2-METHYL-1,3-DITHIANE
- Product Name
- 2-METHYL-1,3-DITHIANE
- CAS No.
- 6007-26-7
- Chemical Name
- 2-METHYL-1,3-DITHIANE
- Synonyms
- 2-methyl-m-dithian;2-Methyl-m-dithiane;2-methyl-3-dithiane;methyl-2dithiane-1,3;Methyl-2 dithiane-1,3;m-Dithiane, 2-methyl-;2-METHYL-1,3-DITHIANE;1,3-Dithiane, 2-methyl-;2-Methyl-1,3-dithiane 98%;2-Methyl-1,3-dithiane ,98%
- CBNumber
- CB3456059
- Molecular Formula
- C5H10S2
- Formula Weight
- 134.26
- MOL File
- 6007-26-7.mol
2-METHYL-1,3-DITHIANE Property
- Boiling point:
- 56-59 °C/3 mmHg (lit.)
- Density
- 1.121 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.560(lit.)
- Flash point:
- 180 °F
- form
- Liquid
- color
- Colorless to brown
- Odor
- at 0.10 % in dipropylene glycol. sulfurous
- Odor Type
- sulfurous
- Water Solubility
- Not miscible or difficult to mix in water. Soluble in alcohol.
- BRN
- 102766
- LogP
- 2.265 (est)
- CAS DataBase Reference
- 6007-26-7(CAS DataBase Reference)
Safety
- Safety Statements
- 23-24/25
- RIDADR
- 3334
- WGK Germany
- 3
- RTECS
- JO5263000
- HS Code
- 2934999090
N-Bromosuccinimide Price
- Product number
- 359130
- Product name
- 2-Methyl-1,3-dithiane
- Purity
- 99%
- Packaging
- 5ML
- Price
- $123
- Updated
- 2023/06/20
- Product number
- L00209
- Product name
- 2-Methyl-1,3-dithiane, 98%
- Packaging
- 5g
- Price
- $187.65
- Updated
- 2024/03/01
- Product number
- L00209
- Product name
- 2-Methyl-1,3-dithiane, 98%
- Packaging
- 1g
- Price
- $57.3
- Updated
- 2021/12/16
- Product number
- L00209
- Product name
- 2-Methyl-1,3-dithiane, 98%
- Packaging
- 25g
- Price
- $623.65
- Updated
- 2024/03/01
- Product number
- CHM0009022
- Product name
- 2-METHYL-1,3-DITHIANE
- Purity
- 95.00%
- Packaging
- 5ML
- Price
- $840.61
- Updated
- 2021/12/16
2-METHYL-1,3-DITHIANE Chemical Properties,Usage,Production
Uses
It has been employed in the synthesis of methyl ketones. 2-Methyl-1,3-dithiane is suitable for use in the preparation of potassium trifluoro(2-methyl-1,3-dithiano)borate.
Synthesis Reference(s)
Tetrahedron Letters, 27, p. 6305, 1986 DOI: 10.1016/S0040-4039(00)87793-X
General Description
2-Methyl-1,3-dithiane is a versatile acyl anion equivalent. Role of hyperconjugation in the conformational analysis of 2-methyl-1,3-dithiane has been reported.
Purification Methods
Wash the dithiane with H2O, 2.5 M aqueous NaOH, H2O, brine, dry over K2CO3 (use toluene as solvent if the volume of reagent is small), filter, evaporate and distil the colourless residue. IR film: 1455, 1371 and 1060 (all medium and CH3), 1451m, 1422s, 1412m, 1275m, 1236m, max 1190m, 1171w, 918m and 866w (all dithiane) cm-1 [Corey & Erickson J Org Chem 36 3553 1971, Seebach & Corey J Org Chem 40 231 1975]. [Beilstein 19 III/IV 49, 19/1 V 53.]
2-METHYL-1,3-DITHIANE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-METHYL-1,3-DITHIANE manufacturers
- Product
- 2-Methyl-1,3-dithiane 6007-26-7
- Price
- US $0.00-0.00/KG
- Min. Order
- 1g
- Purity
- 98%minNMR
- Supply Ability
- 100kg/month
- Release date
- 2021-12-25
- Product
- 2-METHYL-1,3-DITHIANE 6007-26-7
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 85.0-99.8%
- Supply Ability
- 20 tons
- Release date
- 2019-12-25