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ChemicalBook > CAS DataBase List > (+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE

(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE

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Product Name
(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE
CAS No.
205064-10-4
Chemical Name
(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE
Synonyms
[((SS)-Me-DuPhos)Rh(COD)]BF4;(+)-1,2-Bis((2S,5S)-2,5-dimethyL;Bisdimethylphospholanobenzenecyclooctadienerhodium;(+)-1,2-BIS((2S,5S)-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I) BF4;(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(l)tetra;(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(l)tetrafluoroborate;(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE;(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE;(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate;(+)-1,2-Bis[(2S,5S)-2,5-diMethylphospholano]benzene(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate, 97%
CBNumber
CB3728521
Molecular Formula
C26H40BF4P2Rh4*
Formula Weight
604.25
MOL File
205064-10-4.mol
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(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE Property

form 
crystal
color 
red-orange
Sensitive 
air sensitive
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Safety

Risk Statements 
36/37/38
Safety Statements 
24/25
WGK Germany 
3
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Strem Chemicals
Product number
45-0159
Product name
(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-DUPHOS-Rh
Packaging
100mg
Price
$125
Updated
2024/03/01
Strem Chemicals
Product number
45-0159
Product name
(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-DUPHOS-Rh
Packaging
500mg
Price
$531
Updated
2024/03/01
Strem Chemicals
Product number
45-0159
Product name
(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-DUPHOS-Rh
Packaging
2g
Price
$1725
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
OGM0000034
Product name
(+)-1,2-BIS((2S,5S)-2,5-DIMETHYL PHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUORO BORATE
Purity
95.00%
Packaging
500MG
Price
$1152.11
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
OGM0000034
Product name
(+)-1,2-BIS((2S,5S)-2,5-DIMETHYL PHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUORO BORATE
Purity
95.00%
Packaging
100MG
Price
$697.34
Updated
2021/12/16
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(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE Chemical Properties,Usage,Production

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  1. The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides.
  2. Forms superior catalysts for asymmetric reductive aminations.
  3. Catalyst used for the asymmetric hydrogenation of enol phosphonates.
  4. A novel enantioselective synthesis of β-amino alcohols and 1,2-diamines.
  5. Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO.
  6. Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization.
  7. Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines.
  8. Palladium catalyzed asymmetric phosphination. 

Chemical Properties

orange or red crystalline powder

Uses

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE Preparation Products And Raw materials

Raw materials

Preparation Products

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(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE Suppliers

Belgium 1 China 27 Germany 2 India 1 Switzerland 1 United States 4 Global 36

205064-10-4, (+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATERelated Search:

Benzene (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate (+)-1,2-BIS[(2S,5S)-2,5-DIMETHYLPHOSPHOLANO]BENZENE (+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE (+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE

  • (+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE
  • (+)-1,2-BIS((2S,5S)-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I) BF4
  • (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(l)tetrafluoroborate
  • Bisdimethylphospholanobenzenecyclooctadienerhodium
  • (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(I)tetrafluoroborate,98+%(S,S)-Me-DUPHOS-Rh
  • (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-DUPHOS-Rh
  • (+)-1,2-Bis[(2S,5S)-2,5-diMethylphospholano]benzene(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate, 97%
  • (+)-1,2-Bis((2S,5S)-2,5-diMethylphospholano)benzene(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate (S,S)-Me-DUPHOS-Rh
  • (+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(1,5-CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE,98+%(S,S)-ME-DUPHOS-RH
  • (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(l)tetra
  • (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
  • (+)-1,2-Bis((2S,5S)-2,5-dimethyL
  • Rhodium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene][(2S,2'S,5S,5'S)-1,1'-(1,2-phenylene)bis[2,5-dimethylphospholane-κP]]-, tetrafluoroborate(1-) (1:1)
  • (1,2,5,6-η)-1,5-Cyclooctadiene][(2S,2'S,5S,5'S)-1,1'-(1,2-phenylene)bis[2,5-dimethylphospholane-κP]]-rhodium Tetrafluoroborate
  • (+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE
  • [((SS)-Me-DuPhos)Rh(COD)]BF4
  • 205064-10-4
  • C26H40BF4P2Rh
  • Chiral Catalysts, Ligands, and Reagents
  • Asymmetric Synthesis
  • Hydrogenation
  • Chiral Catalysts, Ligands, and Reagents
  • DuPhos/BPE
  • Privileged Ligands and Complexes
  • organometallic complex