ChemicalBook > CAS DataBase List > 2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID 98

2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID 98

Application Application

Product Name: 2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID 98
CAS No.: 913835-94-6
Chemical Name: 2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID 98
Synonyms: ETHYL 4-BORONO-3-CHLOROBENZOATE;2-CHLORO-4-(ETHOXYCARBONYL)PHENYLBORONIC ACID;2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID;Benzoic acid, 4-borono-3-chloro-, 1-ethyl ester;2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID 98;2-Chloro-4-(ethoxycarbonyl)benzeneboronic acid 98%
CBNumber: CB3501038
Molecular Formula: C9H10BClO4
Formula Weight: 228.44
MOL File: 913835-94-6.mol

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2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID 98 Property

Melting point:: 115-118
storage temp.: Sealed in dry,2-8°C

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Safety

Hazard Codes: Xi
Hazard Note: Irritant/Keep Cold
HS Code: 2931900090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC

Product number: E926203
Product name: Ethyl4-borono-3-chlorobenzoate
Packaging: 250mg
Price: $85
Updated: 2021/12/16

Matrix Scientific

Product number: 093172
Product name: (2-Chloro-4-(ethoxycarbonyl)phenyl)boronic acid
Purity: 98%
Packaging: 250mg
Price: $152
Updated: 2021/12/16

AK Scientific

Product number: X1454
Product name: 2-Chloro-4-(ethoxycarbonyl)phenylboronicacid
Packaging: 1g
Price: $177
Updated: 2021/12/16

SynQuest Laboratories

Product number: 6660-5-10
Product name: 2-Chloro-4-(ethoxycarbonyl)benzeneboronic acid
Purity: 98%
Packaging: 1g
Price: $200
Updated: 2021/12/16

Matrix Scientific

Product number: 093172
Product name: (2-Chloro-4-(ethoxycarbonyl)phenyl)boronic acid
Purity: 98%
Packaging: 1g
Price: $336
Updated: 2021/12/16

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2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID 98 Chemical Properties,Usage,Production

Application

Ethyl 4-boron-3-chlorobenzoate can be used as a pharmaceutical synthesis intermediate in the Suzuki coupling reaction. CN107207488 reports that ethyl 4-boron-3-chlorobenzoate can be used to prepare 3-chloro-4-(5-(4,7-dimethylbenzofuran-2-yl)-1,2,4-thiadiazol-3-yl)benzoic acid, which selectively activates retinoic acid receptor β (RARβ) (e.g., RARβ2) in vitro or in vivo.

Application

Preparation of methyl 3-chloro-4-(5-(4,7-dimethylbenzofuran-2-yl)-1,2,4-thiadiazole-3-yl)benzoate: 0.323 mmol of 3-bromo-5-(4,7-dimethylbenzofuran-2-yl)-1,2,4-thiadiazole, ethyl 4-boron-3-chlorobenzoate, 0.388 mmol of K3PO4·H2O, 0.647 mmol of Pd(Ph3P)4, 0.03 mmol of DMF (2 mL), and 0.5 mL of H2O were added to a sealed tube. The mixture was heated in a microwave reactor at 130 °C for 15 min. The mixture was cooled to RT and partitioned between DCM (10 mL) and H2O (3 mL). The organic solution was washed with water (3 mL), passed through a phase separation column, and concentrated under vacuum. The residue was purified by silica gel chromatography in isohexane (0-10% EtOAc) to give methyl 3-chloro-4-(5-(4,7-dimethylbenzofuran-2-yl)-1,2,4-thiadiazol-3-yl)benzoate.

2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID 98 Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID 98 manufacturers

Career Henan Chemical Co

Product: 2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID 98 913835-94-6
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%-100%
Supply Ability: 1
Release date: 2018-08-12

913835-94-6, 2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID 98Related Search:

2-Chloro-4-methylphenylboronic acid ETHYL 3-CHLOROBENZOATE 3-Chlorobenzoic acid 2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID 98 4-CARBOXY-2-CHLOROPHENYLBORONIC ACID Methyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate Methyl 4-borono-3-chlorobenzoate

2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID

2-CHLORO-4-(ETHOXYCARBONYL)PHENYLBORONIC ACID

ETHYL 4-BORONO-3-CHLOROBENZOATE

2-CHLORO-4-(ETHOXYCARBONYL)BENZENEBORONIC ACID 98

2-Chloro-4-(ethoxycarbonyl)benzeneboronic acid 98%

Benzoic acid, 4-borono-3-chloro-, 1-ethyl ester

913835-94-6

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