2-BROMOBENZAMIDE
- Product Name
- 2-BROMOBENZAMIDE
- CAS No.
- 4001-73-4
- Chemical Name
- 2-BROMOBENZAMIDE
- Synonyms
- 2-BROMOBENZAMIDE;O-BROMOBENZAMIDE;Benzamide, o-bromo-;Benzamide, 2-bromo-;2-Bromobenzamide >2-BROMOBENZAMIDE 98%;2-Bromobenzamide,98%;2-Bromobenzamide, 97+%;2-Bromobenzenecarboxamide
- CBNumber
- CB3692905
- Molecular Formula
- C7H6BrNO
- Formula Weight
- 200.03
- MOL File
- 4001-73-4.mol
2-BROMOBENZAMIDE Property
- Melting point:
- 160-162 °C (lit.)
- Boiling point:
- 158-161 °C(Press: 12 Torr)
- Density
- 1.5488 (rough estimate)
- refractive index
- 1.5500 (estimate)
- storage temp.
- Sealed in dry,Room Temperature
- form
- Powder
- pka
- 15.36±0.50(Predicted)
- color
- Beige
- Water Solubility
- Slightly soluble in water.
- CAS DataBase Reference
- 4001-73-4(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 190594
- Product name
- 2-Bromobenzamide
- Purity
- 98%
- Packaging
- 10g
- Price
- $129.2
- Updated
- 2025/07/31
- Product number
- B2050
- Product name
- 2-Bromobenzamide
- Purity
- >98.0%(HPLC)(N)
- Packaging
- 5g
- Price
- $161
- Updated
- 2025/07/31
- Product number
- B680328
- Product name
- 2-Bromobenzamide
- Packaging
- 2.5g
- Price
- $65
- Updated
- 2021/12/16
- Product number
- FB54900
- Product name
- 2-Bromobenzamide
- Packaging
- 10g
- Price
- $60
- Updated
- 2021/12/16
- Product number
- 4648-9-02
- Product name
- 2-Bromobenzamide
- Purity
- 98%
- Packaging
- 5G
- Price
- $20
- Updated
- 2021/12/16
2-BROMOBENZAMIDE Chemical Properties,Usage,Production
Chemical Properties
Beige powder
Uses
2-Bromobenzamide has been used in microwave assisted one-pot synthesis of substituted 3-(phenylmethylene)isoindolin-1-ones, palladium-catalyzed synthesis of phenanthridinones and in the synthesis of new water-soluble iminophosphorane ligand.
Uses
2-Bromobenzamide has been used in:
- microwave assisted one-pot synthesis of substituted 3-(phenylmethylene)isoindolin-1-ones
- palladium-catalyzed synthesis of phenanthridinones
- synthesis of new water-soluble iminophosphorane ligand
Synthesis
34158-72-0
4001-73-4
General procedure for the synthesis of 2-bromobenzamide from 2-bromobenzaldehyde oxime: In a 25 mL Schlenk reaction flask, 2-bromobenzaldehyde oxime (100 mg, 0.5 mmol) and water (1 mL) were added sequentially. Subsequently, [Cp*Ir(H2O)3][OTf] catalyst was added. The reaction mixture was stirred at 110 °C for 12 h and then cooled to room temperature. Water was removed by rotary evaporation and the product was purified by column chromatography. Yield: 80%. Product characterization data: 1H NMR (500 MHz, DMSO-d6) δ 7.88 (br s, 1H, NH2), 7.64-7.58 (m, 2H, ArH), 7.41-7.34 (m, 2H, ArH); 13C NMR (125 MHz, DMSO-d6) δ 169.0, 139.3, 132.7, 130.6, 128.5, 127.5, 118.6.
References
[1] RSC Advances, 2016, vol. 6, # 43, p. 37093 - 37098
[2] Advanced Synthesis and Catalysis, 2009, vol. 351, # 11-12, p. 1807 - 1812
[3] Catalysis Science and Technology, 2014, vol. 4, # 4, p. 988 - 996
[4] Patent: CN104418682, 2016, B. Location in patent: Paragraph 0070-0074
[5] Catalysis Communications, 2015, vol. 60, p. 120 - 123
2-BROMOBENZAMIDE Preparation Products And Raw materials
Raw materials
Preparation Products
2-BROMOBENZAMIDE Suppliers
- Tel
- 800-4238616
- Fax
- +1-888-520-1075 / +1-503-283-1987
- sales@tciamerica.com
- Country
- Americas
- ProdList
- 23653
- Advantage
- 75
View Lastest Price from 2-BROMOBENZAMIDE manufacturers
- Product
- 2-BROMOBENZAMIDE 4001-73-4
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 10000KGS
- Release date
- 2025-04-29
- Product
- 2-BROMOBENZAMIDE 4001-73-4
- Price
- US $1.00-2.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100000KG
- Release date
- 2024-07-26
- Product
- 2-BROMOBENZAMIDE 4001-73-4
- Price
- US $3.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 100KG
- Release date
- 2020-02-01