inhibits aortic atherosclerosis or intracardial thrombosis in rat models of diet-induced atherosclerosis or intravascular thrombosis, respectively.

Chemical Properties

light yellow fluffy fine flakes

Uses

Oral anticoagulant (indanedione).

Uses

Like coumarin derivatives, phenindione, a compound of the indandione class, acts by altering biosynthesis of coagulant proteins in the liver. It is used for preventing and treating thrombosis, thrombophlebitis, and thromboembolism. However, because of a number of side effects such as polyurea, polydipsia, tachycardia, and others, it is rarely used in practical medicine.

Definition

ChEBI: Phenindione is a beta-diketone and an aromatic ketone. It has a role as an anticoagulant. It derives from a hydride of an indane.

brand name

Hedulin (Sanofi Aventis).

Clinical Use

Anticoagulant

Synthesis

Phenindione, 3-phenylindan-1,3-dion (24.1.16), is synthesized in two ways. The first consists of condensating benzaldehyde with phthalide in the presence of sodium ethoxide. Evidently, the resulting phenylmethylenphthalide (24.1.15) rearranges under the reaction conditions to give the desired phenindione (24.1.16). The second method consists of condensation of phenylacetic acid with phthalic anhydride, forming phenylmethylenphthalide (24.1.15), which rearranges further in the presence of sodium ethoxide to phenindione.

Drug interactions

Potentially hazardous interactions with other drugs There are many significant interactions with coumarins. Prescribe with care with regard to the following:
Anticoagulant effect enhanced by: alcohol, amiodarone, anabolic steroids, aspirin, aztreonam, bicalutamide, cephalosporins, chloramphenicol, cimetidine, ciprofloxacin, dronedarone, fibrates, clopidogrel, cranberry juice, danazol, dipyridamole, disulfiram, fibrates, grapefruit juice, levofloxacin, macrolides, metronidazole, nalidixic acid, neomycin, norfloxacin, NSAIDs, ofloxacin, paracetamol, penicillins, ritonavir, rosuvastatin, sulphonamides, thyroid hormones, testosterone, tetracyclines, tigecycline, tramadol, trimethoprim.
Anticoagulant effect decreased by: oral contraceptives, rifamycins, vitamin K.
Anticoagulant effects enhanced/reduced by: anion exchange resins, corticosteroids, dietary changes, enteral feeds.
Analgesics: increased risk of bleeding with IV diclofenac and ketorolac - avoid.
Anticoagulants: increased risk of haemorrhage with apixaban, dabigatran, edoxaban and rivaroxaban - avoid.
Ciclosporin: there have been a few reports of altered anticoagulant effect; decreased ciclosporin levels have been seen rarely

Metabolism

Hepatically metabolised. Metabolites of phenindione often colour the urine pink or orange.

Purification Methods

Crystallise the dione from EtOH (m 156o) or CHCl3 (m 148-150o). [Beilstein 7 H 808, 7 III 4100, 7 IV 2570.]

2-PHENYL-1,3-INDANDIONE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-PHENYL-1,3-INDANDIONE Suppliers

Hubei Zhixin Biopharmaceutical Technology Co., Ltd.
Tel
13163286261
Email
18672992087@163.cn
Country
China
ProdList
60
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Wuhan Yuanxing Biomedical Technology Co.,
Tel
13642377995
Email
258676831@qq.com
Country
China
ProdList
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58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
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TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
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81
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8418
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Energy Chemical
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021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
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LGM Pharma
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1-(800)-881-8210
Fax
615-250-9817
Email
inquiries@lgmpharma.com
Country
United States
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Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
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BOC Sciences
Tel
1-631-485-4226; 16314854226
Email
info@bocsci.com
Country
United States
ProdList
14055
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ShangHai YuanYe Biotechnology Co., Ltd.
Tel
021-61312847 13636370518
Fax
021-55068248
Email
shyysw007@163.com
Country
China
ProdList
4940
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View Lastest Price from 2-PHENYL-1,3-INDANDIONE manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
2-phenyl-1,3-indandione 83-12-5
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-11
Hebei Mojin Biotechnology Co., Ltd
Product
2-PHENYL-1,3-INDANDIONE 83-12-5
Price
US $100.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
5000KG
Release date
2023-07-31

83-12-5, 2-PHENYL-1,3-INDANDIONERelated Search:


  • AURORA KA-4422
  • 2-PHENYL-1,3-INDANDIONE
  • 2-PHENYL-1,3-INDANEDIONE
  • 2-PHENYL-1,3-DIKETOHYDRINDENE
  • 2-PHENYL-1H-INDEN-1,3(2H)-DIONE
  • PHENYLINDIONE
  • PHENINDIONE
  • PHENINDONE
  • Phenylindandione
  • 2-Phenyl-1H-inden-1,3(2H)-dione,99%
  • 1,3(2H)-Indenedione, 2-phenyl-
  • 1,3-Indandione, 2-phenyl-
  • 1,3-Indandione,2-phenyl-
  • 1H-Indene-1,3(2H)-dione, 2-phenyl-
  • 1H-Indene-1,3(2H)-dione,2-phenyl-
  • 2-fenyloindandion-1,3
  • 2-Phenyl-1H-indene-1,3(2H)-dione
  • 2-phenyl-1h-indene-3(2h)-dione
  • 2-phenyl-3-indandione
  • 2-Phenyl-indan-1,3-dione
  • 2-Phenylindan-1,3-dione
  • 2-phenylindan-1-3-dione
  • 2-Phenylindandione
  • Athrombon
  • Bindan
  • Cronodione
  • Danedion
  • Danilon
  • Danilone
  • Diadilan
  • Dindevan
  • Dineval
  • Diophindane
  • Emandion
  • Emandione
  • Eridione
  • Fenhydren
  • Fenilin
  • Fenindion
  • heducin
  • Hedulin
  • Hemolidione
  • Indema
  • Indion
  • Indon
  • Phenhydren
  • Phenillin
  • Phenindion
  • phenindione(INN)
  • Phenylen
  • Phenylin
  • Phenylindanedione
  • Phenyline
  • Phenyllin
  • PID
  • Pindione
  • Rectadione
  • Theradione