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(PHENYLTHIOMETHYL)TRIMETHYLSILANE

Product Name
(PHENYLTHIOMETHYL)TRIMETHYLSILANE
CAS No.
17873-08-4
Chemical Name
(PHENYLTHIOMETHYL)TRIMETHYLSILANE
Synonyms
PHENYLTHIO(TRIMETHYLSILYL)METHANE;(PHENYLTHIOMETHYL)TRIMETHYLSILANE;TRIMETHYL(PHENYLTHIOMETHYL)SILANE;PHENYL TRIMETHYLSILYLMETHYL SULFIDE;(Phenylthiomethyl)trimethylsilane>Silane, trimethyl(phenylthio)methyl-;[[(Trimethylsilyl)methyl]thio]benzene;[(Trimethylsilyl)methyl]phenyl sulfide;Benzene, [[(trimethylsilyl)methyl]thio]-;Phenylthio(trimethylsilyl)methane Phenyl Trimethylsilylmethyl Sulfide Trimethyl(phenylthiomethyl)silane
CBNumber
CB3462685
Molecular Formula
C10H16SSi
Formula Weight
196.38
MOL File
17873-08-4.mol
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(PHENYLTHIOMETHYL)TRIMETHYLSILANE Property

Boiling point:
158-159 °C52 mm Hg(lit.)
Density 
0.967 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.539(lit.)
Flash point:
103 °F
solubility 
sol most common organic solvents.
form 
clear liquid
color 
Colorless to Almost colorless
Specific Gravity
0.97
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
BRN 
1932375
NIST Chemistry Reference
Silane, trimethyl[(phenylthio)methyl]-(17873-08-4)
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Safety

Hazard Codes 
Xn
Risk Statements 
20-38
Safety Statements 
23-28
RIDADR 
UN 1993 3/PG 3
WGK Germany 
3
HS Code 
2931.90.6000
HazardClass 
3.2
PackingGroup 
III
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P243Take precautionary measures against static discharge.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
268585
Product name
Trimethyl(phenylthiomethyl)silane
Purity
99%
Packaging
25g
Price
$160
Updated
2023/01/07
TCI Chemical
Product number
P1172
Product name
(Phenylthiomethyl)trimethylsilane
Purity
>98.0%(GC)
Packaging
5mL
Price
$345
Updated
2024/03/01
TRC
Product number
P337430
Product name
(Phenylthiomethyl)trimethylsilane
Packaging
50mg
Price
$45
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ORS0000125
Product name
(PHENYLTHIOMETHYL)TRIMETHYLSILANE
Purity
95.00%
Packaging
5ML
Price
$228
Updated
2021/12/16
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(PHENYLTHIOMETHYL)TRIMETHYLSILANE Chemical Properties,Usage,Production

Physical properties

bp 158–159 °C/52 mmHg; d20 0.967 g cm?3; n20 D 1.5390.

Uses

lithio derivative is a one-carbon homologating agent leading to aldehydes via sila-Pummerer rearrangement, vinyl sulfides via Peterson alkenation, and vinylsilanes from silyl epoxides.

Purification Methods

If the sample is suspect, then add H2O, wash it with 10% aqueous NaOH, H2O again, dry (anhydrous CaCl2) and fractionally distil it through a 2ft column packed with glass helices. [Cooper J Am Chem Soc 76 3713 1954.]

(PHENYLTHIOMETHYL)TRIMETHYLSILANE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from (PHENYLTHIOMETHYL)TRIMETHYLSILANE manufacturers

Zhengzhou Gecko Scientific Inc.
Product
[[(Trimethylsilyl)methyl]thio]benzene 17873-08-4
Price
US $0.00-0.00/g
Min. Order
10g
Purity
100%
Supply Ability
10kg
Release date
2022-09-27
Career Henan Chemical Co
Product
(PHENYLTHIOMETHYL)TRIMETHYLSILANE 17873-08-4
Price
US $9.80/KG
Min. Order
1g
Purity
≥99%
Supply Ability
100kg
Release date
2020-01-08

17873-08-4, (PHENYLTHIOMETHYL)TRIMETHYLSILANERelated Search:


  • (PHENYLTHIOMETHYL)TRIMETHYLSILANE
  • PHENYLTHIO(TRIMETHYLSILYL)METHANE
  • PHENYL TRIMETHYLSILYLMETHYL SULFIDE
  • TRIMETHYL(PHENYLTHIOMETHYL)SILANE
  • [(Trimethylsilyl)methyl]phenyl sulfide
  • [[(Trimethylsilyl)methyl]thio]benzene
  • Phenylthio(trimethylsilyl)methane Phenyl Trimethylsilylmethyl Sulfide Trimethyl(phenylthiomethyl)silane
  • Silane, trimethyl(phenylthio)methyl-
  • (Phenylthiomethyl)trimethylsilane, (Trimethylsilyl)methyl phenyl sulfide, Phenyl (trimethylsilyl)methyl sulfide
  • (Phenylthiomethyl)trimethylsilane&gt
  • Benzene, [[(trimethylsilyl)methyl]thio]-
  • 17873-08-4
  • C6H5SCH2SiCH33
  • Si (Classes of Silicon Compounds)
  • Silicon Compounds (for Synthesis)
  • Sulfur Compounds (for Synthesis)
  • Si-(C)4 Compounds
  • Organometallic Reagents
  • Others
  • Organosilicon
  • Si (Classes of Silicon Compounds)
  • Si-(C)4 Compounds
  • Silicon Compounds (for Synthesis)
  • Sulfur Compounds (for Synthesis)
  • Synthetic Organic Chemistry