ChemicalBook > CAS DataBase List > 4'-(Octyloxy)-4-biphenylcarbonitrile

4'-(Octyloxy)-4-biphenylcarbonitrile

Product Name
4'-(Octyloxy)-4-biphenylcarbonitrile
CAS No.
52364-73-5
Chemical Name
4'-(Octyloxy)-4-biphenylcarbonitrile
Synonyms
8OCB;M-24;RO-CM-5324;m24(liquidcrystal);OCTYLOXYCYANOBIPHENYL;Octoxybiphenylnitrile;4-cyano-4-octylophenyl;4-octyloxycyanodiphenyl;4-octoxy-4'-cyanobiphenyl;4-Cyano-4’-octoxybiphenyl
CBNumber
CB3452127
Molecular Formula
C21H25NO
Formula Weight
307.43
MOL File
52364-73-5.mol
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4'-(Octyloxy)-4-biphenylcarbonitrile Property

Melting point:
51-77 °C (lit.)
Boiling point:
447.93°C (rough estimate)
Density 
1.0505 (rough estimate)
refractive index 
1.5614 (estimate)
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
form 
liquid crystal (Nematic)
color 
White to Almost white
InChI
InChI=1S/C21H25NO/c1-2-3-4-5-6-7-16-23-21-14-12-20(13-15-21)19-10-8-18(17-22)9-11-19/h8-15H,2-7,16H2,1H3
InChIKey
GPGGNNIMKOVSAG-UHFFFAOYSA-N
SMILES
C1(C2=CC=C(OCCCCCCCC)C=C2)=CC=C(C#N)C=C1
NIST Chemistry Reference
Octyloxycyanobiphenyl(52364-73-5)
EPA Substance Registry System
[1,1'-Biphenyl]-4-carbonitrile, 4'-(octyloxy)- (52364-73-5)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-36
WGK Germany 
3
RTECS 
DV1764500
TSCA 
Yes
HS Code 
29269090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P273Avoid release to the environment.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
338672
Product name
4′-(Octyloxy)-4-biphenylcarbonitrile
Purity
liquid crystal (nematic)
Packaging
250mg
Price
$36.1
Updated
2023/06/20
Sigma-Aldrich
Product number
338672
Product name
4′-(Octyloxy)-4-biphenylcarbonitrile
Purity
liquid crystal (nematic)
Packaging
1g
Price
$114
Updated
2023/06/20
TCI Chemical
Product number
C2618
Product name
4-Cyano-4'-n-octyloxybiphenyl
Purity
>98.0%(GC)
Packaging
5g
Price
$157
Updated
2025/07/31
TCI Chemical
Product number
C2618
Product name
4-Cyano-4'-n-octyloxybiphenyl
Purity
>98.0%(GC)
Packaging
25g
Price
$545
Updated
2025/07/31
TRC
Product number
O293265
Product name
4''-(Octyloxy)-4-biphenylcarbonitrile
Packaging
5g
Price
$130
Updated
2021/12/16
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4'-(Octyloxy)-4-biphenylcarbonitrile Chemical Properties,Usage,Production

Chemical Properties

White Crysstalline

Uses

8CB may be used in the preparation of asymmetrical zinc phthalocyanine (aZnPc)-functional photocurable copolymer.

Uses

Intermediates of Liquid Crystals

General Description

4′-octyl-4- biphenylcarbonitrile (8CB) is a low molar mass liquid crystal (LCs), which shows different liquid crystalline phases depending on temperature conditions. Under normal temperature conditions 8CB exists only as bulk smectic-A phase. LCs are responsive to minor changes in temperature, shear, electric (or magnetic) fields, and the structure of solid surfaces with which they are in contact.

Synthesis

111-83-1

19812-93-2

52364-73-5

GENERAL STEPS: 4'-hydroxybiphenyl-4-carbonitrile (20.0 g, 0.1 mol), potassium carbonate (28.0 g, 0.2 mol) and N,N-dimethylformamide (600 mL) were added sequentially in a 1000 mL three-necked flask with magnetic stirring turned on. Subsequently, 1-bromooctane (23.0 g, 0.12 mol) was slowly added dropwise, and the reaction system was warmed to 120 °C and kept for 48 hours. Upon completion of the reaction, the mixture was cooled to room temperature, slowly poured into ice water (1000 mL) and allowed to stand overnight. The precipitated solid product was collected by filtration and purified by recrystallization with ethanol to afford the target compound 4'-octyloxy-[1,1'-biphenyl]-4-carbonitrile.

References

[1] Molecular Crystals and Liquid Crystals, 2008, vol. 480, # 1, p. 287 - 294
[2] Tetrahedron, 2012, vol. 68, # 39, p. 8172 - 8180
[3] Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals, 1995, vol. 268, p. 21 - 44
[4] Journal of Organic Chemistry USSR (English Translation), 1984, vol. 20, p. 1192 - 1195
[5] Zhurnal Organicheskoi Khimii, 1984, vol. 20, # 6, p. 1310 - 1314

4'-(Octyloxy)-4-biphenylcarbonitrile Preparation Products And Raw materials

Raw materials

Preparation Products

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4'-(Octyloxy)-4-biphenylcarbonitrile Suppliers

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View Lastest Price from 4'-(Octyloxy)-4-biphenylcarbonitrile manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
4'-(Octyloxy)-4-biphenylcarbonitrile 52364-73-5
Price
US $2.00-5.00/KG
Min. Order
0.1KG
Purity
99%
Supply Ability
g-kg-tons
Release date
2025-07-10
Hebei Chuanghai Biotechnology Co., Ltd
Product
4'-(Octyloxy)-4-biphenylcarbonitrile 52364-73-5
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2024-11-13
Shanghai UCHEM Inc.
Product
4'-(Octyloxy)-4-biphenylcarbonitrile 52364-73-5
Price
US $40.00-413.00/g
Min. Order
25g
Purity
0.98
Supply Ability
25kg
Release date
2023-12-28

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