(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE

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Product Name: (+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE
CAS No.: 205064-10-4
Chemical Name: (+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE
Synonyms: [((SS)-Me-DuPhos)Rh(COD)]BF4;(+)-1,2-Bis((2S,5S)-2,5-dimethyL;Bisdimethylphospholanobenzenecyclooctadienerhodium;(+)-1,2-BIS((2S,5S)-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I) BF4;(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(l)tetra;(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(l)tetrafluoroborate;(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE;(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE;(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate;(+)-1,2-Bis[(2S,5S)-2,5-diMethylphospholano]benzene(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate, 97%
CBNumber: CB3728521
Molecular Formula: C26H40BF4P2Rh4*
Formula Weight: 604.25
MOL File: 205064-10-4.mol

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(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE Property

form: crystal
color: red-orange
Sensitive: air sensitive

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Safety

Risk Statements: 36/37/38
Safety Statements: 24/25
WGK Germany: 3
HS Code: 29310099

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Strem Chemicals

Product number: 45-0159
Product name: (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-DUPHOS-Rh
Packaging: 100mg
Price: $125
Updated: 2024/03/01

Strem Chemicals

Product number: 45-0159
Product name: (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-DUPHOS-Rh
Packaging: 500mg
Price: $531
Updated: 2024/03/01

Strem Chemicals

Product number: 45-0159
Product name: (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-DUPHOS-Rh
Packaging: 2g
Price: $1725
Updated: 2024/03/01

American Custom Chemicals Corporation

Product number: OGM0000034
Product name: (+)-1,2-BIS((2S,5S)-2,5-DIMETHYL PHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUORO BORATE
Purity: 95.00%
Packaging: 500MG
Price: $1152.11
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: OGM0000034
Product name: (+)-1,2-BIS((2S,5S)-2,5-DIMETHYL PHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUORO BORATE
Purity: 95.00%
Packaging: 100MG
Price: $697.34
Updated: 2021/12/16

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(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE Chemical Properties,Usage,Production

Reactions

The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides.
Forms superior catalysts for asymmetric reductive aminations.
Catalyst used for the asymmetric hydrogenation of enol phosphonates.
A novel enantioselective synthesis of β-amino alcohols and 1,2-diamines.
Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO.
Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization.
Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines.
Palladium catalyzed asymmetric phosphination.

Chemical Properties

orange or red crystalline powder

Uses

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE Preparation Products And Raw materials

Raw materials

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(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE Suppliers

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205064-10-4, (+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATERelated Search:

Benzene (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate (+)-1,2-BIS[(2S,5S)-2,5-DIMETHYLPHOSPHOLANO]BENZENE (+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE (+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE

(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE

(+)-1,2-BIS((2S,5S)-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I) BF4

(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(l)tetrafluoroborate

Bisdimethylphospholanobenzenecyclooctadienerhodium

(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(I)tetrafluoroborate,98+%(S,S)-Me-DUPHOS-Rh

(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-DUPHOS-Rh

(+)-1,2-Bis[(2S,5S)-2,5-diMethylphospholano]benzene(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate, 97%

(+)-1,2-Bis((2S,5S)-2,5-diMethylphospholano)benzene(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate (S,S)-Me-DUPHOS-Rh

(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(1,5-CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE,98+%(S,S)-ME-DUPHOS-RH

(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(l)tetra

(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

(+)-1,2-Bis((2S,5S)-2,5-dimethyL

Rhodium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene][(2S,2'S,5S,5'S)-1,1'-(1,2-phenylene)bis[2,5-dimethylphospholane-κP]]-, tetrafluoroborate(1-) (1:1)

(1,2,5,6-η)-1,5-Cyclooctadiene][(2S,2'S,5S,5'S)-1,1'-(1,2-phenylene)bis[2,5-dimethylphospholane-κP]]-rhodium Tetrafluoroborate

(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE

[((SS)-Me-DuPhos)Rh(COD)]BF4

205064-10-4

C26H40BF4P2Rh

Chiral Catalysts, Ligands, and Reagents

Asymmetric Synthesis

Hydrogenation

Chiral Catalysts, Ligands, and Reagents

DuPhos/BPE

Privileged Ligands and Complexes

organometallic complex