ChemicalBook > CAS DataBase List > (S)-1-Benzyl-3-pyrrolidinol

(S)-1-Benzyl-3-pyrrolidinol

Product Name
(S)-1-Benzyl-3-pyrrolidinol
CAS No.
101385-90-4
Chemical Name
(S)-1-Benzyl-3-pyrrolidinol
Synonyms
S-BHP;CAS:101385-90-4;Compound Fr12310;Benzylpyrrolidinol;N-BENZYL-(S)-3-PYRROLIDINOL;(S)-1-BENZYL-3-PYRROLIDINOL;(S) -1-benzyl-3-pyrrolidine;(3S)-1-Benzyl-3-pyrrolidinol;(3S)-1-BENZYLPYRROLIDIN-3-OL;(S)-1-BENZYL-PYRROLIDIN-3-OL
CBNumber
CB3736601
Molecular Formula
C11H15NO
Formula Weight
177.24
MOL File
101385-90-4.mol
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(S)-1-Benzyl-3-pyrrolidinol Property

alpha 
-3.7 º (c=5, MeOH)
Boiling point:
115 °C0.8 mm Hg(lit.)
Density 
1.07 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.548(lit.)
Flash point:
>230 °F
storage temp. 
2-8°C
form 
Liquid
pka
14.82±0.20(Predicted)
color 
Clear light yellow to pale brown
optical activity
[α]24/D 3.7°, c = 5 in methanol
BRN 
4982831
InChI
InChI=1S/C11H15NO/c13-11-6-7-12(9-11)8-10-4-2-1-3-5-10/h1-5,11,13H,6-9H2/t11-/m0/s1
InChIKey
YQMXOIAIYXXXEE-NSHDSACASA-N
SMILES
N1(CC2=CC=CC=C2)CC[C@H](O)C1
CAS DataBase Reference
101385-90-4(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
HS Code 
29339900
Storage Class
10 - Combustible liquids
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
366943
Product name
(S)-(?)-1-Benzyl-3-pyrrolidinol
Purity
99%
Packaging
5g
Price
$38.7
Updated
2025/07/31
TCI Chemical
Product number
B1533
Product name
(S)-1-Benzyl-3-pyrrolidinol
Purity
>98.0%(GC)
Packaging
5g
Price
$76
Updated
2021/12/16
TCI Chemical
Product number
B1533
Product name
(S)-1-Benzyl-3-pyrrolidinol
Purity
>98.0%(GC)
Packaging
25g
Price
$279
Updated
2021/12/16
TRC
Product number
B130165
Product name
(S)-1-Benzylpyrrolidin-3-ol
Packaging
500mg
Price
$60
Updated
2021/12/16
Oakwood
Product number
011443
Product name
(S)-1-Benzylpyrrolidin-3-ol
Purity
97%
Packaging
25g
Price
$71
Updated
2021/12/16
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(S)-1-Benzyl-3-pyrrolidinol Chemical Properties,Usage,Production

Chemical Properties

Clear light yellow liquid

Uses

For synthesis of optically active products

Synthesis

A four-necked round-bottomed flask was charged with 9.20 g (242.4 mmol) of lithium aluminum hydride and 100 mL of tetrahydrofuran, and 17.00 g (82.84 mmol) of (3S)-N-benzyl-3-hydroxysuccinimide in tetrahydrofuran (80 mL) was added dropwise at 0-10 ??C. The mixture was heated to reflux and stirred at this temperature for 6 h. The mixture was cooled to 10-20 ??C and water (40 mL) and 4N sodium hydroxide solution (10 mL) were added, the mixture was filtered and the resulting filter cake was washed with ethyl acetate (2 x 200 mL). The mother liquor was concentrated in vacuo and the remaining residue was dissolved in ethyl acetate (400 mL) and washed with brine. The organic layer was dried over anhydrous sodium sulfate and concentrated in vacuo to afford 18.00 g (quantitative yield) of (S)-3-hydroxy-1-benzylpyrrolidine as an oil .

(S)-1-Benzyl-3-pyrrolidinol Preparation Products And Raw materials

Raw materials

L-Malic acid Calcium chloride Acetyl chloride Benzylamine Sodium borohydride Tetrahydrofuran Ethyl acetate Lithium Aluminum Hydride Hydrochloric acid Dichloromethane Methanol Sodium hydroxide PETROLEUM ETHER

Preparation Products

(3S)-(-)-3-(DIMETHYLAMINO)PYRROLIDINE (3R)-(+)-3-(DIMETHYLAMINO)PYRROLIDINE
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(S)-1-Benzyl-3-pyrrolidinol Suppliers

Americas 1 China 213 Europe 2 France 1 Germany 8 India 15 Japan 6 Slovakia 1 South Korea 4 Switzerland 3 The Netherlands 1 United Kingdom 19 United States 43 Global 317
Chengdu Firster Pharmaceutical Co., Ltd.
Tel
028-87078428 028-87074958
Fax
8772-8116
Email
chengzhenyong@cdfirster.com
Country
China
ProdList
2598
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60
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
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76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
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INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
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Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
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TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
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81
Energy Chemical
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021-021-58432009 400-005-6266
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021-58436166
Email
sales8178@energy-chemical.com
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China
ProdList
44801
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Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35896
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56
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Country
China
ProdList
18207
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66
Shanghai Sinch Parmaceuticals Tech. Co. Ltd.
Tel
+86-21-54098501
Fax
+86-21-54096319
Email
sales@sinch.com.cn
Country
China
ProdList
11598
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View Lastest Price from (S)-1-Benzyl-3-pyrrolidinol manufacturers

Watson Biotechnology Co.,Ltd
Product
(S)-1-Benzyl-3-pyrrolidinol 101385-90-4
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20MT
Release date
2025-02-18
Henan Aochuang Chemical Co.,Ltd.
Product
(S)-1-Benzyl-3-pyrrolidinol 101385-90-4
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1Ton
Release date
2022-10-08
Hebei Yanxi Chemical Co., Ltd.
Product
(S)-1-Benzyl-3-Pyrrolidinol 101385-90-4
Price
US $0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
100kg
Release date
2023-09-15

101385-90-4, (S)-1-Benzyl-3-pyrrolidinol Related Search:

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  • (3S)-1-BENZYLPYRROLIDIN-3-OL
  • 3-PYRROLIDINOL, 1-(PHENYLMETHYL)-, (S)
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  • (S)-1-N-BENZYL-3-HYDROXYPYRROLIDINE
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  • (S)-1-BENZYL-PYRROLIDINE-3-OL
  • (S)-3-HYDROXY-1-BENZYL-PYRROLIDINE
  • S-BHP
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  • Benzylpyrrolidinol
  • (R)-N-Benzy-3-hydroxypyrrolidine
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  • (S)-1-Benzyl-3-hydroxypyrrolidine.(D)-Mandelicacid
  • (S)-1-Benzyl-3-pyrrolidinol&gt
  • (S) -1-benzyl-3-pyrrolidine
  • S(-) -1- benzyl-3-Pyrrodinol
  • (3S)-1-(Phenylmethyl)-3-pyrrolidinol
  • (3S)-1-Benzyl-3-methylpyrrolidine
  • tianfu-chem-(S)-1-Benzyl-3-pyrrolidinol,101385-90-4
  • Compound Fr12310
  • CAS:101385-90-4
  • (<i>S</i>)-(?)-1-Benzyl-3-pyrrolidinol
  • IsopropylN-[(S)-(2,3,4,5,6-pentafluorophenoxy)phenoxyphosphoryl]-L-alaninate
  • (S)-1-Benzylpyrrolidin-3-ol - [B91463]
  • 101385-90-4
  • C11H15NO
  • AMINE
  • Heterocyclic Building Blocks
  • Pyrrolidines
  • Chiral Building Blocks
  • Simple Alcohols (Chiral)
  • Asymmetric Synthesis
  • Pyrrole&Pyrrolidine&Pyrroline
  • Alcohols and Derivatives
  • Heterocyclic Building Blocks
  • Chiral Building Blocks