2-Methyl-2-nitropropan-1-ol
- Product Name
- 2-Methyl-2-nitropropan-1-ol
- CAS No.
- 76-39-1
- Chemical Name
- 2-Methyl-2-nitropropan-1-ol
- Synonyms
- 1-Propanol, 2-methyl-2-nitro-;2-Methyl-2-nitropropanol;2-methyl-2-nitro-1-propano;2-NITRO-2-METHYL-1-PROPANOL;2-METHYL-2-NITRO-1-PROPANOL;2-NITROISOBUTANOL;Methylnitropropanol;methyl-2nitro-2propanol;2-Nitro-2-methylpropanol;2-methyl-2-nitropropan-1-ol
- CBNumber
- CB3474945
- Molecular Formula
- C4H9NO3
- Formula Weight
- 119.12
- MOL File
- 76-39-1.mol
2-Methyl-2-nitropropan-1-ol Property
- Melting point:
- 86-89 °C(lit.)
- Boiling point:
- 94-95 °C10 mm Hg(lit.)
- Density
- 1.0765 (estimate)
- refractive index
- 1.4413 (estimate)
- pka
- 13.79±0.10(Predicted)
- InChI
- InChI=1S/C4H9NO3/c1-4(2,3-6)5(7)8/h6H,3H2,1-2H3
- InChIKey
- MVGJRISPEUZYAQ-UHFFFAOYSA-N
- SMILES
- C(O)C(C)([N+]([O-])=O)C
- NIST Chemistry Reference
- 1-Propanol, 2-methyl-2-nitro-(76-39-1)
- EPA Substance Registry System
- 1-Propanol, 2-methyl-2-nitro- (76-39-1)
Safety
- WGK Germany
- 3
- RTECS
- UB8575000
- Hazardous Substances Data
- 76-39-1(Hazardous Substances Data)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P330Rinse mouth.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- 0231BA
- Product name
- 2-Methyl-2-nitro-1-propanol
- Packaging
- 250mg
- Price
- $181
- Updated
- 2021/12/16
- Product number
- 159675
- Product name
- 2-Methyl-2-nitropropan-1-ol
- Packaging
- 0.500g
- Price
- $240
- Updated
- 2021/12/16
- Product number
- 159675
- Product name
- 2-Methyl-2-nitropropan-1-ol
- Packaging
- 1g
- Price
- $300
- Updated
- 2021/12/16
- Product number
- CHM0009071
- Product name
- 2-METHYL-2-NITRO-1-PROPANOL
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $499.28
- Updated
- 2021/12/16
- Product number
- 159675
- Product name
- 2-Methyl-2-nitropropan-1-ol
- Packaging
- 5g
- Price
- $1000
- Updated
- 2021/12/16
2-Methyl-2-nitropropan-1-ol Chemical Properties,Usage,Production
Uses
The direct hydrogenation of 2-Methyl-2-nitropropan-1-ol obtains product 2-amino-2-methyl-1-propanol (AMP-95). AMP-95 is a kind of multifunction additive being widely known by the people, be widely used in coating and printing ink, metal working fluid, in the industries such as personal nursing and medicine intermediate.
Synthesis
By catalyst 10g (Ti-V-ZSM-5), acetone 58.08g, ammonium hydroxide 20g are
added in 400ml methanol, are warming up to 70
DEG C, hydrogen peroxide (35%) 226.7g is slowly added dropwise,
temperature is maintained to react 1h at 65-75°C, obtain 2- nitros
third after being added dropwise
Alkane reaction solution；Filtering adds in 5g sodium hydroxides to
reaction solution, is warming up to 35°C, formaldehyde (40% aqueous
solution) is added dropwise, drip with
the reaction was continued afterwards 3h, obtains 2-Methyl-2-nitropropan-1-ol.
Purification Methods
Distil it under vacuum and/or crystallise it from pet ether or MeOH. [Astle & Abbott J Org Chem 21 1229 1956, Kambe & Yasuda Bull Soc Chem Jpn 41 1444 1968, Beilstein 1 H 378, 1 III 1546, 1 IV 1604.]
2-Methyl-2-nitropropan-1-ol Preparation Products And Raw materials
Raw materials
Preparation Products
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