CARBAZOL-9-YL-ACETIC ACID

Product Name: CARBAZOL-9-YL-ACETIC ACID
CAS No.: 524-80-1
Chemical Name: CARBAZOL-9-YL-ACETIC ACID
Synonyms: TIMTEC-BB SBB010077;N,N-Diphenyleneglycine;9-CARBAZOLEACETIC ACID;(9-carbazolyl)acetic acid;CARBAZOL-9-YL-ACETIC ACID;9H-Carbazole-9-acetic acid;9-(Carboxymethyl)carbazole;2-(9-carbazolyl)acetic acid;2-(Carbazol-9-yl)acetic acid;9-(Carboxymethyl)-9H-carbazole
CBNumber: CB3703186
Molecular Formula: C14H11NO2
Formula Weight: 225.24
MOL File: 524-80-1.mol

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CARBAZOL-9-YL-ACETIC ACID Property

Melting point:: 191-194 °C
Boiling point:: 366.75°C (rough estimate)
Density: 1.1508 (rough estimate)
refractive index: 1.5780 (estimate)
storage temp.: Sealed in dry,Room Temperature
pka: 3.13±0.10(Predicted)
Appearance: White to off-white Solid
Merck: 13,1798
BRN: 190299
InChIKey: PBDMLLFEZXXJNE-UHFFFAOYSA-N

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Safety

Hazard Codes: Xn,Xi
Risk Statements: 22-36/37/38
Safety Statements: 26
WGK Germany: 3
HazardClass: IRRITANT

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

AK Scientific

Product number: 4926AE
Product name: Carbazol-9-yl-aceticacid
Packaging: 100mg
Price: $155
Updated: 2021/12/16

Matrix Scientific

Product number: 008067
Product name: Carbazol-9-yl-acetic acid
Packaging: 1g
Price: $378
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0028800
Product name: CARBAZOL-9-YL-ACETIC ACID
Purity: 95.00%
Packaging: 500MG
Price: $762.3
Updated: 2021/12/16

Arctom

Product number: AS022070
Product name: 2-(9H-Carbazol-9-yl)aceticacid
Purity: 95%
Packaging: 100mg
Price: $81
Updated: 2021/12/16

Ambeed

Product number: A109091
Product name: 2-(9H-Carbazol-9-yl)aceticacid
Purity: 95%
Packaging: 100mg
Price: $82
Updated: 2021/12/16

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CARBAZOL-9-YL-ACETIC ACID Chemical Properties,Usage,Production

Synthesis

86-74-8

105-36-2

524-80-1

The general procedure for the synthesis of 9-carbazoleacetic acid from carbazole and ethyl bromoacetate was as follows: 5 g (0.03 mol) of carbazole was dissolved in 100 mL of DMF, followed by the addition of 6.68 g (0.04 mol) of ethyl bromoacetate. The reaction mixture was stirred continuously at 35 °C for 12 hours. After completion of the reaction, the mixture was poured into 200 mL of water and separated by filtration. The pH of the filtrate was adjusted to 1.0 with 2 M hydrochloric acid. the crude product was collected by filtration and dried. The crude product was recrystallized by dichloromethane/ethanol solvent mixture to give 6.1 g of white crystalline product in 90% yield. The structure of the product was confirmed by 1H NMR (CDCl3, 400 MHz, δ ppm) and 13C NMR (DMSO-d6, 100 MHz, δ ppm): 1H NMR showed δ 13.10 (s, 1H), 8.16 (d, 2H, J = 7.8 Hz), 7.55 (m, 2H), 7.42 (m, 2H), 7.22 ( m, 2H), 5.23 (s, 2H); 13C NMR showed δ 170.2, 140.4, 125.6, 122.2, 120.1, 119.0, 109.2, 43.9.

Purification Methods

Crystallise the acid from ethyl acetate. [Fan et al. Anal Chim Acta 367 1 1998, Beilstein 20 III/IV 3841.]

References

[1] Tetrahedron, 2014, vol. 70, # 14, p. 2478 - 2486
[2] Organic Preparations and Procedures International, 2000, vol. 32, # 3, p. 284 - 287

CARBAZOL-9-YL-ACETIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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CARBAZOL-9-YL-ACETIC ACID Suppliers

China 60 Germany 1 India 2 Russia 1 Switzerland 1 United Kingdom 4 United States 9 Global 78

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Wuhan Chemwish Technology Co.， Ltd

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ShangHai Angti Biotechnology Co., Ltd.

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524-80-1, CARBAZOL-9-YL-ACETIC ACIDRelated Search:

Vinyl acetate CARBAZOL-9-YL-ACETIC ACID 2-pyrrol-1-ylacetic acid Carbazole-9-ethanol Indol-1-yl-acetic acid (9-METHYL-9H-CARBAZOL-2-YL)-ACETIC ACID (1,2,3,4-TETRAHYDRO-CARBAZOL-9-YL)-ACETIC ACID (6-FLUORO-1,2,3,4-TETRAHYDRO-CARBAZOL-9-YL)-ACETIC ACID (6,7,8,9-TETRAHYDRO-5H-CARBAZOL-2-YL)-ACETIC ACID AMINO-(9-ETHYL-9H-CARBAZOL-3-YL)-ACETIC ACID (3-METHYLAMINO-1,2,3,4-TETRAHYDRO-CARBAZOL-9-YL)-ACETIC ACID ETHYL ESTER 2-(9H-carbazol-9-yl)acetic acid (S)-AMINO-(9-ETHYL-9H-CARBAZOL-3-YL)-ACETIC ACID (1,2,3,4-TETRAHYDRO-CARBAZOL-9-YL)-ACETIC ACID HYDRAZIDE TERT-BUTYL 2-(1,4-DIMETHYL-6-NITRO-9H-CARBAZOL-9-YL)ACETATE methyl 2-(9H-carbazol-9-yl)acetate TERT-BUTYL 2-(1,4-DIMETHYL-9H-CARBAZOL-9-YL)ACETATE

TIMTEC-BB SBB010077

CARBAZOL-9-YL-ACETIC ACID

9-CARBAZOLEACETIC ACID

(9-carbazolyl)acetic acid

(9-Carbazolyl)acetic acid, 9-(Carboxymethyl)carbazole

9-Carbazoleacetic acid, ≥99.0% (T)

2-(9-carbazolyl)acetic acid

2-(9H-Carbazole-9-yl)acetic acid

9H-Carbazole-9-acetic acid

N,N-Diphenyleneglycine

9-Carbazoleacetic acid,(9-Carbazolyl)acetic acid, 9-(Carboxymethyl)carbazole

2-(Carbazol-9-yl)acetic acid

9-(Carboxymethyl)-9H-carbazole

9-(Carboxymethyl)carbazole

524-80-1

524-80-8

Biochemicals and Reagents

BioChemical

Derivatization agents

Luminescent Compounds/Detection