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Bis(2-chloroethoxy)methane

Product Name
Bis(2-chloroethoxy)methane
CAS No.
111-91-1
Chemical Name
Bis(2-chloroethoxy)methane
Synonyms
rcrawastenumberu024;DICHLOROETHYL FORMAL;dichlorodiethylformal;di-2-chloroethylformal;Rcra waste number U024;2,2-Dichloroethylformal;dichlorodiethylmethylal;Di-2-chloroethyl formal;bis(2-chloroethyl)formal;Bis(2-chloroethyl) formal
CBNumber
CB3440463
Molecular Formula
C5H10Cl2O2
Formula Weight
173.04
MOL File
111-91-1.mol
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Bis(2-chloroethoxy)methane Property

Melting point:
-32.3°C
Boiling point:
112°C/20mm
Density 
1.23
vapor pressure 
1 at 53 °C (Weast, 1986)
refractive index 
1.45
storage temp. 
Refrigerator, under inert atmosphere
solubility 
Chloroform (Sparingly), Methanol (Slightly)
form 
Oil
color 
Colorless liquid
Water Solubility 
81,00 mg/L at 25 °C using method of Moriguchi (1975)
Henry's Law Constant
(x 10-7 atm?m3/mol): 3.78 (calculated, U.S. EPA, 1980a)
LogP
1.6 at 20℃
CAS DataBase Reference
111-91-1(CAS DataBase Reference)
NIST Chemistry Reference
Methane, bis(2-chloroethoxy)-(111-91-1)
EPA Substance Registry System
Bis(2-chloroethoxy)methane (111-91-1)
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Safety

Hazard Codes 
Xi,T
Risk Statements 
25
Safety Statements 
45
RIDADR 
2810
HazardClass 
6.1(b)
PackingGroup 
III
Hazardous Substances Data
111-91-1(Hazardous Substances Data)
Toxicity
Acute oral LD50 for rats 65 mg/kg (quoted, RTECS, 1985).
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

H312Harmful in contact with skin

H330Fatal if inhaled

H370Causes damage to organs

H373May cause damage to organs through prolonged or repeated exposure

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P284Wear respiratory protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P307+P311IF exposed: call a POISON CENTER or doctor/physician.

P310Immediately call a POISON CENTER or doctor/physician.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P314Get medical advice/attention if you feel unwell.

P320Specific treatment is urgent (see … on this label).

P321Specific treatment (see … on this label).

P322Specific measures (see …on this label).

P330Rinse mouth.

P363Wash contaminated clothing before reuse.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
B418520
Product name
Bis(2-chloroethoxy)methane
Packaging
1g
Price
$275
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0070007
Product name
BIS(2-CHLOROETHOXY)METHANE
Purity
95.00%
Packaging
5G
Price
$784.25
Updated
2021/12/16
Matrix Scientific
Product number
007514
Product name
Bis(2-chloroethoxy)methane
Purity
97%
Packaging
5g
Price
$48
Updated
2021/12/16
AK Scientific
Product number
8827AC
Product name
Bis(2-chloroethoxy)methane
Packaging
250mg
Price
$164
Updated
2021/12/16
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Bis(2-chloroethoxy)methane Chemical Properties,Usage,Production

Description

Bis(2-chloroethoxy)methane is a colorlessliquid. Molecular weight=173.1; Boiling point=218℃;Freezing/Melting point=233℃; Flash point=110℃(oc). Hazard Identification (based on NFPA-704 M RatingSystem): Health 2, Flammability 1, Reactivity 0. Slight solubility in water; solubility=0.8%.

Chemical Properties

Bis(2-chloroethoxy)methane is a colorless liquid.

Uses

Manufacture of insecticides, polymers; degreasing solvent; intermediate for polysulfide rubber.

Uses

Bis(2-chloroethoxy)methane is an chloroether used to manufacture polysulfide polymers.

General Description

A colorless liquid. Boiling point 217.5°C, Flash point 230°F. Density 1.23 g / cm3. May be toxic by ingestion or inhalation. Severely irritates skin, eyes, and mucous membranes. Used as a solvent.

Air & Water Reactions

Slightly soluble in water.

Reactivity Profile

Bis(2-chloroethoxy)methane, the b-chloroethyl acetal of formaldehyde, is incompatible with oxidizing agents.

Health Hazard

ACUTE/CHRONIC HAZARDS: Toxic by inhalation and ingestion; Strong irritant.

Fire Hazard

Not Flammable.

Potential Exposure

The chloroalkyl ethers have a wide variety of industrial uses in organic synthesis, treatment of textiles; the manufacture of polymers; polysulfide rubbers, and insecticides; as degreasing agents and solvents; and in the preparation of ion exchange resins.

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least 15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.

Environmental Fate

Biological. Using settled domestic wastewater inoculum, bis(2-chloroethoxy)methane (5 and 10 mg/L) did not degrade after 28 d of incubation at 25 °C (Tabak et al., 1981).
Chemical/Physical. At influent concentrations of 10, 1.0, 0.1, and 0.01 mg/L, the GAC adsorption capacities were 50, 11, 2.6, and 0.6 mg/g, respectively (Dobbs and Cohen, 1980).

storage

Color Code—Green: General storage may be used.Store in tightly closed containers in a cool, well-ventilatedarea away from oxidizers. Sources of ignition, such assmoking and open flames, are prohibited where this chemical is used, handled, or stored in a manner that could createa potential fire or explosion hazard.

Shipping

UN2810 Toxic liquids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1—Poisonous materials, Technical Name Required.

Incompatibilities

The aqueous solution is a strong acid; keep away from bases and alkaline material. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Contact with mineral acids causes decomposition.

Waste Disposal

Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. Destroy by high-temperature incineration with HCl scrubber.

Bis(2-chloroethoxy)methane Preparation Products And Raw materials

Raw materials

Preparation Products

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Bis(2-chloroethoxy)methane Suppliers

Canada 1 China 39 Europe 1 France 1 Germany 2 India 1 Japan 1 Slovakia 1 United Kingdom 2 United States 17 Global 66
J & K SCIENTIFIC LTD.
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3B Pharmachem (Wuhan) International Co.,Ltd.
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Zouping Mingxing Chemical Co.,Ltd.
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View Lastest Price from Bis(2-chloroethoxy)methane manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
Bis(2-chloroethoxy)methane 111-91-1
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-28
Hebei Yanxi Chemical Co., Ltd.
Product
Bis(2-chloroethoxy)methane 111-91-1
Price
US $70.00-10.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20 tons
Release date
2023-09-14

111-91-1, Bis(2-chloroethoxy)methaneRelated Search:

Triphenylmethyl Chloride 1,3-Dioxan-5-ol Diethanolamine Chloromethane Dimethoxymethane 2,2-Diethoxyethylamine Niclosamide ethanolamine salt DIETHOXYMETHANE Bromoacetaldehyde diethyl acetal CHLORODIBROMOMETHANE Sucralose PENTAERYTHRITYL TETRABROMIDE TRIPHENYL METHANE CHLORID Cloretate Trichloroparaldehyde Difluorochloromethane 2-Chloroethanol TRIS(2-CHLOROETHYL)- ORTHOFORMATE

  • 1,1’-(methylenebis(oxy))bis(2-chloro-ethan
  • 1,1’-(methylenebis(oxy))bis(2-chloroethane)
  • 1,1’-[methylenebis(oxy)]bis[2-chloro-ethan
  • 1,1’-[methylenebis(oxy)]bis[2-chloro-Ethane
  • 1-Chloro-2-[(2-chloroethoxy)methoxy]ethane
  • 2,2-Dichloroethylformal
  • beta,beta,-dichlorodiethylformal
  • di-2-chloroethylformal
  • dichlorodiethylformal
  • dichlorodiethylmethylal
  • Ethane, 1,1'-[methylenebis(oxy)]bis[2-chloro-
  • ethane,1,-[methylenebis(oxy)]bis[2-chloro-
  • Formaldehyde bis(2-chloroethyl) acetal
  • Formaldehyde bis(beta-chloroethyl) acetal
  • formaldehydebis(2-chloroethyl)acetal
  • formaldehydebis(beta-chloroethyl)acetal
  • Rcra waste number U024
  • rcrawastenumberu024
  • bis(2-chloroethoxy)-methan
  • bis(2-chloroethoxy)methane,[liquid]
  • Bis(2-chloroethyl) formal
  • bis(2-chloroethyl)formal
  • Bis(beta-chloroethyl) formal
  • bis(betachloroethyl)formal
  • bis(beta-chloroethyl)formal
  • bis(chloro-2ethoxy)methane
  • Di-2-chloroethyl formal
  • DICHLOROETHYL FORMAL
  • BIS(2-CHLOROETHOXY)METHANE
  • Dichloromethoxy ethane: (bis(2-Chloroethoxy)methane)
  • 2,2'-(Methylenebisoxy)bis(1-chloroethane)
  • Bis(2-chloroethoxy)methane 1g [111-91-1]
  • bis(2-Chloroethoxy)methane@1000 μg/mL in MeOH
  • bis(2-Chloroethoxy)methane @100 μg/mL in Dichloromethane
  • bis(2-Chloroethoxy)methane @5.0 mg/mL in MeOH
  • 111-91-1
  • ClCH2CH2OCH2OCH2CH2Cl