TRIS(DIMETHYLAMINO)METHANE
- Product Name
- TRIS(DIMETHYLAMINO)METHANE
- CAS No.
- 5762-56-1
- Chemical Name
- TRIS(DIMETHYLAMINO)METHANE
- Synonyms
- TRIS(DIMETHYLAMINO)METHANE;Tris(dimethylamino)methane,85%;Tris(N,N-dimethylamino)methane;Tris(dimethylamino)methane 97%;Tris(dimethylamino) methane, 96%+;Tris(diMethylaMino)Methane, 85% 5GR;N,N,N,N,N,N-HEXAMETHYLMETHANETRIAMINE;N,N',N''-Methylidynetris(dimethylamine);N,N,N',N',N'',N''-HEXAMETHYLMETHANETRIAMINE;Methanetriamine, N,N,N',N',N'',N''-hexamethyl-
- CBNumber
- CB3478150
- Molecular Formula
- C7H19N3
- Formula Weight
- 145.25
- MOL File
- 5762-56-1.mol
TRIS(DIMETHYLAMINO)METHANE Property
- Boiling point:
- 42-43 °C/12 mmHg (lit.)
- Density
- 0.838 g/mL at 20 °C (lit.)
- refractive index
- n20/D 1.436(lit.)
- Flash point:
- 4 °F
- storage temp.
- 2-8°C
- form
- Liquid
- pka
- 6.50±0.38(Predicted)
- color
- Clear colorless to slightly yellow
- BRN
- 1901162
Safety
- Hazard Codes
- F,C
- Risk Statements
- 11-34
- Safety Statements
- 16-26-36/37/39-45
- RIDADR
- UN 2733 3/PG 2
- WGK Germany
- 3
- F
- 3-8-10-21
- Hazard Note
- Corrosive/Highly Flammable
- HazardClass
- 3.1
- PackingGroup
- II
- HS Code
- 29212900
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233Keep container tightly closed.
P240Ground/bond container and receiving equipment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 221058
- Product name
- Tris(dimethylamino)methane
- Purity
- 97%
- Packaging
- 5g
- Price
- $266
- Updated
- 2023/01/07
- Product number
- 221058
- Product name
- Tris(dimethylamino)methane
- Purity
- 97%
- Packaging
- 25g
- Price
- $890
- Updated
- 2023/01/07
- Product number
- T1057
- Product name
- Tris(dimethylamino)methane
- Purity
- >97.0%(T)
- Packaging
- 5mL
- Price
- $253
- Updated
- 2024/03/01
- Product number
- T1057
- Product name
- Tris(dimethylamino)methane
- Purity
- >97.0%(T)
- Packaging
- 25mL
- Price
- $867
- Updated
- 2024/03/01
- Product number
- H296930
- Product name
- N,N,N'',N'',N'''',N''''-Hexamethylmethanetriamine
- Packaging
- 1g
- Price
- $135
- Updated
- 2021/12/16
TRIS(DIMETHYLAMINO)METHANE Chemical Properties,Usage,Production
Chemical Properties
Clear colorless to slightly yellow liquid
Uses
Reagent for the introduction of the dimethylaminoethylidene group.1 General review;2 RO polymerization of lactide.3
Uses
N,N,N'',N'',N'''',N''''-Hexamethylmethanetriamine, can be used in the synthesis of the phosphoramidite derivative of the new nucleoside analog. It can also be used as reagent for the introduction of the dimethylaminoethylidene group.
Uses
Tris(dimethylamino)methane was used:
- to prepare the phosphoramidite derivative of the new nucleoside analog
- as reagent for the introduction of the dimethylaminoethylidene group
- in ring-opening (RO) polymerization of lactide
General Description
NMR spectra and their temperature-dependence has been reported for tris(dimethylamino)methane. Tris(dimethylamino)methane reacts with crowded α-(o-nitrophenyl) ketone to yield tetrahydroquinoline derivative.
Purification Methods
Dry it over KOH and distil it through a Vigreux column (p 11) at water pump vacuum. Store it in the absence of CO2. [Bredereck et al. Chem Ber 101 1885 1968 and Angew Chem, Int Ed Engl 5 132 1966.]