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DIALLATE

Product Name
DIALLATE
CAS No.
2303-16-4
Chemical Name
DIALLATE
Synonyms
DATC;Avadex;cp15336;Diallat;Pyradex;2,3-DCDT;Avadex I;DIALLATE;CP 15336;cp15,336
CBNumber
CB3751152
Molecular Formula
C10H17Cl2NOS
Formula Weight
270.22
MOL File
2303-16-4.mol
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DIALLATE Property

Melting point:
25-30℃
Boiling point:
bp9 150°
Density 
1.1556 (rough estimate)
refractive index 
1.6000 (estimate)
Flash point:
>100 °C
storage temp. 
0-6°C
pka
-1.63±0.70(Predicted)
form 
Viscous Liquid
color 
Colorless to light yellow
Water Solubility 
40mg/L(room temperature)
IARC
3 (Vol. 30, Sup 7) 1987
EPA Substance Registry System
Diallate (2303-16-4)
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Safety

Hazard Codes 
Xn,N
Risk Statements 
22-40-50/53
Safety Statements 
25-36/37-60-61
RIDADR 
2902
RTECS 
EZ8225000
HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
29302000
Hazardous Substances Data
2303-16-4(Hazardous Substances Data)
Toxicity
LD50 orally in rats: 395 mg/kg (Bailey, White)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H351Suspected of causing cancer

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P281Use personal protective equipment as required.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P308+P313IF exposed or concerned: Get medical advice/attention.

P330Rinse mouth.

P391Collect spillage. Hazardous to the aquatic environment

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
D414830
Product name
Diallate
Packaging
25mg
Price
$200
Updated
2021/12/16
TRC
Product number
D414830
Product name
Diallate
Packaging
100mg
Price
$770
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
API0010746
Product name
AVADEX(R)
Purity
95.00%
Packaging
5MG
Price
$499.03
Updated
2021/12/16
AHH
Product number
MT-49919
Product name
Diallate
Purity
98%
Packaging
0.5g
Price
$240
Updated
2021/12/16
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DIALLATE Chemical Properties,Usage,Production

Description

Diallate is a brown liquid. Molecularweight = 270.21; Boiling point =150℃ at 9 mmHg;Freezing/Melting point = 25-30℃. Hazard Identification(based on NFPA-704 M Rating System): Health 2,Flammability 0, Reactivity 0. Slightly soluble in water;solubility = 14 mg/L at 25℃.

Chemical Properties

Diallate is a brown liquid.

Uses

Herbicide.

Uses

Preemergent, selective herbicide used to control wild oats and blackgrass in barley, corn, flax, lentils, peas, potatoes, soybeans and sugar beets.

Uses

Diallate is a pesticide used to treat fruits and vegetables. Environmental wastewater pollutant.Environmental toxin on US EPA Toxic Release Inventory list (TRI) list.

Definition

ChEBI: Diallat is a tertiary amine.

General Description

Used as an herbicide.

Air & Water Reactions

Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids.

Reactivity Profile

DIALLATE is a thiocarbamate ester. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides.

Safety Profile

Poison by ingestion. Moderately toxic by skin contact. Questionable carcinogen with experimental carcinogenic and tumorigenic data. Mutation data reported. When heated to decomposition it emits very toxic fumes of Cl-, NOx, and SOx. See also CARBAMATES and ALLYL COMPOUNDS.

Potential Exposure

A thiocarbamate herbicide. The slow release of poisonous gases from hydrolysis of many thio and dithiocarbamates requires the use of respirators during handling. Poisoning can also occur by ingestion and absorption through the skin. Diallate is potential danger to those involved in the manufacture, formulation and applica- tion of this re-emergence herbicide.

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seekmedical attention immediately. If this chemical contactsthe skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove fromexposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing hasstopped and CPR if heart action has stopped. Transferpromptly to a medical facility. When this chemical hasbeen swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.

Environmental Fate

Soil. Soil metabolites include 2,3-dichloroallyl alcohol, 2,3-dichloroallyl mercaptan (Hartley and Kidd, 1987) and carbon dioxide (Smith, 1988). The formation of the alcohol occurs via hydrolysis of the ester linkage and transthiolation of the allylic group (Kaufman, 1967). In an agricultural soil, 14CO2 was the only biodegradation identified; however, bound residue and traces of benzene and water-soluble radioactivity were also detected in large amounts (Anderson and Domsch, 1980). The reported half-lives in soil range from 2 to 4 weeks to (Smith and Fitzpatrick, 1970) to approximately 30 days (Hartley and Kidd, 1987). Diallate did not migrate deeper than 5 cm on test field plots (Smith, 1970). In four microbially-active agricultural soils, the half-life was 4 weeks but in sterilized soil the half-life was 20 weeks (Anderson and Domsch, 1976).
Plant. In plants, diallate is metabolized and carbon dioxide is released (Hartley and Kidd, 1987). Diallate undergoes cis/trans isomerization and oxidative cleavage when irradiated at 300 nm forming 2,3-dichloroacrolein and 2-chloroacrolein as products (Ruzo and Casida, 1985).
Photolytic. Irradiation of diallate was also conducted in oxygenated chloroform or water until a 10% conversion was obtained. Products formed included acetaldehyde, 2,3- dichloroacrolein and trace amounts of 2-chloroacrolein (Ruzo and Casida, 1985). Chemical/Physical. Emits toxic fumes of chlorine, nitrogen and sulfur oxides when heated to decomposition (Sax and Lewis, 1987). Though no products were reported, the calculated hydrolysis half-life at 25°C and pH 7 is 6.6 years (Ellington et al., 1988).

storage

Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with diallateyou should be trained on its proper handling and storage.Store in tightly closed containers in a cool, well-ventilatedarea away from alkalies. Where possible, automaticallypump liquid from drums or other storage containers to process containers. A regulated, marked area should be established where this chemical is handled, used, or stored incompliance with OSHA Standard 1910.1045.

Shipping

UN2992 Carbamate pesticides, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Incompatibilities

hiocarbamate esters are combustible. They react violently with powerful oxidizers such as calcium hypochlorite. Poisonous gases are generated by the thermal decomposition of thiocarbamate compounds, including carbon disulfide, oxides of sulfur, oxides of nitro- gen, hydrogen sulfide, ammonia, and methylamine. Many materials in this group slowly decompose in aqueous solu- tion to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids. Flammable gases are generated by the combination of thiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates are incompatible with acids, peroxides, and acid halides.

Waste Disposal

Land burial is acceptable for small quantities. Larger quantities can be incinerated . In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.

DIALLATE Preparation Products And Raw materials

Raw materials

Preparation Products

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DIALLATE Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Sichuan Kulinan Technology Co., Ltd
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11707
Advantage
57
Spectrum Chemical Manufacturing Corp.
Tel
021-021-021-67601398-809-809-809 15221380277
Fax
021-57711696
Email
marketing_china@spectrumchemical.com
Country
China
ProdList
9658
Advantage
60
Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
4008-755-333 18080918076
Fax
028-86757656
Email
800078821@qq.com
Country
China
ProdList
9718
Advantage
55
Alta Scientific Co., Ltd.
Tel
022-6537-8550 15522853686
Fax
022-2532-9655
Email
sales@altasci.com.cn
Country
China
ProdList
4511
Advantage
55
Shanghai Synchem Pharma Co., ltd
Tel
21-619849051-1 18521059765
Email
synchempharma@aliyun.com
Country
China
ProdList
6463
Advantage
55
Codow Chemical Co.,Ltd.
Tel
18620099427
Fax
+86-20-62619665
Email
amy@howeipharm.com
Country
China
ProdList
17687
Advantage
55
Shandong Xiya Chemical Co., Ltd.
Tel
4009903999 13395398332
Fax
0539-6365991
Email
sales@xiyashiji.com
Country
China
ProdList
20806
Advantage
60
Shenzhen Regent Biochemical Technology Co., Ltd.
Tel
0755-0755-85201366 18938635012
Fax
0755-85201366
Email
sales@regentsciences.com
Country
China
ProdList
9357
Advantage
58
Shenzhen Polymeri Biochemical Technology Co., Ltd.
Tel
+86-400-002-6226 +86-13028896684;
Email
sales@rrkchem.com
Country
China
ProdList
56604
Advantage
58

2303-16-4, DIALLATERelated Search:


  • S-2,3-DICHLOROALLYL DIISOPROPYL THIOCARBAMATE
  • S-[2,3-DICHLOROALLYL]-N,N'-DI-ISOPROPYL THIOCARBAMATE
  • DIALLATE MIXTURE OF CIS AND TRANS ISOME&
  • DIALLATE, 100MG, NEAT
  • 2,3-DCDT
  • 2,3-dichlorallyl-n,n-(diisopropyl)-thiocarbamat
  • 2,3-Dichlorallyl-N,N-(diisopropyl)-thiocarbamate
  • 2,3-dichloro-2-propene-1-thiodiisopropylcarbamate
  • 2,3-Dichloro-2-propene-1-thiol, diisopropylcarbamate
  • 2,3-dichloro-2-propene-1-thiol,diisopropylcarbamate
  • 2-Propene-1-thiol, 2,3-dichloro-, diisopropylcarbamate
  • Avadex
  • Avadex I
  • Avadex II
  • Bis(1-methylethyl) carbamothioic acid, S-(2,3-dichloro-2-propenyl)ester
  • bis(1-methylethyl)carbamothioicacid,s-(2,3-dichloro-2-propenyl)ester
  • di-allate (bsi,e-iso)
  • diallate (f-iso,wssa)
  • Diallate (95-98%)
  • SEC-2,3-DICHLOROALLYLDIISOPROPYLTHIOCARBAMATE
  • Diallate(cisortrans)
  • di-allate (ISO) S-(2,3-dichloroallyl)-N,N-diisopropylthiocarbamate
  • Di-allate 100mg [2303-16-4]
  • Diallate Standard
  • S-(2,3-dichloroallyl) diisopropylcarbamothioate
  • S-[(2Z)-2,3-Dichloro-2-propenyl] diisopropylthiocarbamate
  • AVADEX(R)
  • DIALLATE
  • DATC
  • 2,3-Dichloroallyl-N,N-diisopropylthiolcarbamate
  • Carbamic acid, diisopropylthio-, S-(2,3-dichloroallyl) ester
  • carbamicacid,diisopropylthio-,s-(2,3-dichloroallyl)ester
  • Carbamothioicacid,bis(1-methylethyl)-,S-(2,3-dichloro-2-propenyl)ester
  • CP 15,336
  • CP 15336
  • cp15,336
  • cp15336
  • Diallaat
  • Diallat
  • Dichloroallyl diisopropylthiocarbamate
  • dichloroallyldiisopropylthiocarbamate
  • Diisopropylthiocarbamic acid, S-(2,3-dichloroallyl) ester
  • diisopropylthiocarbamicacid,s-(2,3-dichloroallyl)ester
  • DiisopropylthiocarbamicacidS-2,3-dichloroallylester
  • Di-isopropylthiolocarbamate de S-(2,3-dichloro allyle)
  • di-isopropylthiolocarbamatedes-(2,3-dichloroallyle)
  • di-isopropylthiolocarbamatedes-(2,3-dichloroallyle)(french)
  • Pyradex
  • Rcra waste number U062
  • rcrawastenumberu062
  • S-(2,3-Dichlor-allyl)-N,N-diisopropyl-monothiocarbamaat
  • s-(2,3-dichloro-2-propenyl)bis(1-methylethyl)carbamothioate
  • S-(2,3-Dichloro-allil)-N,N-diisopropil-monotiocarbammato
  • Diallate(Mixture of E and Z isomer)
  • Diallate @100 μg/mL in MeOH
  • Di-allateSolution,1000mg/L,1ml
  • Diallate (95-98%) @1000 μg/mL in Acetonitrile
  • Diallate@1000 μg/mL in Methanol