(PHENYLTHIOMETHYL)TRIMETHYLSILANE

Product Name: (PHENYLTHIOMETHYL)TRIMETHYLSILANE
CAS No.: 17873-08-4
Chemical Name: (PHENYLTHIOMETHYL)TRIMETHYLSILANE
Synonyms: PHENYLTHIO(TRIMETHYLSILYL)METHANE;(PHENYLTHIOMETHYL)TRIMETHYLSILANE;TRIMETHYL(PHENYLTHIOMETHYL)SILANE;PHENYL TRIMETHYLSILYLMETHYL SULFIDE;(Phenylthiomethyl)trimethylsilane>Silane, trimethyl(phenylthio)methyl-;[[(Trimethylsilyl)methyl]thio]benzene;[(Trimethylsilyl)methyl]phenyl sulfide;Benzene, [[(trimethylsilyl)methyl]thio]-;Phenylthio(trimethylsilyl)methane Phenyl Trimethylsilylmethyl Sulfide Trimethyl(phenylthiomethyl)silane
CBNumber: CB3462685
Molecular Formula: C10H16SSi
Formula Weight: 196.38
MOL File: 17873-08-4.mol

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(PHENYLTHIOMETHYL)TRIMETHYLSILANE Property

Boiling point:: 158-159 °C52 mm Hg(lit.)
Density: 0.967 g/mL at 25 °C(lit.)
refractive index: n20/D 1.539(lit.)
Flash point:: 103 °F
solubility: sol most common organic solvents.
form: clear liquid
color: Colorless to Almost colorless
Specific Gravity: 0.97
Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions
BRN: 1932375
InChI: 1S/C10H16SSi/c1-12(2,3)9-11-10-7-5-4-6-8-10/h4-8H,9H2,1-3H3
InChIKey: UOQDIMYVQSHALM-UHFFFAOYSA-N
SMILES: C[Si](C)(C)CSc1ccccc1
NIST Chemistry Reference: Silane, trimethyl[(phenylthio)methyl]-(17873-08-4)

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Safety

Hazard Codes: Xn
Risk Statements: 20-38
Safety Statements: 23-28
RIDADR: UN 1993 3/PG 3
WGK Germany: 3
HS Code: 2931.90.6000
HazardClass: 3.2
PackingGroup: III
Storage Class: 3 - Flammable liquids
Hazard Classifications: Acute Tox. 4 Inhalation
Flam. Liq. 3
Skin Irrit. 2

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P243Take precautionary measures against static discharge.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 268585
Product name: Trimethyl(phenylthiomethyl)silane
Purity: 99%
Packaging: 25g
Price: $160
Updated: 2023/01/07

TCI Chemical

Product number: P1172
Product name: (Phenylthiomethyl)trimethylsilane
Purity: >98.0%(GC)
Packaging: 5mL
Price: $414
Updated: 2025/07/31

TRC

Product number: P337430
Product name: (Phenylthiomethyl)trimethylsilane
Packaging: 50mg
Price: $45
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: ORS0000125
Product name: (PHENYLTHIOMETHYL)TRIMETHYLSILANE
Purity: 95.00%
Packaging: 5ML
Price: $228
Updated: 2021/12/16

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(PHENYLTHIOMETHYL)TRIMETHYLSILANE Chemical Properties,Usage,Production

Physical properties

bp 158–159 °C/52 mmHg; d20 0.967 g cm?3; n20 D 1.5390.

Uses

lithio derivative is a one-carbon homologating agent leading to aldehydes via sila-Pummerer rearrangement, vinyl sulfides via Peterson alkenation, and vinylsilanes from silyl epoxides.

Preparation

(Phenylthiomethyl)trimethylsilane is abtained by reaction of Phenylthiomethyllithium with Chlorotrimethylsilane.^[1]

storage

(Phenylthiomethyl)trimethylsilane is irriting; foul smelling; use in a fume hood.

Purification Methods

If the sample is suspect, then add H2O, wash it with 10% aqueous NaOH, H2O again, dry (anhydrous CaCl2) and fractionally distil it through a 2ft column packed with glass helices. [Cooper J Am Chem Soc 76 3713 1954.]

References

1. (a) Gilman, H.; Webb, F. J. JACS 1940, 62, 987. (b) Cooper, G. D. JACS 1954, 76, 3713. (c) Carey, F. A.; Court, A. S. JOC 1972, 37, 939.

(PHENYLTHIOMETHYL)TRIMETHYLSILANE Preparation Products And Raw materials

Raw materials

Preparation Products

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(PHENYLTHIOMETHYL)TRIMETHYLSILANE Suppliers

Americas 1 China 50 Europe 1 Germany 2 India 1 Japan 1 Switzerland 1 United Kingdom 3 United States 10 Global 70

J & K SCIENTIFIC LTD.

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View Lastest Price from (PHENYLTHIOMETHYL)TRIMETHYLSILANE manufacturers

Zhengzhou Gecko Scientific Inc.

Product: [[(Trimethylsilyl)methyl]thio]benzene 17873-08-4
Price: US $0.00-0.00/g
Min. Order: 10g
Purity: 100%
Supply Ability: 10kg
Release date: 2022-09-27

Career Henan Chemical Co

Product: (PHENYLTHIOMETHYL)TRIMETHYLSILANE 17873-08-4
Price: US $9.80/KG
Min. Order: 1g
Purity: ≥99%
Supply Ability: 100kg
Release date: 2020-01-08

17873-08-4, (PHENYLTHIOMETHYL)TRIMETHYLSILANERelated Search:

Silicon tetrahydride TRIMETHYLSILYLBENZENESULFONATE TRIMETHYLSILYLMETHANETHIOL (PHENYLTHIOMETHYL)TRIMETHYLSILANE

(PHENYLTHIOMETHYL)TRIMETHYLSILANE

PHENYLTHIO(TRIMETHYLSILYL)METHANE

PHENYL TRIMETHYLSILYLMETHYL SULFIDE

TRIMETHYL(PHENYLTHIOMETHYL)SILANE

[(Trimethylsilyl)methyl]phenyl sulfide

[[(Trimethylsilyl)methyl]thio]benzene

Phenylthio(trimethylsilyl)methane Phenyl Trimethylsilylmethyl Sulfide Trimethyl(phenylthiomethyl)silane

Silane, trimethyl(phenylthio)methyl-

(Phenylthiomethyl)trimethylsilane, (Trimethylsilyl)methyl phenyl sulfide, Phenyl (trimethylsilyl)methyl sulfide

(Phenylthiomethyl)trimethylsilane&gt

Benzene, [[(trimethylsilyl)methyl]thio]-

17873-08-4

C6H5SCH2SiCH33

Si (Classes of Silicon Compounds)

Silicon Compounds (for Synthesis)

Sulfur Compounds (for Synthesis)

Si-(C)4 Compounds

Organometallic Reagents

Others

Organosilicon

Si (Classes of Silicon Compounds)

Si-(C)4 Compounds

Silicon Compounds (for Synthesis)

Sulfur Compounds (for Synthesis)

Synthetic Organic Chemistry