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ChemicalBook > CAS DataBase List > 2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID 98

2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID 98

Application Application
Product Name
2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID 98
CAS No.
913835-94-6
Chemical Name
2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID 98
Synonyms
ETHYL 4-BORONO-3-CHLOROBENZOATE;2-CHLORO-4-(ETHOXYCARBONYL)PHENYLBORONIC ACID;2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID;Benzoic acid, 4-borono-3-chloro-, 1-ethyl ester;2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID 98;2-Chloro-4-(ethoxycarbonyl)benzeneboronic acid 98%
CBNumber
CB3501038
Molecular Formula
C9H10BClO4
Formula Weight
228.44
MOL File
913835-94-6.mol
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2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID 98 Property

Melting point:
115-118
storage temp. 
Sealed in dry,2-8°C
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Safety

Hazard Codes 
Xi
Hazard Note 
Irritant/Keep Cold
HS Code 
2931900090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC
Product number
E926203
Product name
Ethyl4-borono-3-chlorobenzoate
Packaging
250mg
Price
$85
Updated
2021/12/16
Matrix Scientific
Product number
093172
Product name
(2-Chloro-4-(ethoxycarbonyl)phenyl)boronic acid
Purity
98%
Packaging
250mg
Price
$152
Updated
2021/12/16
AK Scientific
Product number
X1454
Product name
2-Chloro-4-(ethoxycarbonyl)phenylboronicacid
Packaging
1g
Price
$177
Updated
2021/12/16
SynQuest Laboratories
Product number
6660-5-10
Product name
2-Chloro-4-(ethoxycarbonyl)benzeneboronic acid
Purity
98%
Packaging
1g
Price
$200
Updated
2021/12/16
Matrix Scientific
Product number
093172
Product name
(2-Chloro-4-(ethoxycarbonyl)phenyl)boronic acid
Purity
98%
Packaging
1g
Price
$336
Updated
2021/12/16
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2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID 98 Chemical Properties,Usage,Production

Application

Ethyl 4-boron-3-chlorobenzoate can be used as a pharmaceutical synthesis intermediate in the Suzuki coupling reaction. CN107207488 reports that ethyl 4-boron-3-chlorobenzoate can be used to prepare 3-chloro-4-(5-(4,7-dimethylbenzofuran-2-yl)-1,2,4-thiadiazol-3-yl)benzoic acid, which selectively activates retinoic acid receptor β (RARβ) (e.g., RARβ2) in vitro or in vivo.

Application

Preparation of methyl 3-chloro-4-(5-(4,7-dimethylbenzofuran-2-yl)-1,2,4-thiadiazole-3-yl)benzoate: 0.323 mmol of 3-bromo-5-(4,7-dimethylbenzofuran-2-yl)-1,2,4-thiadiazole, ethyl 4-boron-3-chlorobenzoate, 0.388 mmol of K3PO4·H2O, 0.647 mmol of Pd(Ph3P)4, 0.03 mmol of DMF (2 mL), and 0.5 mL of H2O were added to a sealed tube. The mixture was heated in a microwave reactor at 130 °C for 15 min. The mixture was cooled to RT and partitioned between DCM (10 mL) and H2O (3 mL). The organic solution was washed with water (3 mL), passed through a phase separation column, and concentrated under vacuum. The residue was purified by silica gel chromatography in isohexane (0-10% EtOAc) to give methyl 3-chloro-4-(5-(4,7-dimethylbenzofuran-2-yl)-1,2,4-thiadiazol-3-yl)benzoate.

2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID 98 Preparation Products And Raw materials

Raw materials

Preparation Products

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2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID 98 Suppliers

China 45 India 2 United Kingdom 1 United States 6 Global 54
J & K SCIENTIFIC LTD.
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18210857532; 18210857532
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Henan CoreyChem Co., Ltd
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Amadis Chemical Company Limited
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571-89925085
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0086-571-89925065
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sales@amadischem.com
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AAB-PHARMA LIMITED
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025-66800956 18800000000
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qq3325708371
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sales@njdmchem.com
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View Lastest Price from 2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID 98 manufacturers

Career Henan Chemical Co
Product
2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID 98 913835-94-6
Price
US $1.00/KG
Min. Order
1KG
Purity
98%-100%
Supply Ability
1
Release date
2018-08-12

913835-94-6, 2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID 98Related Search:

2-Chloro-4-methylphenylboronic acid ETHYL 3-CHLOROBENZOATE 3-Chlorobenzoic acid 2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID 98 4-CARBOXY-2-CHLOROPHENYLBORONIC ACID Methyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate Methyl 4-borono-3-chlorobenzoate

  • 2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID
  • 2-CHLORO-4-(ETHOXYCARBONYL)PHENYLBORONIC ACID
  • ETHYL 4-BORONO-3-CHLOROBENZOATE
  • 2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID 98
  • 2-Chloro-4-(ethoxycarbonyl)benzeneboronic acid 98%
  • Benzoic acid, 4-borono-3-chloro-, 1-ethyl ester
  • 913835-94-6
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